FI61784B - Vattendispergerbara triazinherbicidkompositioner - Google Patents
Vattendispergerbara triazinherbicidkompositioner Download PDFInfo
- Publication number
- FI61784B FI61784B FI783114A FI783114A FI61784B FI 61784 B FI61784 B FI 61784B FI 783114 A FI783114 A FI 783114A FI 783114 A FI783114 A FI 783114A FI 61784 B FI61784 B FI 61784B
- Authority
- FI
- Finland
- Prior art keywords
- surfactant
- triazine
- composition according
- weight
- water
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 73
- 239000004094 surface-active agent Substances 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000004009 herbicide Substances 0.000 claims description 22
- -1 1-methyl-3-cyclohexyl-6-cyclohexyl s-triazine-2,4- (1H, 3H) -dione Chemical compound 0.000 claims description 21
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 20
- 230000002363 herbicidal effect Effects 0.000 claims description 18
- 238000002425 crystallisation Methods 0.000 claims description 10
- 230000008025 crystallization Effects 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- ZTFYJIXFKGPCHV-UHFFFAOYSA-N 2-propan-2-ylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C(C)C)=CC=C21 ZTFYJIXFKGPCHV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 2
- 238000009472 formulation Methods 0.000 description 31
- 239000007921 spray Substances 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 17
- 239000013078 crystal Substances 0.000 description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 9
- 159000000000 sodium salts Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 230000000717 retained effect Effects 0.000 description 7
- BFGQTWYXWNCTSX-UHFFFAOYSA-N triazine-4,5-dione Chemical class O=C1C=NN=NC1=O BFGQTWYXWNCTSX-UHFFFAOYSA-N 0.000 description 7
- 239000004563 wettable powder Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 235000021552 granulated sugar Nutrition 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- UAZMXAXHGIZMSU-UHFFFAOYSA-N sodium tin Chemical compound [Na].[Sn] UAZMXAXHGIZMSU-UHFFFAOYSA-N 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 240000007930 Oxalis acetosella Species 0.000 description 2
- 235000008098 Oxalis acetosella Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000011078 sorbitan tristearate Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 239000005510 Diuron Substances 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- NBQCNZYJJMBDKY-UHFFFAOYSA-N Terbacil Chemical compound CC=1NC(=O)N(C(C)(C)C)C(=O)C=1Cl NBQCNZYJJMBDKY-UHFFFAOYSA-N 0.000 description 1
- WPMWEFXCIYCJSA-UHFFFAOYSA-N Tetraethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCO WPMWEFXCIYCJSA-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- JIJAYWGYIDJVJI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 JIJAYWGYIDJVJI-UHFFFAOYSA-N 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012053 oil suspension Substances 0.000 description 1
- YTSACTNRGUJEGO-UHFFFAOYSA-N oxirane prop-1-ene Chemical group CC=C.C1CO1 YTSACTNRGUJEGO-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001993 poloxamer 188 Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- UMFCIIBZHQXRCJ-NSCUHMNNSA-N trans-anol Chemical compound C\C=C\C1=CC=C(O)C=C1 UMFCIIBZHQXRCJ-NSCUHMNNSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (12)
1. Vattendispergerbar triazinherbicidkomposition med för-bättrade kristallisationsegenskaper dispergerad i vatten vid under ca 37°C i en koncentration som överstiger löslighetsgränsen för triazinet, kännetecknad därav, att den väsentligen bestär av (a) 1-metyl-3-cyklohexyl-6-dimetylamino-s-triazin-2,4-(1H,3H)-dion och (b) ätminstone ca 2 vikt-%, pä basis av torrvikt av triazin, av ett ytaktivt medel som är isopropylnaftalensulfon-syra eller alkalimetall- eller jordalkalimetallsalt därav.
2. Komposition enligt patentkravet 1, kännetecknad därav, att den omfattar en blandning av finfördelade partiklar av triazinföreningen och av det ytaktiva medlet.
3. Komposition enligt patentkravet 1, kännetecknad därav, att den omfattar finfördelade partiklar av triazinherbiciden med det ytaktiva medlet inneslutet däri.
4. Komposition enligt patentkravet 1, kännetecknad därav, att den omfattar finfördelade partiklar av triazinherbiciden med det ytaktiva medlet som ett skikt pä ytan därav.
5. Komposition enligt patentkravet 1, kännetecknad därav, att den omfattar en dispersion av triazinherbiciden i en vattenlösning av det ytaktiva medlet.
6. Komposition enligt patentkravet 5, kännetecknad därav, att dispersionen är en flytande uppslamning.
7. Komposition enligt patentkravet 5, kännetecknad därav, att triazinherbiciden löses i vattenlösning av det ytaktiva medlet.
8. Komposition enligt patentkravet 1, kännetecknad därav, att det ytaktiva medlet är närvarande i en mängd av ätminstone ca 5 vikt-%, beräknat pä torrvikt av triazin.
9. Komposition enligt patentkravet 1, kännetecknad därav, att det ytaktiva medlet innehäller i medeltal ca 2,5 isopro-pylgrupper per naftalensulfonatmolekyl.
