GB960046A - Method of making haloarylamines - Google Patents

Method of making haloarylamines

Info

Publication number
GB960046A
GB960046A GB24640/62A GB2464062A GB960046A GB 960046 A GB960046 A GB 960046A GB 24640/62 A GB24640/62 A GB 24640/62A GB 2464062 A GB2464062 A GB 2464062A GB 960046 A GB960046 A GB 960046A
Authority
GB
United Kingdom
Prior art keywords
haloarylamines
prepared
calcium
catalyst
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24640/62A
Inventor
Andrew Joseph Dietzler
Theodore Rolland Keil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB24640/62A priority Critical patent/GB960046A/en
Publication of GB960046A publication Critical patent/GB960046A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C07C209/365—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst by reduction with preservation of halogen-atoms in compounds containing nitro groups and halogen atoms bound to the same carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Haloarylamines are prepared by hydrogenating halonitroaromatic compounds in the presence of a nickel or rhodium catalyst activated by a catalyst promotor consisting of magnesium or calcium hydroxide, calcium or sodium carbonate, calcium or sodium acetate or mixtures thereof. The reaction may be carried out at from 20 to 100 DEG C. and at pressures up to 30 atmospheres in an inert solvent. The starting material may contain besides halo and nitro other substituents such as alkyl, phenly, substituted phenyl, carboxyl and hydroxyl groups. Lists of suitable reactants and of haloarylamines which may be prepared are given. In examples m-bromoaniline and 4-bromo-3-amino biphenyl are prepared using, as catalyst, Raney nickel or rhodium, both catalysts being supported on alumina and promoted by calcium hydroxide.
GB24640/62A 1962-06-27 1962-06-27 Method of making haloarylamines Expired GB960046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB24640/62A GB960046A (en) 1962-06-27 1962-06-27 Method of making haloarylamines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB24640/62A GB960046A (en) 1962-06-27 1962-06-27 Method of making haloarylamines

Publications (1)

Publication Number Publication Date
GB960046A true GB960046A (en) 1964-06-10

Family

ID=10214914

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24640/62A Expired GB960046A (en) 1962-06-27 1962-06-27 Method of making haloarylamines

Country Status (1)

Country Link
GB (1) GB960046A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2036313A1 (en) * 1970-07-22 1972-02-03 Farbenfabriken Bayer Ag, 5090 Leverkusen Process for the preparation of halogen-substituted aromatic amines
US4140719A (en) * 1977-10-31 1979-02-20 Merck & Co., Inc. Solid-liquid phase transfer catalysis improved method of preparing 2,4-difluoroaniline
US4294988A (en) * 1977-10-31 1981-10-13 Merck & Co., Inc. Method of preparing 2,4-difluoroaniline

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2036313A1 (en) * 1970-07-22 1972-02-03 Farbenfabriken Bayer Ag, 5090 Leverkusen Process for the preparation of halogen-substituted aromatic amines
US4140719A (en) * 1977-10-31 1979-02-20 Merck & Co., Inc. Solid-liquid phase transfer catalysis improved method of preparing 2,4-difluoroaniline
US4294988A (en) * 1977-10-31 1981-10-13 Merck & Co., Inc. Method of preparing 2,4-difluoroaniline

Similar Documents

Publication Publication Date Title
ES448262A1 (en) Process for the preparation of polycarbonates containing aliphatically bound hydroxyl end groups
GB959507A (en) Catalytic hydrogenation of nitrophenol
GB960046A (en) Method of making haloarylamines
GB1092157A (en) Process for the manufacture of urethanes
GB1025436A (en) New process for preparing isocyanates
GB1086639A (en) Production of cyclododecene
GB1009024A (en) Process for preparing aminophenols
JPS5227704A (en) Process for selective hydrogenation of compounds containing acetylenic unsaturated bonds
ES431044A1 (en) A procedure for the production of a foam of rigid structure. (Machine-translation by Google Translate, not legally binding)
ES391281A1 (en) Process for the manufacture of polyesters and polyurethane foams
ES438734A1 (en) Process for the preparation of acetoxybutanols
ES433483A1 (en) Process for the production of neohesperidine dihydrochalcone
ES415184A1 (en) 2,5-disubstituted benzoic acids
JPS5225704A (en) Process for preparation of glycols
ES320172A1 (en) Catalytic procedure for the preparation of flexible cellular polyurethane foams. (Machine-translation by Google Translate, not legally binding)
ES215163A1 (en) A procedure for preparing 14-hydroxydehydromorphinone (Machine-translation by Google Translate, not legally binding)
ES410140A1 (en) A procedure for preparing 2- (6-metoxy-2-nafthy) -propionic acid. (Machine-translation by Google Translate, not legally binding)
JPS5273816A (en) Hydrogenation of diacetoxybutene
ES348745A3 (en) A procedure for the preparation of 4,4-metilendi (ciclohexilamina). (Machine-translation by Google Translate, not legally binding)
ES384885A1 (en) Procedure for the manufacture of hezametilendiamina (Machine-translation by Google Translate, not legally binding)
ES434844A1 (en) Production of ethylphenols
ES321552A3 (en) Procedure for the preparation of a 6-desoxitetraciclina. (Machine-translation by Google Translate, not legally binding)
GB596303A (en) Improvements in or relating to the production of nitro olefines
AU273188B2 (en) Process for producing polyurethane froma reaction product, a polyol crosslinking agent, anda catalyst
ES396959A1 (en) Procedure for obtaining a new derivative of p-chlorofenoxy-isobutirico acid. (Machine-translation by Google Translate, not legally binding)