FR2342247A1 - Chlorine dioxide prodn. from sodium chlorate - by reaction with hydrochloric acid, in satd. salt soln. (SW 19.9.77) - Google Patents

Chlorine dioxide prodn. from sodium chlorate - by reaction with hydrochloric acid, in satd. salt soln. (SW 19.9.77)

Info

Publication number
FR2342247A1
FR2342247A1 FR7705305A FR7705305A FR2342247A1 FR 2342247 A1 FR2342247 A1 FR 2342247A1 FR 7705305 A FR7705305 A FR 7705305A FR 7705305 A FR7705305 A FR 7705305A FR 2342247 A1 FR2342247 A1 FR 2342247A1
Authority
FR
France
Prior art keywords
satd
prodn
reaction
sodium chlorate
hydrochloric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7705305A
Other languages
French (fr)
Other versions
FR2342247B1 (en
Inventor
William Howard Rapson
Maurice Fredette
Norman Meyers
Richard Swindells
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Erco Industries Ltd
Original Assignee
Erco Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Erco Industries Ltd filed Critical Erco Industries Ltd
Publication of FR2342247A1 publication Critical patent/FR2342247A1/en
Application granted granted Critical
Publication of FR2342247B1 publication Critical patent/FR2342247B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02Oxides of chlorine
    • C01B11/022Chlorine dioxide (ClO2)
    • C01B11/023Preparation from chlorites or chlorates
    • C01B11/025Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

ClO2 is prepd. by reduction of sodium chlorate with HCl in aq. medium, at the b. pt. of the mixt. at a pressure below atmospheric. The reaction mixt. is satd. with NaCl at a H ion concn. of 0.05-0.3 V, at 30-85 degrees C and at a pressure of 20-400mgHg. When NaCl3 and HCl are reacted together two processes can occur simultaneously, NAClO3+2HCl right arrow ClO2 + 1/2HCl2 + H2O + NaCl (1) and NaClO3 + 6HCl right arrow 3Cl2+3H2O+NaCl (2). The above conditions favour the prodn. of ClO2 by (1) rather than (2).
FR7705305A 1976-02-24 1977-02-23 Chlorine dioxide prodn. from sodium chlorate - by reaction with hydrochloric acid, in satd. salt soln. (SW 19.9.77) Granted FR2342247A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB718876 1976-02-24
GB1112476 1976-03-19
GB3515976 1976-08-24

Publications (2)

Publication Number Publication Date
FR2342247A1 true FR2342247A1 (en) 1977-09-23
FR2342247B1 FR2342247B1 (en) 1979-03-23

Family

ID=27254979

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7705305A Granted FR2342247A1 (en) 1976-02-24 1977-02-23 Chlorine dioxide prodn. from sodium chlorate - by reaction with hydrochloric acid, in satd. salt soln. (SW 19.9.77)

Country Status (10)

Country Link
JP (1) JPS5912601B2 (en)
AR (1) AR216067A1 (en)
AT (1) AT388155B (en)
BR (1) BR7701131A (en)
ES (1) ES456203A1 (en)
FI (1) FI65606C (en)
FR (1) FR2342247A1 (en)
NZ (1) NZ183379A (en)
OA (1) OA05580A (en)
SE (1) SE455089B (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1054456A (en) * 1963-10-10
US3563702A (en) * 1968-03-05 1971-02-16 Hooker Chemical Corp Production of chlorine dioxide
JPS4859095A (en) * 1971-11-22 1973-08-18

Also Published As

Publication number Publication date
FI770601A (en) 1977-08-25
ATA125377A (en) 1988-10-15
BR7701131A (en) 1977-12-06
JPS5912601B2 (en) 1984-03-24
FR2342247B1 (en) 1979-03-23
FI65606C (en) 1984-06-11
AT388155B (en) 1989-05-10
SE455089B (en) 1988-06-20
NZ183379A (en) 1979-03-28
ES456203A1 (en) 1978-01-16
OA05580A (en) 1981-04-30
AR216067A1 (en) 1979-11-30
FI65606B (en) 1984-02-29
SE7701962L (en) 1977-08-25
JPS52125494A (en) 1977-10-21

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Legal Events

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