FI84731B - Transparent mjukelastiskt ytskikt av polyuretan foer transparenta glas- och plastsubstrat. - Google Patents

Transparent mjukelastiskt ytskikt av polyuretan foer transparenta glas- och plastsubstrat. Download PDF

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Publication number
FI84731B
FI84731B FI874359A FI874359A FI84731B FI 84731 B FI84731 B FI 84731B FI 874359 A FI874359 A FI 874359A FI 874359 A FI874359 A FI 874359A FI 84731 B FI84731 B FI 84731B
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FI
Finland
Prior art keywords
weight
polyether
mol
average molecular
surface layer
Prior art date
Application number
FI874359A
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English (en)
Finnish (fi)
Other versions
FI874359A0 (fi
FI874359A (fi
FI84731C (sv
Inventor
Helmer Raedisch
Gerhard Holzer
Udo Gelderie
Kornelia Breuer
Original Assignee
Saint Gobain Vitrage
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19873704294 external-priority patent/DE3704294A1/de
Application filed by Saint Gobain Vitrage filed Critical Saint Gobain Vitrage
Publication of FI874359A0 publication Critical patent/FI874359A0/fi
Publication of FI874359A publication Critical patent/FI874359A/fi
Publication of FI84731B publication Critical patent/FI84731B/fi
Application granted granted Critical
Publication of FI84731C publication Critical patent/FI84731C/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C03C17/322—Polyurethanes or polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5072—Polyethers having heteroatoms other than oxygen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Surface Treatment Of Glass (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Magnetic Record Carriers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Materials For Medical Uses (AREA)

Claims (6)

1. Transparent mjukelastiskt ytskikt av polyuretan för siktförnster eller andra transparenta glas- eller plastsub-strat, som har framställts av en reaktionsblandning som innehäller ätminstone en väsentligt trifunktionell alifatisk polyisocyanat med biuret- eller isocyanuratstruktur som baserats ρά 1,6-hexametylendiisocyanat, med en hait av NCO-grupper av 12,6-28 vikt-% och en genomsnittlig molekylvikt av ca 450-1000 g/mol, och vars polyolkomponent innehäller en bifunktionell sulfoniserad eller sulfonatgrupper inne-hällande polyeterpolyol med en hait av OH-grupper av 0,5-13,2 vikt-% och en genomsnittlig molekylvikt av ca 250-6500 g/mol och en trifunktionell trimetylolpropan och propylen-oxidbaserad polyol med en hait av OH-grupper av 5,1-12,8 vikt-% och en genomsnittlig molekylvikt av ca 400-1000 g/mol, kännetecknat av att som den bifunktionella sulfoni-serade eller sulfonatgrupper innehällande polyeterpolyolen användes en polyoxialkyleneter av 1,2- eller 1,3-dioler vars formel är R-CH20 - (C2H40-)n-(C3H60-)m-CH2CH2CH2 - SO3X varvid H0H2C CH20H R = HO - CH2 - CH - eller C OH C2H5-^^ X * H-, en natrium- eller ammoniumjon, n = 0-100, m = 0-30, n + m 5 1 och reaktionsblandningen innehäller även en icke-jonisk kopolymer av polyoxialkylenmodifierad dimetylpolysiloxan (polyeter-polysiloxan) med en genomsnittlig molekylvikt av ca 500-2000 g/mol och med en allmän formel 17 84731 ch31 ch3 (CH3)3Si-0-Si-0 - Si-0 - Si(CH3)3 c!h3 x y (ch2)3-o-(c2h4o)a-(c3h6o)b-CH3 varvid förhällandet x/y = 5/1 - 1/1, a = 80-100 vikt-%, och b = 20-0 vikt-%.
2. Transparent ytskikt enligt patentkravet 1, kännetecknat av att reaktionsblandningen har en halt av polyeterpolysil-oxan av 1-5 vikt-%.
3. Transparent ytskikt enligt patentkravet 1 eller 2, kännetecknat av att andelen av den bifunktionella sulfoni-serade eller sulfonatgrupper innehällande polyeterpolyolen i reaktionsblandningen är 5-12 vikt-%.
4. Transparent ytskikt enligt ett eller flera av de före-gäende patentkraven 1-3, kännetecknat av att däri användes en polyeterpolysiloxan med en genomsnittlig molekylvikt av ca 1000 g/mol.
5. Transparent ytskikt enligt ett eller flera av patentkraven 1-4, kännetecknat av att polyeterpolysiloxanen som skall användas bestär av etoxi- och propoxigrupper väri polyeterkedjan har ätminstone 80 vikt-% av EO-grupper.
6. Transparent ytskikt enligt patentkravet 5, kännetecknat av att förhällandet mellan etoxi och propoxi hos poly-etersidogrupper är företrädesvis 100/0.
FI874359A 1986-10-06 1987-10-05 Transparent mjukelastiskt ytskikt av polyuretan för transparenta glass - och plastsubstrat FI84731C (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE3633950 1986-10-06
DE3633950 1986-10-06
DE19873704294 DE3704294A1 (de) 1987-02-12 1987-02-12 Transparente deckschicht aus weichelastischem polyurethan fuer transparente glas- oder kunststoffsubstrate
DE3704294 1987-02-12

Publications (4)

Publication Number Publication Date
FI874359A0 FI874359A0 (fi) 1987-10-05
FI874359A FI874359A (fi) 1988-04-07
FI84731B true FI84731B (fi) 1991-09-30
FI84731C FI84731C (sv) 1992-01-10

Family

ID=25848176

Family Applications (1)

