FR2379565A1 - Nouvelles particules expansibles de polymere de styrene et leur procede de preparation - Google Patents
Nouvelles particules expansibles de polymere de styrene et leur procede de preparationInfo
- Publication number
- FR2379565A1 FR2379565A1 FR7803157A FR7803157A FR2379565A1 FR 2379565 A1 FR2379565 A1 FR 2379565A1 FR 7803157 A FR7803157 A FR 7803157A FR 7803157 A FR7803157 A FR 7803157A FR 2379565 A1 FR2379565 A1 FR 2379565A1
- Authority
- FR
- France
- Prior art keywords
- styrene polymer
- ester
- preparation process
- polymer particles
- new
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract 8
- 239000002245 particle Substances 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
L'invention concerne des particules expansibles de polymère de styrène et un procédé pour leur préparation. Les particules expansible de polymère de styrène comportent à leur surface un ester d'un acide carboxylique aliphatique et d'un alcool aliphatique, l'ester n'ayant pas de radical hydroxy dans sa molécule et étant solide à la température ordinaire, ou un mélange de cet ester et d'un lubrifiant finement divisé. L'invention s'applique en particulier à l'accroissement de la productivité d'articles moulés constitués de particules expansées de polymère de styrène par diminution du temps de refroidissement lors du moulage.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52011341A JPS5856568B2 (ja) | 1977-02-04 | 1977-02-04 | 新規発泡性スチレン系樹脂粒子およびその製造法 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2379565A1 true FR2379565A1 (fr) | 1978-09-01 |
FR2379565B1 FR2379565B1 (fr) | 1982-05-14 |
Family
ID=11775323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7803157A Granted FR2379565A1 (fr) | 1977-02-04 | 1978-02-03 | Nouvelles particules expansibles de polymere de styrene et leur procede de preparation |
Country Status (4)
Country | Link |
---|---|
US (1) | US4238570A (fr) |
JP (1) | JPS5856568B2 (fr) |
DE (1) | DE2804688B2 (fr) |
FR (1) | FR2379565A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0046494A1 (fr) * | 1980-08-08 | 1982-03-03 | BASF Aktiengesellschaft | Particules expansibles en polymère de styrène et leur application |
EP0249711A2 (fr) * | 1986-06-14 | 1987-12-23 | Hüls Aktiengesellschaft | Procédé de préparation de dispersions aqueuses à viscosité basse d'esters de glycérine et d'acides gras à longue chaîne |
WO1995005414A1 (fr) * | 1993-08-16 | 1995-02-23 | Shell Internationale Research Maatschappij B.V. | Perles d'un polymere d'un compose vinylaromatique |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2942182A1 (de) * | 1979-10-18 | 1981-05-07 | Basf Ag, 6700 Ludwigshafen | Teilchenfoermige, treibmittelhaltige styrolpolymerisate und deren verwendung |
JPS56112944A (en) * | 1980-02-14 | 1981-09-05 | Badische Yuka Co Ltd | Expandable styrene resin particle |
US4361656A (en) * | 1981-08-03 | 1982-11-30 | American Hoechst Corporation | Method of making expandable styrene-type polymer beads |
JPS58122935A (ja) * | 1982-01-19 | 1983-07-21 | Satsuki Kitani | 発泡ビ−ズの製造方法 |
JPS58141219A (ja) * | 1982-02-16 | 1983-08-22 | Badische Yuka Co Ltd | 発泡性メタクリル酸メチル系樹脂粒子 |
JPS58222122A (ja) * | 1982-06-18 | 1983-12-23 | Kanegafuchi Chem Ind Co Ltd | 発泡性スチレン系重合体粒子の製造方法 |
JPS58222121A (ja) * | 1982-06-18 | 1983-12-23 | Kanegafuchi Chem Ind Co Ltd | 発泡性熱可塑性重合体粒子の製造方法 |
US4520136A (en) * | 1982-09-24 | 1985-05-28 | Cosden Technology, Inc. | Foamable polymeric styrene particles |
US4548956A (en) * | 1982-09-24 | 1985-10-22 | Cosden Technology, Inc. | Foamable polymeric styrene particles |
DE3317169A1 (de) | 1982-10-26 | 1984-04-26 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von verbesserten formmassen aus kleinteiligen blaehfaehigen styrolpolymerisaten durch beschichten und verwenden des beschichteten produktes |
CA1203950A (fr) * | 1982-12-23 | 1986-04-29 | Harold S. Cox | Articles a l'epreuve de l'electricite statique |
EP0122460B1 (fr) * | 1983-03-23 | 1988-07-06 | Chuo Kagaku Co., Ltd. | Production d'une mousse de résine en utilisant une composition aqueuse |
US4429058A (en) | 1983-04-08 | 1984-01-31 | Cosden Technology, Inc. | Expandable polymeric styrene particles |
US4439490A (en) * | 1983-04-08 | 1984-03-27 | Cosden Technology, Inc. | Expandable polymeric styrene particles |
