FI3470457T4 - Rikin avulla silloitettava kautsuseos, kautsuseoksen vulkanoitu kumi ja ajoneuvon rengas - Google Patents

Rikin avulla silloitettava kautsuseos, kautsuseoksen vulkanoitu kumi ja ajoneuvon rengas Download PDF

Info

Publication number
FI3470457T4
FI3470457T4 FIEP17195625.3T FI17195625T FI3470457T4 FI 3470457 T4 FI3470457 T4 FI 3470457T4 FI 17195625 T FI17195625 T FI 17195625T FI 3470457 T4 FI3470457 T4 FI 3470457T4
Authority
FI
Finland
Prior art keywords
rubber
mixture
phr
htc
rubber mixture
Prior art date
Application number
FIEP17195625.3T
Other languages
English (en)
Swedish (sv)
Inventor
Nils Walter Hojdis
Carla Recker
Michael Wark
Hendrik Multhaupt
Original Assignee
Continental Reifen Deutschland Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=60191092&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FI3470457(T4) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Continental Reifen Deutschland Gmbh filed Critical Continental Reifen Deutschland Gmbh
Application granted granted Critical
Publication of FI3470457T4 publication Critical patent/FI3470457T4/fi

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/002—Methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
    • B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
    • C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/086—Hydrothermal carbonization
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C08K2003/168—Zinc halides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/006—Additives being defined by their surface area
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (13)

