FR2113312A5 - N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether - Google Patents
N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or etherInfo
- Publication number
- FR2113312A5 FR2113312A5 FR7138587A FR7138587A FR2113312A5 FR 2113312 A5 FR2113312 A5 FR 2113312A5 FR 7138587 A FR7138587 A FR 7138587A FR 7138587 A FR7138587 A FR 7138587A FR 2113312 A5 FR2113312 A5 FR 2113312A5
- Authority
- FR
- France
- Prior art keywords
- acetone
- isopropylaniline
- aniline
- ether
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/45—Monoamines
- C07C211/46—Aniline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
- C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
N-Isopropylaniline, which is of use as an intermediate (esp. for plant-protection agents) and as a solvent, is prepd. by alkylating aniline with acetone in H2 atmos. over a Pt catalyst and in the presence of 0.01-10 (pref. 0.02-5) wt.% (based on the reaction mixture) of an additive consisting of one or more alcohols and/or ethers. The additive limits undersired hydrogenation of the acetone to isopropanol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE150238A BE821884Q (en) | 1971-10-27 | 1974-11-05 | N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HUKI000633 | 1970-10-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2113312A5 true FR2113312A5 (en) | 1972-06-23 |
Family
ID=10997804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7138587A Expired FR2113312A5 (en) | 1970-10-31 | 1971-10-27 | N-isopropylaniline by reductive alkylation of aniline - with acetone in presence of platinum catalyst, alcohol and/or ether |
Country Status (9)
Country | Link |
---|---|
AT (1) | AT322533B (en) |
BG (1) | BG20555A3 (en) |
CH (1) | CH557329A (en) |
CS (1) | CS177069B2 (en) |
DE (1) | DE2153792C3 (en) |
EG (1) | EG10648A (en) |
FR (1) | FR2113312A5 (en) |
PL (1) | PL74208B1 (en) |
RO (1) | RO76229A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4304939A (en) * | 1978-11-02 | 1981-12-08 | Uop Inc. | Preparation of N-phenyl-N-alkylphenylenediamines |
DE2902172C2 (en) * | 1979-01-20 | 1984-05-10 | UOP Inc., 60016 Des Plaines, Ill. | Process for the preparation of an N, N'-dialkylphenylenediamine |
-
1971
- 1971-10-27 FR FR7138587A patent/FR2113312A5/en not_active Expired
- 1971-10-28 EG EG476/71A patent/EG10648A/en active
- 1971-10-28 DE DE2153792A patent/DE2153792C3/en not_active Expired
- 1971-10-29 AT AT933971A patent/AT322533B/en not_active IP Right Cessation
- 1971-10-29 PL PL1971151288A patent/PL74208B1/en unknown
- 1971-10-29 CH CH1582571A patent/CH557329A/en not_active IP Right Cessation
- 1971-10-30 RO RO7168613A patent/RO76229A/en unknown
- 1971-10-30 BG BG18899A patent/BG20555A3/xx unknown
- 1971-11-01 CS CS7646A patent/CS177069B2/cs unknown
Also Published As
Publication number | Publication date |
---|---|
DE2153792A1 (en) | 1972-05-10 |
PL74208B1 (en) | 1974-10-30 |
SU438178A3 (en) | 1974-07-30 |
EG10648A (en) | 1976-04-30 |
RO76229A (en) | 1981-02-28 |
CH557329A (en) | 1974-12-31 |
DE2153792B2 (en) | 1980-07-31 |
BG20555A3 (en) | 1975-12-05 |
DE2153792C3 (en) | 1981-04-16 |
CS177069B2 (en) | 1977-07-29 |
AT322533B (en) | 1975-05-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |