FI96223C - Komposition, som är användbar i insmörjningmedel och funktionella vätskor - Google Patents

Komposition, som är användbar i insmörjningmedel och funktionella vätskor Download PDF

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Publication number
FI96223C
FI96223C FI893258A FI893258A FI96223C FI 96223 C FI96223 C FI 96223C FI 893258 A FI893258 A FI 893258A FI 893258 A FI893258 A FI 893258A FI 96223 C FI96223 C FI 96223C
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FI
Finland
Prior art keywords
group
acid
groups
sulfur
carbon atoms
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FI893258A
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English (en)
Finnish (fi)
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FI893258A (sv
FI96223B (sv
FI893258A0 (sv
Inventor
Paul E Adams
James Noel Vinci
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Lubrizol Corp
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Publication of FI893258A0 publication Critical patent/FI893258A0/sv
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Publication of FI96223C publication Critical patent/FI96223C/sv

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    • C—CHEMISTRY; METALLURGY
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    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/42—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms polycarboxylic
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
    • C10M129/50—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring monocarboxylic
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    • C10M129/86—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
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Claims (8)

1. Komposition, som är användbar i insmörjningmedel och funktionella vätskor, kännetecknad dä-5 rav, att den omfattar (A) minst en sur organisk förening, minst ett neutralt eller basiskt metallsalt eller ett borhaltigt, neutralt eller basiskt metallsalt, varvid den sura or-ganiska föreningen är vald ur en eller flera karboxylsy- 10 ror, svavelhaltiga syror, fenoler eller en blandning av tvä eller flera av dessa, varvid metallen i nämnda sait är jordalkalimetall, zink, koppar, aluminium eller en blandning av tvä eller flera av nämnda metaller; (B) minst en metalldeaktivator, som är bensotriazol 15 substituerad med alkyl, aryl, alkaryl eller bensotriazol substituerad med arylalkyl ; bensotriazol substituerad med en hydroxi-, alkoxi-, halogen-, nitro-, karboxi- eller karbalkoxigrupp ; en reaktionsprodukt av minst en av nämnda bensotriazoler och aminer; en reaktionsprodukt av 20 minst en av nämnda bensotriazoler och minst ett kvävehal-tigt askfritt dispergeringsmedel; eller en blandning av tvä eller flera av dessa; och (C) minst en förening, vilken valts bland (C-l) en fosforhaltig amid med formeln 25 x3 R3 R5 χ5 r7 a\j_χ4___J^ J_rq R2!*2)^ R4 R6n <XIII>
30 L. L· J -I var i X1, X2, X3, X4 och X5 betecknar oberoende av varandra syre eller svavel; R1, R2 betecknar oberoende av varandra en hydrokar-35 bylgrupp; 96223 102 R3, R4, R5, R6 och R7 betecknar oberoende av varandra väte, halogen eller en hydrokarbylgrupp; a och b betecknar oberoende av varandra talet 0 eller 1; 5 n är 0 eller 1; n' är 1, 2 eller 3; förutsatt att (1) dä n' är 1, R8 är väte, -R, -RÖH, -R0R, -RSR eller R -RN-R; 10 (2) dä n* är 2, R8 är en bindningsgrupp, vilken valts bland: -R-, -R*-, -R-0-R, -R-S-R-, OSH R II II I I -R-, -R-, -R-N-R- tai -R-N-R-; och 15 (3) dä n' är 3, R8 är en bindningsgrupp -R-N-R- R varvid varenda R är oberoende av varandra en hydrokarbylgrupp med 1-12 kolatomer; och R* är en hydrokar-20 byl- eller en karboxylhydrokarbylgrupp med 1-60 kolatomer; (C-2) en ester, som innehäller fosfor men inte me-tall, med formeln
25 X3 R3 R5 0 ^\ll 4_‘ '___& 6 J^P-X -C—C-c-OR0
2. Komposition enligt patentkrav 1, känne-tecknad av, att den sura, organiska föreningen, om-fattar minst en alifatisk, cykloalifatisk eller aromatisk 15 karboxy1syra.