  1. Table 2
    Char Starting T Yield | Carbon con- | BET e E [STI EE = ju s jae] ja joja ja ja [eben | fm jm Js Dj a jos Reese = a epa a ke Dj = joe | mikek a jou juju hoe =
    Table 3 Char T Yield | Carbon con- | BET ST Er joj EE cl I EJ + a jae fw fa js wale [oi a ja (www jo EF. a | jaja J 2 ja eps jp = a | jaja je je a jaa jaja ja ja = | esse a jaa jajaja ja ja 2 | jaja je a ja pj = a | jaja ja ja a ja Jw [uv j = a ja wes je jw a [ana jaja ja ja Jo s ja eps j js a [ava jaja ja ja jo a je jaja e A a [aura ju jaja ja (= In table 3 Coconit 300 © was used as the starting substance.
    Table 4 Char | Salt to | T Yield | Carbon con- | BET no. |start. sub. tent wt. ratio Te jee [e a js jek ke Js a [= jea e a jes je ja js. a ja jek Jw Jo [% a ja: jeju ja fe Ju In table 4 Coconit 300 9 was used as the starting substance and ZnCl> was used as the salt. Substances used a) Biomass: Mixture of grass and rushes from green wastes from the area to the northeast of Oldenburg. Contains around 70% of common rushes (Juncus ef- fusus), 25-30% of grasses (Poaceae, Cyperaceae) and smaller amounts and traces of herbs. The different grasses and rushes were used already mixed and comminuted to afford particles having a size of about 0.2 mm. b) Coconut husk: Coconut husk granulates of less than 1 inch in size from Mahl- werk Neubauer-Friedrich Geffers GmbH c) Coconit 300: Coconut husk flour from Mahlwerk Neubauer-Friedrich Geffers GmbH d) Rice husks: from Kazulube e) Glucose: D(+)-Glucose anhydrous, VWR f) Cellulose: a-cellulose powder (“powder”), Sigma Aldrich An HTC char produced using at least one salt has an increased surface roughness and an optimized surface functionality.
    The surface roughness may be qualitatively assessed using TEM images by way of comparison as shown for example in figures 1 and 2.
    Fig. 1 shows an HTC char produced using the salt mixture ZnCl2/KCl (reaction at 180°C for 12 hours).
    Fig. 2 shows a char produced without using the salt mixture under otherwise iden- tical conditions (reaction at 180°C for 12 hours). Asis apparent from the comparison of Fig. 1 and Fig. 2 the HTC char produced using at least one salt has a higher roughness.
    Fig. 3 is an exemplary FTIR spectrum. Here, transmission is plotted qualitatively (units: a.u. = arbitrary units) against wavenumber (W for short) (units: cm™). The spectra and their relevant sections are shown for the following substances: - for the starting substance coconut husk flour 4; -for a hydrochar 5 produced by hydrothermal carbonization of coconut husk flour (reaction at 180°C for 12 hours) without salt - for a salt hydrochar 6 produced using the salt ZnCl: but otherwise identical con- ditions (reaction at 180°C for 12 hours; coconut husk flour); - for an activated salt hydrochar 7 produced using the salt mixture LiCl/ZnCl2 (re- action at 180°C for 12 hours; coconut husk flour) and subsequent activation by water vapor at 500°C for 1 hour; — -for carbon black N 660 8.
    It is apparent in Fig. 3 that a salt hydrochar 6 still comprises functional groups compared to a salt hydrochar 7 activated in a further step, as is apparent from the bands for carbonyl compounds 1 and the bands for oxygen-containing functional groups 3. The char produced with salt simultaneously exhibits bands for C=C dou- ble bonds 2 in the FTIR spectrum.
    The spectrum for the carbon black 8 also exhib- its bands for oxygen-containing functional groups 3 and for C=C double bonds 2 and the salt hydrochar 6 is therefore chemically at least similar to carbon blacks.
    The salt hydrochar thus has functional groups which may possibly result in in- creased interactions in a rubber mixture.
    Compared to hydrochar (without salt) 5 it
    1s apparent that while use of the salt causes part of the functionality to be lost and only the above described groups to be retained the band for oxygen-containing functional groups 3 is actually stronger in the salt hydrochar 6.
    It is further conceivable that the loss of the potentially disruptive groups results in
    — improved interactivity of the salt hydrochar in a rubber mixture.
    The HTC chars summarized in table 1 were incorporated into rubber mixtures whose general formulations are shown in table 5. When choosing the chars the focus was on sustainability for economic reasons and several waste biomasses
    — were therefore selected as starting substances.
    The mixtures labeled "E" are mix- tures which contain at least one HTC char as a filler while the mixtures marked with "V" are comparative mixtures containing carbon black as a filler.
    The mix- tures E6 and E14 are mixtures according to the invention.
    — The mixture was produced according to the process customary in the rubber indus- try under standard conditions in three stages in a laboratory mixer having a volume of 300 milliliters to 3 liters wherein initially in the first mixing stage (preliminary mixing stage) all constituents apart from the vulcanization system (sulfur and vul- canization influencers) were mixed at 145°C to 165°C, target temperatures of
    152°Cto 157°C, for 200 to 600 seconds.
    This preliminary mixture was mixed again in a further step.
    Addition of the vulcanization system in the third stage (final mixing stage) afforded the final mixture, mixing being carried out at 90°C to 120°C for 180 to 300 seconds.
    All mixtures were used to produce test specimens by vulcanization and these test specimens were used to determine material properties typical for the rubber indus-
    — try and these are summarized in tables 6 and 7. The tests described above were carried out on test samples using the following test methods:
