FR2131895A1 - 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane - Google Patents
1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethaneInfo
- Publication number
- FR2131895A1 FR2131895A1 FR7111552A FR7111552A FR2131895A1 FR 2131895 A1 FR2131895 A1 FR 2131895A1 FR 7111552 A FR7111552 A FR 7111552A FR 7111552 A FR7111552 A FR 7111552A FR 2131895 A1 FR2131895 A1 FR 2131895A1
- Authority
- FR
- France
- Prior art keywords
- dichlorethane
- trichlorethane
- degrees
- reaction
- obtd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/04—Chloro-alkenes
- C07C21/073—Dichloro-alkenes
- C07C21/08—Vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
- C07C19/043—Chloroethanes
- C07C19/05—Trichloroethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Selective chlorination of dichlorethane-1,2 to trichlorethane-1, 1, 2 is obtd. by reacting a mixt. contg. dichlorethane-1, 2 and Cl2, using as starting material, the fraction of residues from the cracking of dichlorethane-1, 2 to give vinyl chloride, which contain is not >50% of dichlorethane-1, 2. The reaction is carried out at 50 degrees-150 degrees C, pref. 80 degrees-120 degrees C. The transformation rate is 75%, pref. ca 50%, of the dichlorethane introduced, and the reaction is carried out so that the trichlorethane-1, 1,2 obtd. escapes from the reaction media in gaseous form, after which the mixture obtd. is fractionated, the dichlorethane and lighter fractions being recycled into the chlorination reaction. The trichlorethane may be dehydrochlorinated to vinylidene chloride for use in polymers.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7111552A FR2131895A1 (en) | 1971-04-01 | 1971-04-01 | 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7111552A FR2131895A1 (en) | 1971-04-01 | 1971-04-01 | 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2131895A1 true FR2131895A1 (en) | 1972-11-17 |
FR2131895B1 FR2131895B1 (en) | 1973-11-30 |
Family
ID=9074595
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7111552A Granted FR2131895A1 (en) | 1971-04-01 | 1971-04-01 | 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2131895A1 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1399526A (en) * | 1963-07-10 | 1965-05-14 | Pittsburgh Plate Glass Co | Improved process for preparing 1, 1, 2-trichloroethane |
-
1971
- 1971-04-01 FR FR7111552A patent/FR2131895A1/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1399526A (en) * | 1963-07-10 | 1965-05-14 | Pittsburgh Plate Glass Co | Improved process for preparing 1, 1, 2-trichloroethane |
Also Published As
Publication number | Publication date |
---|---|
FR2131895B1 (en) | 1973-11-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |