FI84618B - Skivformiga jaernoxidpigment. - Google Patents
Skivformiga jaernoxidpigment. Download PDFInfo
- Publication number
- FI84618B FI84618B FI874610A FI874610A FI84618B FI 84618 B FI84618 B FI 84618B FI 874610 A FI874610 A FI 874610A FI 874610 A FI874610 A FI 874610A FI 84618 B FI84618 B FI 84618B
- Authority
- FI
- Finland
- Prior art keywords
- pigments
- pigment
- formula
- alxfe2
- reduction
- Prior art date
Links
- 239000000049 pigment Substances 0.000 claims description 40
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000002537 cosmetic Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000006104 solid solution Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 235000013980 iron oxide Nutrition 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001034 iron oxide pigment Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- JAQXDZTWVWLKGC-UHFFFAOYSA-N [O-2].[Al+3].[Fe+2] Chemical compound [O-2].[Al+3].[Fe+2] JAQXDZTWVWLKGC-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000001057 purple pigment Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000005169 Debye-Scherrer Methods 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000009283 thermal hydrolysis Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
- C09C1/245—Oxides of iron of plate-like shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
- Compounds Of Iron (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (5)
1. Skivformade pigment av järnoxid och innehällande aluminiumoxid i form av en fast lösning, k ä n n e - 5 tecknade därav, att de har formeln AlxFe2_x03_y, i vilken x är 0,02 - 0,5 och y Sr 0,3 - 1,0.
2. Pigment enligt patentkravet 1, k ä n n e -tecknade därav, att de ytterligare innehäller oxi-der av grundämnen ur det periodiska systemets huvud- och/- 10 eller sidogrupper II, IV, V och/eller VI.
3. Förfarande för framställning av skivformade pigment med formeln AlxFe2_x03_y, i vilken x är 0,02 - 0,5 och y är 0,3 - 1,0, kännetecknat därav, att ett pigment med formeln AlxFe2_x03, i vilken x är 0,02 - 0,5, 15 upphettas i reducerande atmosfär vid en temperatur av ca 200 - 800 °C.
4. Förfarande enligt patentkravet 3, kännetecknat därav, att pigmenten beläggs före eller efter upphettningen med en oxid av grundämnen ur det peri- 20 odiska systemets huvud- och/eller sidogrupp II, IV, V och/eller VI.
5. Användning av pigment enligt patentkravet 1 i lack, mälfärger, plaster, fibrer, glas, keramik eller kosinet iskä produkter. Il
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3636076 | 1986-10-23 | ||
DE19863636076 DE3636076A1 (de) | 1986-10-23 | 1986-10-23 | Plaettchenfoermige eisenoxidpigmente |
Publications (4)
Publication Number | Publication Date |
---|---|
FI874610A0 FI874610A0 (fi) | 1987-10-20 |
FI874610A FI874610A (fi) | 1988-04-24 |
FI84618B true FI84618B (fi) | 1991-09-13 |
FI84618C FI84618C (sv) | 1991-12-27 |
Family
ID=6312315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI874610A FI84618C (sv) | 1986-10-23 | 1987-10-20 | Skivformiga järnoxidpigment |
Country Status (13)
Country | Link |
---|---|
US (1) | US4780140A (sv) |
EP (1) | EP0268072B1 (sv) |
JP (1) | JPS63123818A (sv) |
KR (1) | KR880005218A (sv) |
AU (1) | AU609063B2 (sv) |
BR (1) | BR8705657A (sv) |
DE (2) | DE3636076A1 (sv) |
ES (1) | ES2022257B3 (sv) |
FI (1) | FI84618C (sv) |
HU (1) | HUT47966A (sv) |
IN (1) | IN168864B (sv) |
PL (1) | PL268358A2 (sv) |
ZA (1) | ZA877984B (sv) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3709217A1 (de) * | 1987-03-20 | 1988-09-29 | Basf Ag | Plaettchenfoermige pigmente auf basis eisenoxid |
DE3719804A1 (de) * | 1987-06-02 | 1989-03-16 | Basf Ag | Verfahren zur herstellung von plaettchenfoermigen zweiphasenpigmenten |
GB8729729D0 (en) * | 1987-12-21 | 1988-02-03 | Cookson Group Plc | Pigment compositions |
DE3803940A1 (de) * | 1988-02-10 | 1989-08-24 | Bayer Ag | Neue oxidationsstabile hitzebestaendige eisenoxidschwarzpigmente, verfahren zu ihrer herstellung sowie deren verwendung |