    e Archimedes density e Shore A hardness at room temperature RT and 70*C using a durometer accord- ing to ISO 868 e Rebound resilience at RT and 70°C according to ISO 4662 e Stress values at 50% and 100% strain at room temperature according to ISO 37 and ASTM D 412 (M50 and M100) Table5 e kk! Pk Cw we? mP!
    Substances used g) SSBR: Nipol NS 210R, Zeon Europe GmbH h) chars from table 1; as reported in tables 6 to 9, in each case in the reported amounts of 60 or 40 phr i) aging stabilizers, antiozonant wax, zinc oxide, stearic acid
    As is apparent from tables 6 and 7 carbon black (N 660) (mixtures V1 and V2) may be completely substituted by HTC chars, the reduced rebound resiliences re- sulting in improved room-temperature wet grip indicators, especially for use in vehicle tires.
    Stiffness (values for M50 und M100 hardnesses) and thus the han- dling indicators and rebound resilience at 70°C remain at a comparable level ac- ceptable for use in vehicle tires.
    In addition, the rubber mixtures according to the invention show a reduced density compared to the respective comparative mixtures which in turn results in lighter and thus rolling resistance-optimized components for vehicle tires.
    Table 6 [EE EEEEEE Char no. from 1 7 i EET EEE TE 1 1 11111 1! |. wes foe Hardness Shore A | 58.8 | 59.0 | 59.4 | 52.3 | 47.6 | 56.2 | 55.6 | 62.0 | 56.7 Flo [].
    Reb. resil. | % 59.4 | 56.0 | 53.6 | 56.2 | 53.2 | 52.0 | 55.2 | 56.4 | 56.4 = TO PII IITIT Table 7 [me em fw fe a Char no. from 1 7 mn TI PPP of 11111 11] |. Properties [uus Rebound resili- | % 53.2 | 52.0 | 55.2 | 54.0 | 54.8 | 54.6 | 55.2 | 53.0 | 56.4 mm | PE Rebound resili- | % 61.6 | 58.4 | 57.2 | 59.4 | 58.8 | 57.0 | 58.4 | 55.0 | 58.2 e | [PPT ve a fa a a fs a a As further working examples the hydrochars reported in tables 2 to 4 may further- more be employed in the rubber mixture according to the invention.
    List of reference numerals (Part of the description) 1 band for carbonyl compound C=O (in FTIR spectrum) 2 band for C=C double bond (in FTIR spectrum) 3 band for oxygen-containing functional groups -O- (in FTIR spec- trum) 4 section of the FTIR spectrum for the starting substance coconut husk flour 5 section of the FTIR spectrum for hydrochar: HTC (12 h, 180°C) 6 section of the FTIR spectrum for salt hydrochar: HTC (12 h, 180*C) with zinc chloride 7 section of the FTIR spectrum for activated salt hydrochar: HTC (12 h, 180°C) with lithium chloride/zinc chloride and activated (1 h, 500°C) with steam 8 section of the FTIR spectrum for carbon black N 660
    PATENTTIVAATIMUKSET
    1. Rikin avulla silloitettava kautsu- seos, joka sisältää ainakin seuraavia aineosia: - vähintään yhtä dieenikautsua; - vähintään yhtä hiiltä (HTC-hiiltä), joka on valmistettu karbonoimalla hydrotermisesti vähintään yksi lähtöaine, - jolloin hydrotermisessä karbonoinnissa käy- tetään vähintään yhtä metallihalogenidia, jolloin hyd- roterminen karbonointi toteutetaan 210 - 230*C:n 1läm- pötilassa, ja jossa hiilen typpipinta-ala (BET-pinta- ala DIN ISO 9277:n mukaan) on 20 - 200 m2/g.
  2. 2. Patenttivaatimuksen 1 mukainen rikin avulla silloitettava kautsuseos, tunnettu siitä, että metallihalogenidi on ainakin ZnC1l,.
  3. 3. Patenttivaatimuksen 1 tai 2 mukainen rikin avulla silloitettava kautsuseos, tunnettu siitä, että ainakin yhtenä metallihalogenidina käyte- tään suolaa, joka on valittu ryhmästä, joka koostuu LiCl:sta, NaCl:sta ja KCl:sta.
  4. 4. Jonkin edellä esitetyistä patentti- vaatimuksista mukainen rikin avulla silloitettava kaut- suseos, tunnettu siitä, että lähtöaineena käyte- tään vähintään yhtä biomassaa ja/tai sen hajoamistuo- tetta (hajoamistuotteita).
  5. 5. Patenttivaatimuksen 4 mukainen rikin avulla silloitettava kautsuseos, tunnettu siitä, että biomassa on valittu ryhmästä, joka koostuu viljan- jyvien kuorista, pähkinänkuorista, hedelmien kuorista, kasvien leikkuujätteestä, puujätteistä, kuten sahajau- hosta, ja levistä.
  6. 6. Jonkin edellä esitetyistä patentti- vaatimuksista mukainen rikin avulla silloitettava kaut- suseos, tunnettu siitä, että ainakin yksi lähtö- aine on valittu ryhmästä, joka koostuu ligniinistä,
    selluloosasta, hemiselluloosasta ja sokerista, eritvi- sesti glukoosista.
  7. 7. Jonkin edellä esitetyistä patentti- vaatimuksista mukainen rikin avulla silloitettava kaut- suseos, tunnettu siitä, että hydroterminen karbo- nointi toteutetaan 2—20 bar:n paineessa.
  8. 8. Jonkin edellä esitetyistä patentti- vaatimuksista mukainen rikin avulla silloitettava kaut- suseos, tunnettu siitä, että se ei sisällä HTC- hiilen ohella mitään muuta lujittavaa täyteainetta, eri- tyisesti 0 phr nokimustaa ja 0 phr piihappoa.
  9. 9. Jonkin patenttivaatimuksen 1-7 mukai- nen rikin avulla silloitettava kautsuseos, tun - nettu siitä, että se sisältää vähintään yhtä muuta lujittavaa täyteainetta, joka on valittu piihaposta ja nokimustasta.
  10. 10. Jonkin edellä esitetyistä patentti- vaatimuksista mukainen rikin avulla silloitettava kaut- suseos, tunnettu siitä, että se sisältää 5-100 phr vähintään yhtä HTC-hiiltä.
  11. 11. Vulkanoitu kumi, joka on saatu rikki- vulkanoimalla vähintään yksi jonkin patenttivaatimuk- sista 1-10 mukainen kautsuseos.
  12. 12. Ajoneuvon rengas, jossa on vähintään yhdessä rakenneosassa vähintään yhtä patenttivaatimuk- sen 11 mukaista vulkanoitua kumia.
  13. 13. Patenttivaatimuksen 12 mukainen ajo- neuvon rengas, jolloin se käsittää vulkanoitua kumia ainakin sivuseinässä ja/tai laippaprofiilissa (Hornpro- fil) ja/tai sisemmässä rakenneosassa.
FIEP17195625.3T 2017-10-10 2017-10-10 Rikin avulla silloitettava kautsuseos, kautsuseoksen vulkanoitu kumi ja ajoneuvon rengas FI3470457T4 (fi)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP17195625.3A EP3470457B2 (de) 2017-10-10 2017-10-10 Schwefelvernetzbare kautschukmischung, vulkanisat der kautschukmischung und fahrzeugreifen