2. I 4 I (XVI) R2(X2)b K H 30 vari X1, X2, X3 och X4 betecknar oberoende av varandra syre eller svavel; R1, R2 betecknar oberoende av varandra en hydrokarbylgrupp;
35 R3, R4 och R5 betecknar oberoende av varandra väte, • · II 96223 103 halogen eller en hydrokarbylgrupp; R6 är en hydrokarbylgrupp; a och b betecknar oberoende av varandra talet 0 eller 1; 5 (C-3) ett ditiokarbonat, som är bundet med svavel, med formeln Rl R2 11 Sx-f-C-^C— S(SJCNR5r€)2 (XVII)
10 S3 k* varl R1, R2 och R3 betecknar oberoende av varandra H eller en hydrokarbylgrupp;
15 R4 är H, OH eller en hydrokarbylgrupp; R5 och R6 betecknar oberoende av varandra väte, hydrokarbyl eller hydroxylhydrokarbyl; eller R3 och R4 tillsammans och/eller R5 och R6 tillsammans och/eller R1 och R3 tillsammans och/eller R2 och R4 20 tillsammans kan bilda cykliska grupper; och x är ett tai 1-8; (C-4) en svavelhaltig förening med formeln Rl F3
25 Gl-C-(S)x-C-G2 U) r2 R4 vari R1, R2, R3 och R4 betecknar oberoende av varandra H 30 eller en hydrokarbylgrupp; R1 och/eller R3 kan vara G1 eller G2; R1 och R2 och/eller R3 och R4 kan tillsammans beteck-na en alkylengrupp med ca 4 - 7 kolatomer; G1 och G2 betecknar oberoende av varandra C(X)R,
35 COOR, ΟξΝ, R5-C=NR6, C0N(R)2 eller N02/ och G1 kan även vara 96223 104 CH2OH, där X är O eller S, R och R5 betecknar oberoende av varandra väte eller en hydrokarbylgrupp; R6 är H eller en hydrokarbylgrupp; di bide G1 och G2 betecknar R5C=NR6, kan de bägge R6-5 grupperna tillsammans vara en hydrokarbylengrupp som förbinder de bägge kväveatomerna ; di G1 är CH20H och G2 är C00R, kan ett lakton bildas genom intramolekylär kondensation av G1 och G2; och x är ett heltal 1-8; och 10 (C-5) en blandning av tvi eller flera av förenin- garna i (C-l) till (C-4).
3. Komposition enligt patentkrav 1, känne-tecknad av, att den sura, organiska föreningen, om-fattar minst en förening med formeln II eller III
20 R-CHC00H „ „„ I R-CH— CH2C00H eller \q CH2-C^ UI) UH) 25 väri R är en hydrokarbylgrupp.
4. Komposition enligt patentkrav 1, känne-tecknad av, att den sura, organiska föreningen har 30 formeln V (R8)c~j^J \ ,(0H) a II 96223 105 väri R7 och R8 är alifatiska hydrokarbylgrupper, a och b är tai 0-5, förutsatt att summan av a och b ej överstiger 5, och c är ett tai 0-4.
5. Komposition enligt patentkrav 1, känne-5 tecknad av, att den sura, organiska föreningen om-fattar minst en förening med formeln XII Ra-Ar-(0H)b (XII) 10 väri R är en hydrokarbylgrupp med ca. 4 - ca. 400 kolato-mer, Ar är en aromatisk grupp, a och b är tai minst 1, varvid summan av a och b ligger i omrädet frän 2 upp tili antalet undanträngbara väteatomer i den aromatiska kärnan eller kärnorna av Ar.
6. Komposition enligt patentkrav 1, känne- tecknad av, att metallen i det nämnda saltet (A) är litium, natrium, magnesium, kalcium, kalium barium, aluminium, zink, koppar eller en blandning av tvä eller flera av dessa.
7. Komposition enligt patentkrav 1, känne- tecknad av, att komponenten (B) är bensotriazol.
8. Komposition enligt patentkrav 1, känne-tecknad av, att den omfattar (A) minst en förening, vilken är vald ur gruppen « 25 magnesiumsulfonat, natriumsulfonat, magnesiumsalicylat eller en blandning av tvä eller flera av dessa; (B) minst en förening, vilken är vald ur gruppen bensotriazol, tolyltriazol eller en blandning av dessa; (C) en blandning av 30 (C-l) minst en fosforditionsyraamid; och J (C-2) minst en fosforditionsyraester. *
FI893258A 1987-11-05 1989-07-04 Komposition, som är användbar i insmörjningmedel och funktionella vätskor FI96223C (sv)

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Application Number Priority Date Filing Date Title
US11725487A 1987-11-05 1987-11-05
US11725487 1987-11-05
PCT/US1988/003723 WO1989004358A2 (en) 1987-11-05 1988-10-21 Compositions and lubricants and functional fluids containing same
US8803723 1988-10-21

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FI893258A FI893258A (sv) 1989-07-04
FI893258A0 FI893258A0 (sv) 1989-07-04
FI96223B FI96223B (sv) 1996-02-15
FI96223C true FI96223C (sv) 1996-05-27

