FR2355860A1 - Remplissage granulaire pour chromatographie en phase liquide - Google Patents

Remplissage granulaire pour chromatographie en phase liquide

Info

Publication number
FR2355860A1
FR2355860A1 FR7719676A FR7719676A FR2355860A1 FR 2355860 A1 FR2355860 A1 FR 2355860A1 FR 7719676 A FR7719676 A FR 7719676A FR 7719676 A FR7719676 A FR 7719676A FR 2355860 A1 FR2355860 A1 FR 2355860A1
Authority
FR
France
Prior art keywords
component
granular filling
mole
epoxy groups
liquid phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7719676A
Other languages
English (en)
Other versions
FR2355860B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Publication of FR2355860A1 publication Critical patent/FR2355860A1/fr
Application granted granted Critical
Publication of FR2355860B1 publication Critical patent/FR2355860B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
    • B01J20/267—Cross-linked polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Epoxy Resins (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

L'invention concerne un remplissage granulaire pour chromatographie en phase liquide. Le procédé selon l'invention est caractérisé par le fait qu'on soumet : a. 10 à 90 moles % d'un ester ou un éther glicidylique monovinylique; et b. 90 à 10 moles % d'un ester divinylique d'un alkylène-glycol à une polymérisation en suspension aqueuse en présence d'un diluant organique inerte insoluble dans l'eau et capable de dissoudre des constituants a et b de manière à produire des particules d'un copolymère poreux du type gel, dans lequel le constituant a est réticulé avec le constituant b et contenant dans sa molécule des groupes époxy attribuables au constituant a, ou on fait réagir le copolymère obtenu avec un composé modificateur ayant un groupe hydrophile, oléophile ou échangeur d'ions pour modifier les groupes epoxy par décyclisation.
FR7719676A 1976-06-25 1977-06-27 Remplissage granulaire pour chromatographie en phase liquide Granted FR2355860A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP51074401A JPS5858026B2 (ja) 1976-06-25 1976-06-25 クロマトグラフイ−用充填剤及びその製造法

Publications (2)

Publication Number Publication Date
FR2355860A1 true FR2355860A1 (fr) 1978-01-20
FR2355860B1 FR2355860B1 (fr) 1980-03-14

Family

ID=13546122

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7719676A Granted FR2355860A1 (fr) 1976-06-25 1977-06-27 Remplissage granulaire pour chromatographie en phase liquide

Country Status (5)

Country Link
US (1) US4118347A (fr)
JP (1) JPS5858026B2 (fr)
DE (1) DE2728146C2 (fr)
FR (1) FR2355860A1 (fr)
GB (1) GB1566647A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2377826A1 (fr) * 1977-01-19 1978-08-18 Ceskoslovenska Akademie Ved Adsorbant polymere polaire a base d'ester de glycidyle pour la chromatographie en phase gazeuse et liquide
EP0021817A1 (fr) * 1979-06-22 1981-01-07 Sekisui Kagaku Kogyo Kabushiki Kaisha Remplissage pour chromatographie en phase liquide, procédé pour séparer des substances solubles dans l'eau à l'aide de ce remplissage et utilisation de ce remplissage dans la séparation de substances biochimiques solubles dans l'eau
FR2468906A1 (fr) * 1979-11-01 1981-05-08 Asahi Chemical Ind Materiau hydrophile de garnissage pour chromatographie
EP0282177A2 (fr) * 1987-03-09 1988-09-14 Dionex Corporation Résine échangeuse d'ions comportant une couche extérieure de résine acrylique
WO2000075195A1 (fr) * 1999-06-06 2000-12-14 Amersham Pharmacia Biotech Ab Procede de modification de surface, nouvelle matrice de support et utilisation de ladite matrice