Publications (1)

Publication Number Publication Date
FI3470457T4 true FI3470457T4 (fi) 2023-12-19

Family

ID=60191092

Family Applications (1)

Application Number Title Priority Date Filing Date
FIEP17195625.3T FI3470457T4 (fi) 2017-10-10 2017-10-10 Rikin avulla silloitettava kautsuseos, kautsuseoksen vulkanoitu kumi ja ajoneuvon rengas

Country Status (5)

Country Link
US (1) US11952494B2 (fi)
EP (1) EP3470457B2 (fi)
ES (1) ES2862748T5 (fi)
FI (1) FI3470457T4 (fi)
WO (1) WO2019072431A1 (fi)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020223404A1 (en) * 2019-04-29 2020-11-05 Bridgestone Corporation Sidewall supports for pneumatic tires
US20220227968A1 (en) * 2019-04-30 2022-07-21 Firestone Industrial Products Company, Llc Air spring bellows made by processes employing a eutectic mixture
ES2950044T3 (es) * 2020-09-23 2023-10-04 Suncoal Ind Gmbh Composición de caucho para un revestimiento interior para neumáticos de vehículos
CA3220448A1 (en) 2021-05-20 2022-11-24 Suncoal Industries Gmbh Organic fillers modified with organosilanes and rubber compositions containing the same
JP2024518131A (ja) 2021-05-20 2024-04-24 サンコール・インダストリーズ・ゲーエムベーハー 表面修飾有機充填剤及びそれを含有するゴム組成物
AU2022334874A1 (en) 2021-08-23 2024-02-22 Suncoal Industries Gmbh Peroxide-crosslinkable rubber compositions containing organic fillers
CN113769709B (zh) * 2021-09-26 2022-08-26 塔里木大学 一种枣树枝条制备改性生物炭吸附材料的制备方法
AU2022356231A1 (en) 2021-09-28 2024-03-14 Suncoal Industries Gmbh Sulfur-crosslinkable rubber composition containing organic fillers and organosilane
CN114014320A (zh) * 2021-11-18 2022-02-08 兰州城市学院 一种利用藻类生物质制备碳硅复合材料的方法及在锂离子电池中的应用
WO2023180405A1 (de) 2022-03-22 2023-09-28 Suncoal Industries Gmbh Kautschukzusammensetzung für einen innerliner für fahrzeugluftreifen
WO2024105237A1 (en) 2022-11-18 2024-05-23 Suncoal Industries Gmbh Organic fillers with thioether linkages

