FR2373503A2 - Cpds. contg. perfluoro-alkyl or perfluoro-alkenyl radicals - prepd. from perfluoro"alkyl halide, metal couple. and reactant, e.g. carbon dioxide - Google Patents
Cpds. contg. perfluoro-alkyl or perfluoro-alkenyl radicals - prepd. from perfluoro"alkyl halide, metal couple. and reactant, e.g. carbon dioxideInfo
- Publication number
- FR2373503A2 FR2373503A2 FR7637240A FR7637240A FR2373503A2 FR 2373503 A2 FR2373503 A2 FR 2373503A2 FR 7637240 A FR7637240 A FR 7637240A FR 7637240 A FR7637240 A FR 7637240A FR 2373503 A2 FR2373503 A2 FR 2373503A2
- Authority
- FR
- France
- Prior art keywords
- perfluoro
- alkyl
- prepd
- cpds
- contg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
Abstract
Prepn. of cpds. contg. a perfluoroalkyl or perfluoroalkenyl gp., esp. derivs. of acids of formula: RFCOOH and RFSO2H, comprises reacting a perfluoro cpd. of formula: RFX (where RF is a 2-12C perfluoroalkyl or perfluoroalkenyl radical and X is Cl, Br or I), with an appropriate reactant, esp. CO2 and SO2, in the presence of a dispersion in a sulphoxide solvent of a metallic couple cpd. of a metal M, selected from Group 1b,2a,2b or 3a metals and a metal M2 having a lower electrochemical potential than (and which deposits on) metal M. Acids RF COOH and RFSO3H (prepd. from RFSO2H) are surfactants and also intermediates to textile, paper and leather treating agents and other surfactants.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7637240A FR2373503A2 (en) | 1976-12-10 | 1976-12-10 | Cpds. contg. perfluoro-alkyl or perfluoro-alkenyl radicals - prepd. from perfluoro"alkyl halide, metal couple. and reactant, e.g. carbon dioxide |
IT67412/77A IT1117060B (en) | 1976-03-05 | 1977-02-24 | PROCEDURE FOR THE PREPARATION OF PERFLUORATED COMPOUNDS, PARTICULARLY OF PERFLUOROCARBOXYLIC AND PERFLUOROALKAN SULPHINIC ACIDS |
US05/772,107 US4098806A (en) | 1976-03-05 | 1977-02-25 | Process for functionalizing perfluorohalogenoalkanes |
GB8640/77A GB1539300A (en) | 1976-03-05 | 1977-03-01 | Process for the preparation of perfluorinated compounds |
DE2708751A DE2708751C3 (en) | 1976-03-05 | 1977-03-01 | Process for increasing the reactivity of perfluorohaloalkanes |
CH273277A CH620673A5 (en) | 1976-03-05 | 1977-03-04 | |
NLAANVRAGE7702368,A NL186082C (en) | 1976-03-05 | 1977-03-04 | PROCESS FOR INCREASING THE REACTIVITY OF PERFLUORALOGENE ALKANES. |
JP52022901A JPS606332B2 (en) | 1976-03-05 | 1977-03-04 | Method for producing a carboxylic acid or sulfinic acid derivative having a perfluoroalkyl group |
CA273,245A CA1084524A (en) | 1976-03-05 | 1977-03-04 | Process for the functionalization of perfluorated radicals |
CH45880A CH620413A5 (en) | 1976-03-05 | 1980-01-21 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7637240A FR2373503A2 (en) | 1976-12-10 | 1976-12-10 | Cpds. contg. perfluoro-alkyl or perfluoro-alkenyl radicals - prepd. from perfluoro"alkyl halide, metal couple. and reactant, e.g. carbon dioxide |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2373503A2 true FR2373503A2 (en) | 1978-07-07 |
FR2373503B2 FR2373503B2 (en) | 1979-10-05 |
Family
ID=9180900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7637240A Granted FR2373503A2 (en) | 1976-03-05 | 1976-12-10 | Cpds. contg. perfluoro-alkyl or perfluoro-alkenyl radicals - prepd. from perfluoro"alkyl halide, metal couple. and reactant, e.g. carbon dioxide |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2373503A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2521987A1 (en) * | 1982-02-23 | 1983-08-26 | Ugine Kuhlmann | PROCESS FOR THE PREPARATION OF POLYFLUORINATED ALCOHOLS OF THE RFCH2CH2OH TYPE |
US4478760A (en) * | 1980-04-18 | 1984-10-23 | Produits Chimiques Ugine Kuhlmann | Process for the preparation of fluorinated products |
-
1976
- 1976-12-10 FR FR7637240A patent/FR2373503A2/en active Granted
Non-Patent Citations (1)
Title |
---|
NEANT * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4478760A (en) * | 1980-04-18 | 1984-10-23 | Produits Chimiques Ugine Kuhlmann | Process for the preparation of fluorinated products |
FR2521987A1 (en) * | 1982-02-23 | 1983-08-26 | Ugine Kuhlmann | PROCESS FOR THE PREPARATION OF POLYFLUORINATED ALCOHOLS OF THE RFCH2CH2OH TYPE |
EP0089859A1 (en) * | 1982-02-23 | 1983-09-28 | Elf Atochem S.A. | Process for the preparation of 2-perfluoroalkyl ethanols |
Also Published As
Publication number | Publication date |
---|---|
FR2373503B2 (en) | 1979-10-05 |
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