JPS6082185A (ja) * | 1983-10-12 | 1985-05-10 | Mitsubishi Heavy Ind Ltd | 含油排水処理に用いられる吸着材量の決定方法 |
JPH0610274B2 (ja) * | 1987-04-24 | 1994-02-09 | 積水化成品工業株式会社 | 発泡性共重合体樹脂粒子組成物 |
JPH0610273B2 (ja) * | 1987-04-24 | 1994-02-09 | 積水化成品工業株式会社 | 発泡性共重合体樹脂粒子組成物 |
US4781983A (en) * | 1987-04-30 | 1988-11-01 | Arco Chemical Company | Method for preparing antistatic expandable polystyrene |
US4792572A (en) * | 1988-02-25 | 1988-12-20 | Texstyrene Plastics, Inc. | Novel particulate expandable styrene polymers having short minimum molding times and method for preparing same |
US5006368A (en) * | 1988-10-19 | 1991-04-09 | The Dow Chemical Company | Plastic particle coated with processing aid and method of coating |
WO1990004463A1 (fr) * | 1988-10-19 | 1990-05-03 | The Dow Chemical Company | Pastilles de plastique enrobees d'un auxiliaire de traitement et procede d'enrobage |
US5317044A (en) * | 1989-05-16 | 1994-05-31 | J. M. Huber Corporation | Endothermic blowing agents for surface migration of components in foamed products, compositions and applications |
JPH08863B2 (ja) * | 1990-12-27 | 1996-01-10 | 積水化成品工業株式会社 | ポリスチレン系樹脂発泡体の製造方法 |
IT1289606B1 (it) * | 1997-01-30 | 1998-10-15 | Enichem Spa | Procedimento per la produzione di particelle espandibili di polimeri stirenici |
JP5436768B2 (ja) * | 2007-10-31 | 2014-03-05 | 株式会社ジェイエスピー | スチレン系樹脂発泡粒子及びスチレン系樹脂発泡粒子成形体 |
US8889748B2 (en) * | 2010-06-01 | 2014-11-18 | Basf Se | Process for producing expandable styrene polymer compositions |
JP7196078B2 (ja) * | 2017-08-04 | 2022-12-26 | 株式会社カネカ | 発泡性ポリスチレン系樹脂粒子、ポリスチレン系予備発泡粒子及び発泡成形体 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2209790A1 (fr) * | 1972-12-08 | 1974-07-05 | Shell Int Research | |
FR2255319A1 (fr) * | 1973-12-24 | 1975-07-18 | Montedison Spa |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2989782A (en) * | 1956-07-05 | 1961-06-27 | Monsanto Chemicals | Method for preparing molded foamed resin article |
US3560414A (en) * | 1968-02-09 | 1971-02-02 | Dart Ind Inc | Process for preparing foamable beads |
BE785883A (fr) * | 1971-07-05 | 1973-01-05 | Hoechst Ag | Particules transformables en mousse a base de polymeres du styrene |
GB1408267A (en) * | 1971-11-22 | 1975-10-01 | Shell Int Research | Expandable polymers of vinylidene aromatic compounds |
GB1405930A (en) * | 1972-12-08 | 1975-09-10 | Shell Int Research | Expandable polymers of vinyl-idene aromatic compounds |
JPS52147669A (en) * | 1976-06-03 | 1977-12-08 | Kanegafuchi Chemical Ind | Process for manufacture of expandable thermoplastic polymer powder |
US4042541A (en) * | 1976-12-13 | 1977-08-16 | The Dow Chemical Company | Expandable polystyrene particles |
-
1977
- 1977-02-04 JP JP52011341A patent/JPS5856568B2/ja not_active Expired
-
1978
- 1978-02-03 DE DE2804688A patent/DE2804688B2/de not_active Withdrawn
- 1978-02-03 FR FR7803157A patent/FR2379565A1/fr active Granted
-
1979
- 1979-02-23 US US06/014,716 patent/US4238570A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2209790A1 (fr) * | 1972-12-08 | 1974-07-05 | Shell Int Research | |
FR2255319A1 (fr) * | 1973-12-24 | 1975-07-18 | Montedison Spa |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0046494A1 (fr) * | 1980-08-08 | 1982-03-03 | BASF Aktiengesellschaft | Particules expansibles en polymère de styrène et leur application |
EP0249711A2 (fr) * | 1986-06-14 | 1987-12-23 | Hüls Aktiengesellschaft | Procédé de préparation de dispersions aqueuses à viscosité basse d'esters de glycérine et d'acides gras à longue chaîne |
EP0249711A3 (en) * | 1986-06-14 | 1988-04-06 | Huls Aktiengesellschaft | Process for the preparation of low-viscosity aqueous dispersions of esters from glycerine and long-chain fatty acids, and their use |
WO1995005414A1 (fr) * | 1993-08-16 | 1995-02-23 | Shell Internationale Research Maatschappij B.V. | Perles d'un polymere d'un compose vinylaromatique |
Also Published As
Publication number | Publication date |
---|---|
DE2804688B2 (de) | 1980-11-06 |
JPS5856568B2 (ja) | 1983-12-15 |
JPS5397060A (en) | 1978-08-24 |
FR2379565B1 (fr) | 1982-05-14 |
US4238570A (en) | 1980-12-09 |
DE2804688A1 (de) | 1978-08-17 |
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