Application Number Title Priority Date Filing Date
FI874359A FI84731C (sv) 1986-10-06 1987-10-05 Transparent mjukelastiskt ytskikt av polyuretan för transparenta glass - och plastsubstrat

Country Status (14)

Country Link
US (1) US4826914A (sv)
EP (1) EP0269469B1 (sv)
JP (1) JP2567415B2 (sv)
KR (1) KR960012435B1 (sv)
AT (1) ATE71071T1 (sv)
AU (1) AU607939B2 (sv)
CA (1) CA1322259C (sv)
DD (1) DD265611A5 (sv)
DE (1) DE3775723D1 (sv)
DK (1) DK521087A (sv)
ES (1) ES2033336T3 (sv)
FI (1) FI84731C (sv)
NO (1) NO874175L (sv)
NZ (1) NZ222002A (sv)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4794147A (en) * 1987-07-24 1988-12-27 Basf Corporation, Inmont Division Novel non-ionic polyurethane resins having polyether backbones in water-dilutable basecoats
DE3817953C1 (sv) * 1988-05-27 1989-05-11 Vegla Vereinigte Glaswerke Gmbh, 5100 Aachen, De
DE4017341A1 (de) * 1990-05-30 1991-12-05 Hella Kg Hueck & Co Beschichtung mit beschlagverhindernder wirkung
DE4317791A1 (de) * 1993-05-28 1994-12-01 Herberts Gmbh Wäßrige Bindemittelzusammensetzung, diese enthaltende Überzugsmittel und deren Verwendung
DE19514908C1 (de) * 1995-04-22 1996-04-18 Ver Glaswerke Gmbh Verfahren zur Herstellung eines Solarmoduls
US5798409A (en) * 1995-10-03 1998-08-25 Minnesota Mining & Manufacturing Company Reactive two-part polyurethane compositions and optionally self-healable and scratch-resistant coatings prepared therefrom
US6284383B1 (en) 1996-11-05 2001-09-04 Teijin Limited Laminated glass for greenhouse
US20050202178A1 (en) 2002-05-02 2005-09-15 Hussmann Corporation Merchandisers having anti-fog coatings and methods for making the same
US20030205059A1 (en) * 2002-05-02 2003-11-06 Hussmann Corporation Merchandisers having anti-fog coatings and methods for making the same
JP4574178B2 (ja) * 2004-01-19 2010-11-04 セントラル硝子株式会社 防曇性物品の製法
US8446799B2 (en) 2011-03-01 2013-05-21 Timer Cap Company, Llc Container cap with a timer
US9361780B2 (en) 2011-03-01 2016-06-07 TimerCap, LLC Device and method for recording and transmitting interval data from a container cap
US20140248813A1 (en) * 2013-03-04 2014-09-04 Basf Se Crystal-clear polyurethanes
EP2774937A1 (de) * 2013-03-04 2014-09-10 Basf Se Glasklare Polyurethane
JP2019052221A (ja) * 2017-09-13 2019-04-04 中国塗料株式会社 樹脂組成物、硬化被膜、被膜付き基材およびその製造方法、ならびに基材に対する防曇処理方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846462A (en) * 1972-08-11 1974-11-05 Union Carbide Corp Organosilicone polymers
US4166149A (en) * 1976-10-01 1979-08-28 Bayer Aktiengesellschaft Novel transparent polyurethane polyureas for lamination of glazing materials
DE2816815A1 (de) * 1978-04-18 1979-10-31 Bayer Ag In wasser dispergierbare oder loesliche polyurethane, sowie ein verfahren zu ihrer herstellung
US4452962A (en) * 1983-03-07 1984-06-05 The Goodyear Tire & Rubber Company Accelerated conditioning of silicone-modified polyester film to yield immediate high slip properties
DE3407563C1 (de) * 1984-03-01 1985-04-25 Th. Goldschmidt Ag, 4300 Essen Sulfonierte Polyoxyalkylenether von 1.2- oder 1.3-Diolen,deren Herstellung und Verwendung
FR2574396B1 (fr) * 1984-12-06 1987-01-02 Saint Gobain Vitrages Sa Couche de revetement ayant des proprietes d'autocicatrisation pour des vitrages notamment ceux exposes aux agents atmospheriques
US4684538A (en) * 1986-02-21 1987-08-04 Loctite Corporation Polysiloxane urethane compounds and adhesive compositions, and method of making and using the same
DE3605765A1 (de) * 1986-02-22 1987-08-27 Ver Glaswerke Gmbh Transparente deckschicht aus weichelastischem polyurethan fuer transparente glas- oder kunststoffsubstrate

Also Published As

Publication number Publication date
CA1322259C (fr) 1993-09-14
FI874359A0 (fi) 1987-10-05
ATE71071T1 (de) 1992-01-15
KR880005178A (ko) 1988-06-28
JP2567415B2 (ja) 1996-12-25
KR960012435B1 (ko) 1996-09-20
DD265611A5 (de) 1989-03-08
FI874359A (fi) 1988-04-07
AU7924287A (en) 1988-04-14
US4826914A (en) 1989-05-02
NZ222002A (en) 1990-07-26
NO874175L (no) 1988-04-07
FI84731C (sv) 1992-01-10
EP0269469B1 (fr) 1992-01-02
NO874175D0 (no) 1987-10-05
DK521087D0 (da) 1987-10-05
DE3775723D1 (de) 1992-02-13
DK521087A (da) 1988-04-07
JPS63132922A (ja) 1988-06-04
EP0269469A2 (fr) 1988-06-01
AU607939B2 (en) 1991-03-21
EP0269469A3 (en) 1989-03-01
ES2033336T3 (es) 1993-03-16

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Owner name: SAINT-GOBAIN VITRAGE