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9806096B1 (pt) 1997-08-21 2009-01-13 mercaptosilano bloqueado; processo para a manufatura de uma borracha com carga; processo para a manufatura de um mercaptosilano bloqueado; composiÇço de borracha; e silano.
DE102006004062A1 (de) 2006-01-28 2007-08-09 Degussa Gmbh Kautschukmischungen
US7968636B2 (en) 2006-12-28 2011-06-28 Continental Ag Tire compositions and components containing silated cyclic core polysulfides
US7968633B2 (en) 2006-12-28 2011-06-28 Continental Ag Tire compositions and components containing free-flowing filler compositions
US7968634B2 (en) 2006-12-28 2011-06-28 Continental Ag Tire compositions and components containing silated core polysulfides
US7968635B2 (en) 2006-12-28 2011-06-28 Continental Ag Tire compositions and components containing free-flowing filler compositions
PL2131953T3 (pl) 2007-02-08 2019-07-31 Grenol Ip Gmbh Hydrotermalne karbonizowanie biomasy
US20100101142A1 (en) 2007-03-22 2010-04-29 Fraunhofer=Gellschaft Zur Forderung Der Angewandten Forschung E. V Method for the wet-chemical transformation of biomass by hydrothermal carbonization
AU2009237607A1 (en) 2008-04-17 2009-10-22 Csl Carbon Solutions Ltd. Process for converting biomass to coal-like material using hydrothermal carbonisation
FR2930188B1 (fr) 2008-04-18 2013-09-20 Snecma Procede pour ebavurer une piece en matiere ceramique.
CA2729267A1 (en) 2008-06-23 2010-01-21 Csl Carbon Solutions Ltd. Process for the preparation of hydrothermal hybrid material from biomass, and hydrothermal hybrid material obtainable by the process
RU2011119468A (ru) 2008-10-16 2012-11-27 Эвоник Карбон Блэк Гмбх Сажа, способ ее получения и ее применение
JP2012522629A (ja) 2009-04-01 2012-09-27 サンコール・インダストリーズ・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 再生可能原料および有機残留物の水熱炭化方法
WO2011017362A1 (en) * 2009-08-03 2011-02-10 The Gates Corporation Method of reinforcing rubber and rubber composition
JP2012012456A (ja) 2010-06-30 2012-01-19 Sumitomo Chemical Co Ltd Ｓ−（３−アミノプロピル）チオ硫酸および／またはその金属塩の使用方法
EP2474591A1 (en) 2011-01-10 2012-07-11 CSL Carbon Solutions Ltd Synthesis of artificial humic matter by hydrothermal carbonization
US20130004408A1 (en) * 2011-06-30 2013-01-03 Rubal Dua Moderate Temperature Synthesis of Mesoporous Carbon
JP2013124346A (ja) * 2011-12-16 2013-06-24 Sumitomo Chemical Co Ltd ゴム組成物
FI126849B (fi) 2012-12-19 2017-06-15 Teknologian Tutkimuskeskus Vtt Oy Menetelmä korkean moolimassan biomateriaalien hydrotermiseen käsittelyyn
FI126818B (fi) 2015-02-06 2017-06-15 Valmet Technologies Oy Menetelmä ligniinipohjaisen materiaalin käsittelemiseksi
DE102016201801A1 (de) * 2015-11-21 2017-05-24 Suncoal Industries Gmbh Partikelförmiges Kohlenstoffmaterial herstellbar aus nachwachsenden Rohstoffen und Verfahren zu dessen Herstellung
EP3243877B1 (en) 2016-05-09 2018-03-14 Nokian Renkaat Oyj A tyre comprising hydrothermally carbonized lignin

Also Published As

Publication number Publication date
EP3470457A1 (de) 2019-04-17
US20200308372A1 (en) 2020-10-01
US11952494B2 (en) 2024-04-09
EP3470457B1 (de) 2021-01-06
ES2862748T5 (es) 2024-05-07
ES2862748T3 (es) 2021-10-07
WO2019072431A1 (de) 2019-04-18
EP3470457B2 (de) 2023-09-20

Similar Documents

Publication Publication Date Title
US11952494B2 (en) Sulfur-crosslinkable rubber mixture, vulcanizate of the rubber mixture, and vehicle tire
JP6799665B2 (ja) ゴムブレンド、硫黄架橋性ゴム混合物、および車両用タイヤ
JP6815481B2 (ja) 硫黄架橋性ゴム混合物および車両用タイヤ
US11326028B2 (en) Sulfur-crosslinked rubber mixture for vehicle tires, containing carbon nanotubes (CNT), vehicle tire having the sulfur-crosslinked rubber mixture, and method for producing the sulfur-crosslinked rubber mixture containing carbon nanotubes
JP6788730B2 (ja) ゴムブレンド、硫黄架橋性ゴム混合物、および車両用タイヤ
JP6378466B1 (ja) ゴム混合物および車両タイヤ
JP7239618B2 (ja) 硫黄架橋可能なゴム混合物、加硫物及び車両タイヤ
US11015041B2 (en) Rubber blend, sulfur-crosslinkable rubber mixture, and vehicle tire
CN111742003A (zh) 硫可交联的橡胶混合物、橡胶混合物的硫化橡胶和车辆轮胎
US11261312B2 (en) Rubber blend, sulfur-crosslinkable rubber mixture, and vehicle tire
JP6916864B2 (ja) 硫黄架橋性ゴム混合物および車両用タイヤ
US11325988B2 (en) Sulfur-crosslinkable rubber mixture, vulcanizate of the rubber mixture, and vehicle tire
JP6799670B2 (ja) ゴムブレンド、硫黄架橋性ゴム混合物、および車両用タイヤ
JP6799669B2 (ja) 硫黄架橋性ゴム混合物および車両用タイヤ
JP6864078B2 (ja) ゴムブレンド、硫黄架橋性ゴム混合物および車両用タイヤ
US20220145049A1 (en) Rubber blend, sulfur-crosslinkable rubber mixture, and vehicle tire