10. Komposition enligt patentkravet 8, kännetecknad därav, att det ytaktiva medlet innehäller i medeltal ca 2,5 iso-propylgrupper per naftalensulfonatmolekyl.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84145077A | 1977-10-12 | 1977-10-12 | |
| US84145077 | 1977-10-12 | ||
| US05/938,631 US4197112A (en) | 1977-10-12 | 1978-09-07 | Water-dispersible herbicide compositions |
| US93863178 | 1978-09-07 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI783114A FI783114A (fi) | 1979-04-13 |
| FI61784B true FI61784B (fi) | 1982-06-30 |
| FI61784C FI61784C (fi) | 1982-10-11 |
Family
ID=27126255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI783114A FI61784C (fi) | 1977-10-12 | 1978-10-12 | Vattendispergerbara triazinherbicidkompositioner |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4197112A (sv) |
| EP (1) | EP0001519B1 (sv) |
| AU (1) | AU527919B2 (sv) |
| BR (1) | BR7806708A (sv) |
| CS (1) | CS209538B2 (sv) |
| DE (1) | DE2861517D1 (sv) |
| DK (1) | DK411278A (sv) |
| ES (1) | ES474152A1 (sv) |
| FI (1) | FI61784C (sv) |
| GB (1) | GB2005541B (sv) |
| YU (1) | YU237978A (sv) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714439A (en) * | 1990-10-31 | 1998-02-03 | Rohm And Haas Company | Propanil dispersible granule |
| CA2054054C (en) * | 1990-10-31 | 2002-11-26 | Richard David Houghton | Propanil dispersible granule formulation |
| FI93416C (sv) | 1991-09-27 | 1995-04-10 | Kemira Oy | Förfarande för framställning av en herbicidprodukt i granul- eller tablettform |
| US5651975A (en) * | 1991-09-27 | 1997-07-29 | Harju-Jeanty; Pontus | Method for the preparation of herbicidal granular products comprising two separate phases |
| EG20596A (en) * | 1992-05-28 | 1999-09-30 | Dow Elanco L L S | Aqueaus flowable phenazaquin composition |
| JP5635887B2 (ja) * | 2010-11-30 | 2014-12-03 | 北興化学工業株式会社 | 水面浮遊性除草製剤 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2044942A (en) * | 1936-06-23 | Preparation of finely divided | ||
| US2635055A (en) * | 1948-07-08 | 1953-04-14 | Hans G Figdor | Water repellent composition |
| US2655445A (en) * | 1949-12-06 | 1953-10-13 | Du Pont | 3-(halophenyl)-1-methyl-1-(methyl or ethyl) ureas and herbicidal compositions and methods employing same |
| US2891855A (en) * | 1954-08-16 | 1959-06-23 | Geigy Ag J R | Compositions and methods for influencing the growth of plants |
| US3248182A (en) * | 1962-11-21 | 1966-04-26 | Intermountain Res & Dev Corp | Crystallization of sodium sesquicarbonate in presence of a surfactant and a hydrocarbon oil |
| US3585230A (en) * | 1968-07-17 | 1971-06-15 | Kaiser Aluminium Chem Corp | Stable liquid polyisocyanate compositions |
| GB1290351A (sv) | 1969-01-22 | 1972-09-27 | ||
| US3989452A (en) * | 1969-07-18 | 1976-11-02 | Ciba-Geigy Corporation | Stable, concentrated solutions of complex metal compounds of azo dyestuffs |
| GB1346425A (en) * | 1970-08-13 | 1974-02-13 | Agfa Gevaert | Method of incorporating photographic compounds into hydrophilic colloids |
| IL42103A (en) * | 1972-05-24 | 1976-05-31 | Du Pont | 6-amino-s-triazine-2,4-(1h,3h)-diones and corresponding 4-thio compounds,their preparation and their use as herbicides |
| US3932224A (en) * | 1973-02-22 | 1976-01-13 | Keishin Matsumoto Director-General Of The Agency Of Industrial Science And Technology | Method of preventing scale from being deposited in case of producing fresh water from sea water |
| US3902887A (en) * | 1973-04-05 | 1975-09-02 | Du Pont | Herbicidal 6-amino-s-triazinediones |
| US3943059A (en) * | 1974-03-05 | 1976-03-09 | Shell Oil Company | Process of displacing oil in subterranean reservoir employing aqueous surfactant systems |
| US3979317A (en) * | 1975-04-28 | 1976-09-07 | Xerox Corporation | Volatile cleaning solution for photoreceptors |
-
1978
- 1978-09-07 US US05/938,631 patent/US4197112A/en not_active Expired - Lifetime
- 1978-09-18 DK DK411278A patent/DK411278A/da not_active Application Discontinuation
- 1978-10-10 BR BR7806708A patent/BR7806708A/pt unknown
- 1978-10-11 GB GB7840136A patent/GB2005541B/en not_active Expired
- 1978-10-11 ES ES474152A patent/ES474152A1/es not_active Expired
- 1978-10-11 YU YU02379/78A patent/YU237978A/xx unknown
- 1978-10-11 AU AU40593/78A patent/AU527919B2/en not_active Expired
- 1978-10-11 DE DE7878300491T patent/DE2861517D1/de not_active Expired
- 1978-10-11 CS CS786613A patent/CS209538B2/cs unknown
- 1978-10-11 EP EP78300491A patent/EP0001519B1/en not_active Expired
- 1978-10-12 FI FI783114A patent/FI61784C/fi not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB2005541A (en) | 1979-04-25 |
| ES474152A1 (es) | 1979-10-16 |
| BR7806708A (pt) | 1979-05-08 |
| US4197112A (en) | 1980-04-08 |
| EP0001519A1 (en) | 1979-04-18 |
| DK411278A (da) | 1979-04-13 |
| AU4059378A (en) | 1980-04-17 |
| GB2005541B (en) | 1982-04-07 |
| EP0001519B1 (en) | 1982-01-06 |
| DE2861517D1 (en) | 1982-02-25 |
| FI61784C (fi) | 1982-10-11 |
| CS209538B2 (en) | 1981-12-31 |
| FI783114A (fi) | 1979-04-13 |
| AU527919B2 (en) | 1983-03-31 |
| YU237978A (en) | 1984-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TC | Name/ company changed in patent |
Owner name: GESTRA GMBH |
|
| MM | Patent lapsed |
Owner name: E.I. DU PONT DE NEMOURS AND COMPANY |