FR2131895A1 - 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane - Google Patents

1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane

Info

Publication number
FR2131895A1
FR2131895A1 FR7111552A FR7111552A FR2131895A1 FR 2131895 A1 FR2131895 A1 FR 2131895A1 FR 7111552 A FR7111552 A FR 7111552A FR 7111552 A FR7111552 A FR 7111552A FR 2131895 A1 FR2131895 A1 FR 2131895A1
Authority
FR
France
Prior art keywords
dichlorethane
trichlorethane
degrees
reaction
obtd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7111552A
Other languages
French (fr)
Other versions
FR2131895B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DEVINTER SA
Original Assignee
DEVINTER SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DEVINTER SA filed Critical DEVINTER SA
Priority to FR7111552A priority Critical patent/FR2131895A1/en
Publication of FR2131895A1 publication Critical patent/FR2131895A1/en
Application granted granted Critical
Publication of FR2131895B1 publication Critical patent/FR2131895B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/04Chloro-alkenes
    • C07C21/073Dichloro-alkenes
    • C07C21/08Vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00Acyclic saturated compounds containing halogen atoms
    • C07C19/01Acyclic saturated compounds containing halogen atoms containing chlorine
    • C07C19/043Chloroethanes
    • C07C19/05Trichloroethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Selective chlorination of dichlorethane-1,2 to trichlorethane-1, 1, 2 is obtd. by reacting a mixt. contg. dichlorethane-1, 2 and Cl2, using as starting material, the fraction of residues from the cracking of dichlorethane-1, 2 to give vinyl chloride, which contain is not >50% of dichlorethane-1, 2. The reaction is carried out at 50 degrees-150 degrees C, pref. 80 degrees-120 degrees C. The transformation rate is 75%, pref. ca 50%, of the dichlorethane introduced, and the reaction is carried out so that the trichlorethane-1, 1,2 obtd. escapes from the reaction media in gaseous form, after which the mixture obtd. is fractionated, the dichlorethane and lighter fractions being recycled into the chlorination reaction. The trichlorethane may be dehydrochlorinated to vinylidene chloride for use in polymers.
FR7111552A 1971-04-01 1971-04-01 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane Granted FR2131895A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7111552A FR2131895A1 (en) 1971-04-01 1971-04-01 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7111552A FR2131895A1 (en) 1971-04-01 1971-04-01 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane

Publications (2)

Publication Number Publication Date
FR2131895A1 true FR2131895A1 (en) 1972-11-17
FR2131895B1 FR2131895B1 (en) 1973-11-30

Family

ID=9074595

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7111552A Granted FR2131895A1 (en) 1971-04-01 1971-04-01 1,1,2-trichlorethane prepn - by selective chlorination of 1,2-dichlorethane

Country Status (1)

Country Link
FR (1) FR2131895A1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1399526A (en) * 1963-07-10 1965-05-14 Pittsburgh Plate Glass Co Improved process for preparing 1, 1, 2-trichloroethane

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1399526A (en) * 1963-07-10 1965-05-14 Pittsburgh Plate Glass Co Improved process for preparing 1, 1, 2-trichloroethane

Also Published As

Publication number Publication date
FR2131895B1 (en) 1973-11-30

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Legal Events

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