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US4963282A (en) * 1989-05-11 1990-10-16 The Lubrizol Corporation Liquid compositions containing thiocarbamates
EP0480875B1 (de) * 1990-10-08 1994-05-04 Ciba-Geigy Ag Schmierstoffzusammensetzung
WO1992019703A1 (en) * 1991-05-01 1992-11-12 The Lubrizol Corporation Thermally stable compositions and lubricants and functional fluids containing the same
JP3086727B2 (ja) * 1991-08-09 2000-09-11 オロナイトジャパン株式会社 低リンエンジン油製造用の添加剤組成物
US5281346A (en) * 1992-04-16 1994-01-25 The Lubrizol Corporation Two-cycle engine lubricant and method of using same comprising alkali or alkaline earth metal salts of carboxylic aromatic acids
US5356546A (en) * 1992-04-16 1994-10-18 The Lubrizol Corporation Metal salts useful as additives for fuels and lubricants
MX9305120A (es) * 1992-09-04 1994-03-31 Lubrizol Corp Composiciones sobrebasificadas sulfuradas.
JPH07150183A (ja) * 1993-08-20 1995-06-13 Lubrizol Corp:The 熱安定性が向上し、そしてスリップ性能が限定された潤滑組成物
ATE328987T1 (de) 1998-07-06 2006-06-15 Lubrizol Corp Gemischte phosphorverbindungen und diese enthaltende schmiermittel
GB0011115D0 (en) 2000-05-09 2000-06-28 Infineum Int Ltd Lubricating oil compositions
JP2003138285A (ja) * 2001-11-02 2003-05-14 Nippon Oil Corp 自動車用変速機油組成物
EP1819739B1 (en) 2004-12-09 2019-07-24 The Lubrizol Corporation Process of preparation of an additive
CN102224228A (zh) * 2008-07-16 2011-10-19 卢布里佐尔公司 用于天然气发动机的改进的润滑剂
US20150240181A1 (en) * 2014-02-26 2015-08-27 Infineum International Limited Lubricating oil composition
CN114437696B (zh) * 2021-12-31 2023-05-30 华东理工大学 一种粘弹性表面活性剂组合物及其制备方法与应用

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GB1365288A (en) * 1970-12-16 1974-08-29 Cooper & Co Ltd Edwin Lubricating compositions
US3923669A (en) * 1974-10-31 1975-12-02 Sun Oil Co Pennsylvania Antiwear hydraulic oil
US4119549A (en) * 1975-03-21 1978-10-10 The Lubrizol Corporation Sulfurized compositions
US4100082A (en) * 1976-01-28 1978-07-11 The Lubrizol Corporation Lubricants containing amino phenol-detergent/dispersant combinations
US4200545A (en) * 1976-01-28 1980-04-29 The Lubrizol Corporation Amino phenol-detergent/dispersant combinations and fuels and lubricants containing same
US4627928A (en) * 1976-08-26 1986-12-09 The Lubrizol Corporation Basic non-carbonated magnesium compositions and fuel, lubricant and additive concentrate compositions containing same
US4181619A (en) * 1978-10-30 1980-01-01 Mobil Oil Corporation Antiwear composition
FR2485031A1 (fr) * 1980-03-10 1981-12-24 Lubrizol Corp Compositions benzotriazole-olefine sulfuree et lubrifiants et concentres les contenant
US4466894A (en) * 1983-04-20 1984-08-21 The Lubrizol Corporation Phosphorus-containing metal salts/sulfurized phenate compositions/aromatic substituted triazoles, concentrates, and functional fluids containing same
EP0216909B1 (en) * 1985-04-08 1990-02-28 The Lubrizol Corporation Lubricating oils comprising boron- and sulfur-containing compositions, and their method of preparation
US5182037A (en) * 1986-11-07 1993-01-26 The Lubrizol Corporation Phosphorus- and/or nitrogen-containing derivatives of sulfur-containing compounds, lubricant, fuel and functional fluid compositions

Also Published As

Publication number Publication date
DK328889D0 (da) 1989-07-03
AU615243B2 (en) 1991-09-26
FI893258A (sv) 1989-07-04
DE3851328T2 (de) 1995-01-26
AU2727488A (en) 1989-06-01
DE3851328D1 (de) 1994-10-06
JPH02502027A (ja) 1990-07-05
CA1337413C (en) 1995-10-24
ATE110766T1 (de) 1994-09-15
DK328889A (da) 1989-09-04
JP2000044975A (ja) 2000-02-15
EP0351428A1 (en) 1990-01-24
JP2001294885A (ja) 2001-10-23
EP0351428B1 (en) 1994-08-31
WO1989004358A3 (en) 1989-08-24
FI96223B (sv) 1996-02-15
BR8807282A (pt) 1990-03-01
FI893258A0 (sv) 1989-07-04
WO1989004358A2 (en) 1989-05-18

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