FR2113312A5 - N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether - Google Patents

N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether

Info

Publication number
FR2113312A5
FR2113312A5 FR7138587A FR7138587A FR2113312A5 FR 2113312 A5 FR2113312 A5 FR 2113312A5 FR 7138587 A FR7138587 A FR 7138587A FR 7138587 A FR7138587 A FR 7138587A FR 2113312 A5 FR2113312 A5 FR 2113312A5
Authority
FR
France
Prior art keywords
acetone
isopropylaniline
aniline
ether
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7138587A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eszakmagyarorszagi Vegyimuevek
Original Assignee
Eszakmagyarorszagi Vegyimuevek
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eszakmagyarorszagi Vegyimuevek filed Critical Eszakmagyarorszagi Vegyimuevek
Application granted granted Critical
Publication of FR2113312A5 publication Critical patent/FR2113312A5/en
Priority to BE150238A priority Critical patent/BE821884Q/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45Monoamines
    • C07C211/46Aniline
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

N-Isopropylaniline, which is of use as an intermediate (esp. for plant-protection agents) and as a solvent, is prepd. by alkylating aniline with acetone in H2 atmos. over a Pt catalyst and in the presence of 0.01-10 (pref. 0.02-5) wt.% (based on the reaction mixture) of an additive consisting of one or more alcohols and/or ethers. The additive limits undersired hydrogenation of the acetone to isopropanol.
FR7138587A 1970-10-31 1971-10-27 N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether Expired FR2113312A5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BE150238A BE821884Q (en) 1971-10-27 1974-11-05 N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
HUKI000633 1970-10-31

Publications (1)

Publication Number Publication Date
FR2113312A5 true FR2113312A5 (en) 1972-06-23

Family

ID=10997804

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7138587A Expired FR2113312A5 (en) 1970-10-31 1971-10-27 N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether

Country Status (9)

Country Link
AT (1) AT322533B (en)
BG (1) BG20555A3 (en)
CH (1) CH557329A (en)
CS (1) CS177069B2 (en)
DE (1) DE2153792C3 (en)
EG (1) EG10648A (en)
FR (1) FR2113312A5 (en)
PL (1) PL74208B1 (en)
RO (1) RO76229A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4304939A (en) * 1978-11-02 1981-12-08 Uop Inc. Preparation of N-phenyl-N-alkylphenylenediamines
DE2902172C2 (en) * 1979-01-20 1984-05-10 UOP Inc., 60016 Des Plaines, Ill. Process for the preparation of an N, N'-dialkylphenylenediamine

Also Published As

Publication number Publication date
DE2153792A1 (en) 1972-05-10
PL74208B1 (en) 1974-10-30
SU438178A3 (en) 1974-07-30
EG10648A (en) 1976-04-30
RO76229A (en) 1981-02-28
CH557329A (en) 1974-12-31
DE2153792B2 (en) 1980-07-31
BG20555A3 (en) 1975-12-05
DE2153792C3 (en) 1981-04-16
CS177069B2 (en) 1977-07-29
AT322533B (en) 1975-05-26

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Legal Events

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ST Notification of lapse