FI59819C - Elektrolytiskt foerfarande foer tillvaratagande av nickel och zink och en vid foerfarandet anvaend elektrolyscell - Google Patents
Elektrolytiskt foerfarande foer tillvaratagande av nickel och zink och en vid foerfarandet anvaend elektrolyscell Download PDFInfo
- Publication number
- FI59819C FI59819C FI752476A FI752476A FI59819C FI 59819 C FI59819 C FI 59819C FI 752476 A FI752476 A FI 752476A FI 752476 A FI752476 A FI 752476A FI 59819 C FI59819 C FI 59819C
- Authority
- FI
- Finland
- Prior art keywords
- electrolyte
- anode
- chambers
- nickel
- anolyte
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 43
- 229910052759 nickel Inorganic materials 0.000 title claims description 21
- 239000003792 electrolyte Substances 0.000 claims description 33
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- 230000035699 permeability Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 150000001450 anions Chemical class 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 5
- 230000007246 mechanism Effects 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 2
- 230000005012 migration Effects 0.000 claims 2
- 238000013508 migration Methods 0.000 claims 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 238000005192 partition Methods 0.000 description 10
- 239000011449 brick Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- 229910021653 sulphate ion Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 229910000323 aluminium silicate Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- -1 hydrogen ions Chemical class 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012527 feed solution Substances 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- BZUIAQFBINSQSL-UHFFFAOYSA-N [Ni].[Cu].[Cu] Chemical compound [Ni].[Cu].[Cu] BZUIAQFBINSQSL-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA7405625 | 1974-09-04 | ||
| ZA00745625A ZA745625B (en) | 1974-09-04 | 1974-09-04 | Improvements in or relating to the electrolytic recovery of nickel and zinc |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI752476A7 FI752476A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-03-05 |
| FI59819B FI59819B (fi) | 1981-06-30 |
| FI59819C true FI59819C (fi) | 1981-10-12 |
Family
ID=25568109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI752476A FI59819C (fi) | 1974-09-04 | 1975-09-03 | Elektrolytiskt foerfarande foer tillvaratagande av nickel och zink och en vid foerfarandet anvaend elektrolyscell |
Country Status (9)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5524924A (en) * | 1978-08-08 | 1980-02-22 | Ebara Yuujiraito Kk | Adjustment of metal ion concentration in nickel plating liquor |
| US4234393A (en) * | 1979-04-18 | 1980-11-18 | Amax Inc. | Membrane process for separating contaminant anions from aqueous solutions of valuable metal anions |
| DE2940741A1 (de) * | 1979-10-08 | 1981-04-16 | SEP Gesellschaft für technische Studien, Entwicklung, Planung mbH, 8000 München | Verfahren zur elektrolytischen gewinnung von nickel |
| ES8801394A1 (es) * | 1984-07-02 | 1987-05-16 | Diaz Nogueira Eduardo | Procedimiento para la electrodeposicion catodica de metales con la generacion del acido correspondiente, a partir de disoluciones de sus sales |
| DE4218915A1 (de) * | 1992-06-10 | 1993-12-16 | Heraeus Elektrochemie | Verfahren und Vorrichtung zur Regenerierung einer Metallionen und Schwefelsäure enthaltenden wäßrigen Lösung sowie Verwendung |
| DE4326854A1 (de) * | 1993-08-11 | 1995-02-16 | Heraeus Elektrochemie | Verfahren zur Regenerierung einer Metallionen und Schwefelsäure enthaltenden wässrigen Lösung sowie Vorrchtung |
| US6569311B2 (en) * | 2001-02-02 | 2003-05-27 | Clariant Finance (Bvi) Limited | Continuous electrochemical process for preparation of zinc powder |
| US6569310B2 (en) * | 2001-02-02 | 2003-05-27 | Clariant Finance (Bvi) Limited | Electrochemical process for preparation of zinc powder |
| RU2256729C1 (ru) * | 2003-10-09 | 2005-07-20 | Открытое акционерное общество "Горно-металлургическая компания "Норильский никель" | Способ изготовления диафрагменного элемента ячейки для электролитического извлечения металлов из водных растворов и диафрагменный элемент |
| FR2977804B1 (fr) * | 2011-07-15 | 2014-01-31 | Tredi | Procede de traitement d'effluents liquides en milieu chlorure et separation du zinc et du nickel, installation pour sa mise en oeuvre et application aux effluents industriels metalliferes |
| CN104532293B (zh) * | 2014-12-22 | 2017-06-09 | 无锡市瑞思科环保科技有限公司 | 化学镀镍废液中提纯镍的方法及镍提纯装置 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1980381A (en) * | 1931-05-27 | 1934-11-13 | Frederic A Eustis | Method of making ductile electrolytic iron from sulphide ores |
| US2480771A (en) * | 1946-04-12 | 1949-08-30 | Int Nickel Co | Process for the electrolytic recovery of nickel |
| US3072545A (en) * | 1961-11-20 | 1963-01-08 | Ionics | Electroplating of metals |
-
1974
- 1974-09-04 ZA ZA00745625A patent/ZA745625B/xx unknown
-
1975
- 1975-09-01 NO NO75752982A patent/NO146208C/no unknown
- 1975-09-02 US US05/609,812 patent/US4073709A/en not_active Expired - Lifetime
- 1975-09-03 CA CA234,698A patent/CA1059064A/en not_active Expired
- 1975-09-03 BE BE159698A patent/BE833017A/xx not_active IP Right Cessation
- 1975-09-03 SE SE7509763A patent/SE406778B/xx unknown
- 1975-09-03 DE DE2539137A patent/DE2539137C3/de not_active Expired
- 1975-09-03 FI FI752476A patent/FI59819C/fi not_active IP Right Cessation
- 1975-09-04 JP JP50106579A patent/JPS5150808A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS559955B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-03-13 |
| FI59819B (fi) | 1981-06-30 |
| NO752982L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-03-05 |
| DE2539137A1 (de) | 1976-03-25 |
| DE2539137B2 (de) | 1980-02-21 |
| DE2539137C3 (de) | 1980-10-09 |
| US4073709A (en) | 1978-02-14 |
| AU8445075A (en) | 1977-03-10 |
| SE7509763L (sv) | 1976-03-05 |
| NO146208C (no) | 1982-08-18 |
| SE406778B (sv) | 1979-02-26 |
| NO146208B (no) | 1982-05-10 |
| BE833017A (fr) | 1975-12-31 |
| JPS5150808A (en) | 1976-05-04 |
| ZA745625B (en) | 1975-12-31 |
| CA1059064A (en) | 1979-07-24 |
| FI752476A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: ANGLOVAAL LIMITED |