FR2378000A1 - Procede de preparation d'imides, d'amides ou d'amides-imides par condensation d'isocyanates avec des acides carboxyliques ou leurs anhydrides - Google Patents

Procede de preparation d'imides, d'amides ou d'amides-imides par condensation d'isocyanates avec des acides carboxyliques ou leurs anhydrides

Info

Publication number
FR2378000A1
FR2378000A1 FR7801616A FR7801616A FR2378000A1 FR 2378000 A1 FR2378000 A1 FR 2378000A1 FR 7801616 A FR7801616 A FR 7801616A FR 7801616 A FR7801616 A FR 7801616A FR 2378000 A1 FR2378000 A1 FR 2378000A1
Authority
FR
France
Prior art keywords
imids
preparation
amids
amid
isocyanates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7801616A
Other languages
English (en)
Other versions
FR2378000B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pharmacia and Upjohn Co
Original Assignee
Upjohn Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upjohn Co filed Critical Upjohn Co
Publication of FR2378000A1 publication Critical patent/FR2378000A1/fr
Application granted granted Critical
Publication of FR2378000B1 publication Critical patent/FR2378000B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0262—Phosphorus acids or phosphorus acid esters comprising phosphinous acid (-ester) groups (R2P(OR')) or the isomeric phosphine oxide groups (R3P=O), i.e. R= C, R'= C, H
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65685—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine oxide or thioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/14—Polyamide-imides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Indole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyamides (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

La présente invention concerne le domaine des imides, amides ou amides-imides. Le procédé de l'invention, pour la préparation de tels composés, comprend la réaction d'un mono- ou poly-iso-cyanate avec un acide ou anhydride carboxylique (mono- ou poly-). On utilise comme catalyseur le dérive 1-oxyde, 1-sulfure ou 1-hydrocarbylimino d'un phospholène, phospholane ou phosphétane. Ces derniers composés sont aussi substitués dans la position 1- par un hydrocarbyle (C1-12 ) ou halohydrocarbyle (C1-2 ) et peuvent porter en outre un ou plusieurs groupes halo, alkoxy inférieur, phénoxy, hydrocarbyle inférieur ou hydrocarbyle halo-substitué, sur les atomes de carbone du noyau. Les produits obtenus sont connus pour leurs propriétés insecticides, fongicides et herbicides.
FR7801616A 1977-01-21 1978-01-20 Procede de preparation d'imides, d'amides ou d'amides-imides par condensation d'isocyanates avec des acides carboxyliques ou leurs anhydrides Granted FR2378000A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/761,614 US4156065A (en) 1977-01-21 1977-01-21 Catalytic condensation of isocyanates and carboxylic acids or anhydrides

Publications (2)

Publication Number Publication Date
FR2378000A1 true FR2378000A1 (fr) 1978-08-18
FR2378000B1 FR2378000B1 (fr) 1983-09-09

Family

ID=25062763

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7801616A Granted FR2378000A1 (fr) 1977-01-21 1978-01-20 Procede de preparation d'imides, d'amides ou d'amides-imides par condensation d'isocyanates avec des acides carboxyliques ou leurs anhydrides

Country Status (7)

Country Link
US (1) US4156065A (fr)
JP (1) JPS5940142B2 (fr)
DE (1) DE2801701C2 (fr)
FR (1) FR2378000A1 (fr)
GB (1) GB1575669A (fr)
IT (1) IT1103108B (fr)
NL (1) NL187849C (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0104391A2 (fr) * 1982-09-27 1984-04-04 The Dow Chemical Company Procédé de polymérisation en phase fondue pour des polyamides et des polyesteramides thermoplastiques
EP0137205A2 (fr) * 1983-08-12 1985-04-17 Hitachi Chemical Co., Ltd. Procédé de préparation de polymères sous forme de particules
EP0375682A1 (fr) * 1987-08-31 1990-07-04 The Dow Chemical Company Mousse ignifuge composee essentiellement de liaisons amides et imides