DE3820499A1 (de) * | 1988-06-16 | 1989-12-21 | Bayer Ag | Thermisch stabile eisenoxidpigmente mit gamma-fe(pfeil abwaerts)2(pfeil abwaerts)0(pfeil abwaerts)3(pfeil abwaerts)-struktur, verfahren zu ihrer herstellung sowie deren verwendung |
DE58907942D1 (de) * | 1988-09-09 | 1994-07-28 | Ciba Geigy Ag | Lacke enthaltend Molybdändisulfid. |
US5080718A (en) * | 1989-02-23 | 1992-01-14 | Engelhard Corporation | Inorganic pigments of the empirical formula Ax By Cz |
DE3918694C1 (sv) * | 1989-05-10 | 1990-10-25 | Bayer Ag, 5090 Leverkusen, De | |
US5071724A (en) * | 1989-06-07 | 1991-12-10 | Olin Hunt Sub I Corp. | Method for making colored magnetic particles and their use in electrostatographic toner compositions |
DE4212950B4 (de) * | 1992-04-18 | 2006-03-09 | Merck Patent Gmbh | Leitfähiges Pigment, Verfahren zur Herstellung und Verwendung |
JP3444919B2 (ja) * | 1992-04-18 | 2003-09-08 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 導電性顔料 |
JP3132918B2 (ja) * | 1992-09-22 | 2001-02-05 | 株式会社資生堂 | 赤色系顔料及びその製造方法 |
US5273576A (en) * | 1992-10-19 | 1993-12-28 | Mearl Corporation | Intensely colored pearlescent pigments |
JP3579432B2 (ja) * | 1992-12-17 | 2004-10-20 | チタン工業株式会社 | 光沢顔料およびその製造法 |
GB2397066B (en) * | 2001-11-29 | 2006-03-22 | Honda Canada Inc | Pearlescent white paint formulations |
JP5400341B2 (ja) * | 2008-10-01 | 2014-01-29 | チタン工業株式会社 | マグネタイト構造を有する鱗片状酸化鉄粒子およびその使用 |
CN102712816B (zh) | 2010-01-15 | 2015-09-09 | 默克专利股份有限公司 | 效果颜料 |
DE102010054803A1 (de) | 2010-12-16 | 2012-06-21 | Merck Patent Gmbh | Pigmentgranulate |
WO2015183674A1 (en) | 2014-05-28 | 2015-12-03 | Basf Se | Effect pigments |
JP7138906B2 (ja) * | 2018-02-20 | 2022-09-20 | 学校法人加計学園 | セラミックス焼結体、ガラス成形品及びそれらの製造方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3030307A (en) * | 1958-04-29 | 1962-04-17 | Sylvania Electric Prod | Ferrite material containing lithium and aluminum oxides |
US4373963A (en) * | 1981-09-03 | 1983-02-15 | Titan Kogyo K.K. | Lustrous pigment and process for producing same |
DE3324400A1 (de) * | 1983-07-06 | 1985-01-24 | Bayer Ag, 5090 Leverkusen | Neues braunpigment auf basis von eisen-aluminium-mischoxiden sowie verfahren zu dessen herstellung |
GB8729729D0 (en) * | 1987-12-21 | 1988-02-03 | Cookson Group Plc | Pigment compositions |
-
1986
- 1986-10-23 DE DE19863636076 patent/DE3636076A1/de not_active Withdrawn
-
1987
- 1987-09-15 IN IN739/CAL/87A patent/IN168864B/en unknown
- 1987-10-13 EP EP87114976A patent/EP0268072B1/de not_active Expired - Lifetime
- 1987-10-13 DE DE8787114976T patent/DE3769758D1/de not_active Expired - Fee Related
- 1987-10-13 ES ES87114976T patent/ES2022257B3/es not_active Expired - Lifetime
- 1987-10-14 AU AU79776/87A patent/AU609063B2/en not_active Ceased
- 1987-10-20 FI FI874610A patent/FI84618C/sv not_active IP Right Cessation
- 1987-10-21 HU HU874729A patent/HUT47966A/hu unknown
- 1987-10-21 KR KR870011686A patent/KR880005218A/ko not_active IP Right Cessation
- 1987-10-22 BR BR8705657A patent/BR8705657A/pt unknown
- 1987-10-22 US US07/111,340 patent/US4780140A/en not_active Expired - Fee Related
- 1987-10-22 PL PL1987268358A patent/PL268358A2/xx unknown
- 1987-10-23 ZA ZA877984A patent/ZA877984B/xx unknown
- 1987-10-23 JP JP62266680A patent/JPS63123818A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ZA877984B (en) | 1988-04-26 |
FI84618C (sv) | 1991-12-27 |
AU609063B2 (en) | 1991-04-26 |
HUT47966A (en) | 1989-04-28 |
IN168864B (sv) | 1991-06-29 |
DE3636076A1 (de) | 1988-04-28 |
EP0268072A1 (de) | 1988-05-25 |
BR8705657A (pt) | 1988-05-31 |
JPS63123818A (ja) | 1988-05-27 |
FI874610A (fi) | 1988-04-24 |
US4780140A (en) | 1988-10-25 |
FI874610A0 (fi) | 1987-10-20 |
ES2022257B3 (es) | 1991-12-01 |
AU7977687A (en) | 1988-04-28 |
PL268358A2 (en) | 1988-07-07 |
EP0268072B1 (de) | 1991-05-02 |
KR880005218A (ko) | 1988-06-28 |
DE3769758D1 (de) | 1991-06-06 |
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