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54160300A (en) * 1978-06-08 1979-12-18 Toyo Soda Mfg Co Ltd Hydrophilic separating carrier and making method thereof
US4468330A (en) * 1981-04-27 1984-08-28 Sekisui Kagaku Kogyo Kabushiki Kaisha Filler for liquid chromatography useful for separating a hemoglobin variant in blood
JPS6057760A (ja) * 1983-09-08 1985-04-03 Toshiba Corp ファクシミリ装置
JPH0750087B2 (ja) * 1984-12-14 1995-05-31 日本エクスラン工業株式会社 液体クロマト用充填剤の製造法
EP0198395A3 (fr) * 1985-04-09 1989-04-12 Mitsubishi Kasei Corporation Agent de séparation pour solutions mixtes
GB2184732B (en) * 1985-12-26 1990-07-11 Showa Denko Kk Active support substance and adsorbent for chromatography
JPH07104447B2 (ja) * 1987-05-28 1995-11-13 東京応化工業株式会社 カラーフィルター形成用有機ガラス組成物およびカラーフィルター形成用有機ガラス層を形成する方法
DD278482A3 (de) * 1988-06-22 1990-05-09 Univ Berlin Humboldt Vorrichtung und verfahren zur chromatographischen trennung
JP2559526B2 (ja) * 1989-09-29 1996-12-04 積水化学工業株式会社 液体クロマトグラフィー用充填剤の製造方法
DE19816910A1 (de) * 1998-04-16 1999-10-21 Pasquart Ag Chur Gel-bildendes Polymer und Verfahren zu seiner Herstellung
JP2001324487A (ja) * 2000-03-09 2001-11-22 Showa Denko Kk 逆相液体クロマトグラフィー用充填剤およびその製造方法
US6533939B2 (en) * 2000-03-09 2003-03-18 Showa Denko Kabushiki Kaisha Packing agent for reversed phase liquid chromatography and production process thereof
JP2004099790A (ja) * 2002-09-11 2004-04-02 Showa Denko Kk 改質されたポリマー粒子、クロマトグラフィー用充填剤、それらの製造方法及びクロマトグラフィー用カラム
MY144940A (en) * 2005-01-25 2011-11-30 Avantor Performance Mat Inc Chromatographic media
CN101193928B (zh) * 2005-06-09 2011-07-20 东曹株式会社 亲水性优异的新型填充剂及其制备方法
WO2007063701A1 (fr) * 2005-12-02 2007-06-07 Sekisui Chemical Co., Ltd. Microparticule polymère hydrophile, charge de remplissage pour la chromatographie liquide par échange d’ions, et procédé de production de la charge de remplissage pour chromatographie liquide par échange d’ions
JP5250985B2 (ja) * 2007-03-19 2013-07-31 東ソー株式会社 充填床用新規充填剤及びその用途
JP4662967B2 (ja) * 2007-09-13 2011-03-30 パンパシフィック・カッパー株式会社 電解液中に含まれるニカワの濃度分析方法
CN105190305A (zh) 2013-03-29 2015-12-23 东曹株式会社 液相色谱用阳离子交换体、其制造方法及其用途
US20210024563A1 (en) 2018-03-27 2021-01-28 Mitsubishi Chemical Aqua Solutions Co., Ltd. Method for separating steviol glycoside, method for producing rebaudioside a, and device for separating steviol glycoside
CN112334490B (zh) 2018-06-20 2024-02-13 Jsr株式会社 使用变异vhh抗体的亲和载体
US11857949B2 (en) 2021-06-28 2024-01-02 Resonac Corporation Packing material and method for producing the same, and column for size exclusion chromatography

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2630429A (en) * 1951-10-05 1953-03-03 Rohm & Haas Preparation of weakly basic anion-exchange resins
US3228920A (en) * 1960-05-12 1966-01-11 Metal Recovery Systems Chelating resins and method of preparation
US3312677A (en) * 1963-10-29 1967-04-04 Thiokol Chemical Corp Interpolymers of lower alkyl acrylate esters, olefin-epoxide monomers and polyene monomers
US3414550A (en) * 1965-05-13 1968-12-03 Alelio D Chelating resins from epoxyalkyl acrylate polymers
FR1483946A (fr) * 1966-04-28 1967-06-09 Dia Prosim Procédé de préparation de résines macroporeuses, et applications de celles-ci à l'obtention d'échangeurs d'ions
US4031037A (en) * 1973-08-29 1977-06-21 Jaroslav Kalal Three-dimensional polymeric gel materials containing phosphoric acid residues capable of dissociation and a method for their preparation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2377826A1 (fr) * 1977-01-19 1978-08-18 Ceskoslovenska Akademie Ved Adsorbant polymere polaire a base d'ester de glycidyle pour la chromatographie en phase gazeuse et liquide
EP0021817A1 (fr) * 1979-06-22 1981-01-07 Sekisui Kagaku Kogyo Kabushiki Kaisha Remplissage pour chromatographie en phase liquide, procédé pour séparer des substances solubles dans l'eau à l'aide de ce remplissage et utilisation de ce remplissage dans la séparation de substances biochimiques solubles dans l'eau
FR2468906A1 (fr) * 1979-11-01 1981-05-08 Asahi Chemical Ind Materiau hydrophile de garnissage pour chromatographie
EP0282177A2 (fr) * 1987-03-09 1988-09-14 Dionex Corporation Résine échangeuse d'ions comportant une couche extérieure de résine acrylique
EP0282177A3 (fr) * 1987-03-09 1989-01-18 Dionex Corporation Résine échangeuse d'ions comportant une couche extérieure de résine acrylique
WO2000075195A1 (fr) * 1999-06-06 2000-12-14 Amersham Pharmacia Biotech Ab Procede de modification de surface, nouvelle matrice de support et utilisation de ladite matrice
US7282237B2 (en) 1999-06-06 2007-10-16 Ge Healthcare Bio-Sciences Ab Method for surface modification, a novel support matrix and the use of the matrix

Also Published As

Publication number Publication date
JPS5858026B2 (ja) 1983-12-23
JPS531087A (en) 1978-01-07
DE2728146A1 (de) 1977-12-29
GB1566647A (en) 1980-05-08
US4118347A (en) 1978-10-03
FR2355860B1 (fr) 1980-03-14
DE2728146C2 (de) 1984-11-15

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