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4395531A (en) * 1981-03-14 1983-07-26 Mitsui Toatsu Chemical Incorporated Process for the preparation of polyamide compounds by the reaction of polycarboxylic acids with diisocyanates in the presence of at least one mono-alkali metal salt of dicarboxylic acid
US4477624A (en) * 1981-11-09 1984-10-16 Showa Electric Wire & Cable Co., Ltd. Heat-resistant synthetic resin composition
US4420603A (en) * 1982-09-27 1983-12-13 The Upjohn Company Continuous, solvent-free process for preparing thermoplastic polyamides and polyesteramides
US4562228A (en) * 1984-02-29 1985-12-31 The Upjohn Company Polymer blends
EP0154037A3 (fr) * 1984-02-29 1987-02-04 The Dow Chemical Company Mélanges de polyamides aromatiques-aliphatiques et de modificateur d'impact
US4795795A (en) * 1985-02-20 1989-01-03 Mitsui Toatsu Chemicals, Incorporated Catalytic preparation of polyamide or polyamide-polymide with N,N'-dimethyl alkylene urea solvent
US4612353A (en) * 1985-04-22 1986-09-16 The Dow Chemical Company Polyamide/polyetherimide alloys
US4604210A (en) * 1985-04-25 1986-08-05 The Dow Chemical Company Method for removing cyclic phosphorus contaminants from organic substrates
US4672094A (en) * 1986-01-21 1987-06-09 The Dow Chemical Company Method for increasing the molecular weight of polyamides and polyesteramides
US4722809A (en) * 1986-09-22 1988-02-02 The Dow Chemical Company Flame retarded polyamide compositions
JP2674749B2 (ja) * 1987-05-19 1997-11-12 株式会社クラレ ポリアミドイミドエラストマー
US5260483A (en) * 1988-03-29 1993-11-09 Drexel University Preparation of n-aryl amides from isocyanates
AT392280B (de) * 1989-02-15 1991-02-25 Chemiefaser Lenzing Ag Verfahren zur herstellung von neuen, schwer entflammbaren, thermostabilen homopolyimiden, homopolyimiden, formkoerper und fasern daraus
AT392973B (de) * 1989-07-10 1991-07-25 Chemiefaser Lenzing Ag Verfahren zur herstellung von polyimiden und imiden
GB2283242B (en) * 1993-10-28 1998-01-14 Kobe Steel Europ Ltd Polyimides
US5663234A (en) * 1995-06-15 1997-09-02 The University Of Akron Cationic multiblock thermoplastic elastomers
US7214825B2 (en) * 2003-10-17 2007-05-08 Honeywell International Inc. O-(3-chloropropenyl) hydroxylamine free base
US6946025B2 (en) * 2003-10-22 2005-09-20 Xerox Corporation Process for preparing tetra-amide compounds
CN101820855B (zh) * 2007-10-10 2012-11-07 荷兰联合利华有限公司 处理毛发的方法
US8034806B2 (en) * 2007-11-02 2011-10-11 Vanderbilt University Bicyclic mGluR5 positive allosteric modulators and methods of making and using same
RU2627390C2 (ru) 2012-01-18 2017-08-08 Сурмодикс, Инк. Скользящее покрытие для медицинских устройств с малым количеством микрочастиц
CN104822654B (zh) 2012-10-19 2017-10-20 苏特沃克技术有限公司 丙烯酰胺基交联单体，它们的制备和应用
CA3128509A1 (fr) 2019-02-08 2020-08-13 Lanxess Corporation Systemes d'urethane et d'urethane-uree degradables
EP4178999A1 (fr) 2020-07-09 2023-05-17 Habasit AG Amorce tpo

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1316245A (fr) * 1961-02-27 1963-01-25 Bayer Ag Uréthanes de polyester et procédé pour les préparer
FR2069253A5 (fr) * 1969-11-11 1971-09-03 Bayer Ag
FR2073871A5 (fr) * 1969-12-16 1971-10-01 Bayer Ag
DE1795752A1 (de) * 1968-04-13 1974-08-01 Bayer Ag Verfahren zur herstellung von hochmolekularen polyamid-imiden
FR2284628A1 (fr) * 1974-09-12 1976-04-09 Bayer Ag Procede de production de polycondensats contenant des groupes imide cycliques

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4419274B1 (fr) * 1965-03-30 1969-08-21
US3708458A (en) * 1971-03-16 1973-01-02 Upjohn Co Copolyimides of benzophenone tetracarboxylic acid dianhydride and mixture of diisocyanates
US3755242A (en) * 1972-04-10 1973-08-28 Minnesota Mining & Mfg Polycarbodiimide prepolymers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1316245A (fr) * 1961-02-27 1963-01-25 Bayer Ag Uréthanes de polyester et procédé pour les préparer
DE1795752A1 (de) * 1968-04-13 1974-08-01 Bayer Ag Verfahren zur herstellung von hochmolekularen polyamid-imiden
FR2069253A5 (fr) * 1969-11-11 1971-09-03 Bayer Ag
FR2073871A5 (fr) * 1969-12-16 1971-10-01 Bayer Ag
FR2284628A1 (fr) * 1974-09-12 1976-04-09 Bayer Ag Procede de production de polycondensats contenant des groupes imide cycliques

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
EXBK/ *
EXBK/62 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0104391A2 (fr) * 1982-09-27 1984-04-04 The Dow Chemical Company Procédé de polymérisation en phase fondue pour des polyamides et des polyesteramides thermoplastiques
EP0104391A3 (en) * 1982-09-27 1985-06-05 The Upjohn Company Melt polymerization process for thermoplastic polyamides and polyester amides
EP0137205A2 (fr) * 1983-08-12 1985-04-17 Hitachi Chemical Co., Ltd. Procédé de préparation de polymères sous forme de particules
EP0137205A3 (fr) * 1983-08-12 1986-06-11 Hitachi Chemical Co., Ltd. Procédé de préparation de polymères sous forme de particules
EP0375682A1 (fr) * 1987-08-31 1990-07-04 The Dow Chemical Company Mousse ignifuge composee essentiellement de liaisons amides et imides
EP0375682A4 (en) * 1987-08-31 1991-03-20 The Dow Chemical Company Fire resistant foam composed of predominantly amide and imide linkages

Also Published As

Publication number Publication date
DE2801701A1 (de) 1978-07-27
GB1575669A (en) 1980-09-24
IT1103108B (it) 1985-10-14
FR2378000B1 (fr) 1983-09-09
NL187849B (nl) 1991-09-02
JPS5392703A (en) 1978-08-15
US4156065A (en) 1979-05-22
IT7847541A0 (it) 1978-01-05
DE2801701C2 (de) 1986-09-18
JPS5940142B2 (ja) 1984-09-28
NL7800518A (nl) 1978-07-25
NL187849C (nl) 1992-02-03

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