FI20070618A - Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma - Google Patents

Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma Download PDF

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Publication number
FI20070618A
FI20070618A FI20070618A FI20070618A FI20070618A FI 20070618 A FI20070618 A FI 20070618A FI 20070618 A FI20070618 A FI 20070618A FI 20070618 A FI20070618 A FI 20070618A FI 20070618 A FI20070618 A FI 20070618A
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FI
Finland
Prior art keywords
product
titanium dioxide
preparation
microcrystalline titanium
well dispersing
Prior art date
Application number
FI20070618A
Other languages
English (en)
Finnish (fi)
Other versions
FI124294B (sv
FI20070618A0 (sv
Inventor
Ralf-Johan Lamminmaeki
Esa Latva-Nirva
Riitta Linho
Johanna Niinimaeki
Visa Vehmanen
Original Assignee
Kemira Pigments Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kemira Pigments Oy filed Critical Kemira Pigments Oy
Priority to FI20070618A priority Critical patent/FI124294B/sv
Publication of FI20070618A0 publication Critical patent/FI20070618A0/sv
Priority to BRPI0815556A priority patent/BRPI0815556B1/pt
Priority to US12/673,360 priority patent/US8182602B2/en
Priority to EP08787739A priority patent/EP2178798B1/en
Priority to AT08787739T priority patent/ATE554053T1/de
Priority to JP2010520605A priority patent/JP5351892B2/ja
Priority to PCT/FI2008/050466 priority patent/WO2009022061A2/en
Publication of FI20070618A publication Critical patent/FI20070618A/sv
Application granted granted Critical
Publication of FI124294B publication Critical patent/FI124294B/sv

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3653—Treatment with inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C09C1/3623—Grinding
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C09C1/363—Drying, calcination
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3653—Treatment with inorganic compounds
    • C09C1/3661—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3669—Treatment with low-molecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D15/00—Woodstains
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
FI20070618A 2007-08-16 2007-08-16 Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma FI124294B (sv)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FI20070618A FI124294B (sv) 2007-08-16 2007-08-16 Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma
BRPI0815556A BRPI0815556B1 (pt) 2007-08-16 2008-08-15 método de preparação de um produto de dióxido de titânio microcristalino de boa dispersibilidade, produto de dióxido de titânio, tinta de efeito e composição de laca de madeira contendo o referido produto
US12/673,360 US8182602B2 (en) 2007-08-16 2008-08-15 Method of preparing a well-dispersable microcrystalline titanium dioxide product, the product, and the use thereof
EP08787739A EP2178798B1 (en) 2007-08-16 2008-08-15 Method of preparing a well-dispersable microcrystalline titanium dioxide product
AT08787739T ATE554053T1 (de) 2007-08-16 2008-08-15 Verfahren zur herstellung eines gut dispergierbaren mikrokristallinen titandioxid- produkts
JP2010520605A JP5351892B2 (ja) 2007-08-16 2008-08-15 分散良好な微結晶二酸化チタン生成物の調製方法、その生成物、およびその使用
PCT/FI2008/050466 WO2009022061A2 (en) 2007-08-16 2008-08-15 Method of preparing a well-dispersable microcrystalline titanium dioxide product, the product, and the use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20070618 2007-08-16
FI20070618A FI124294B (sv) 2007-08-16 2007-08-16 Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma

Publications (3)

Publication Number Publication Date
FI20070618A0 FI20070618A0 (sv) 2007-08-16
FI20070618A true FI20070618A (sv) 2009-02-17
FI124294B FI124294B (sv) 2014-06-13

Family

ID=38468687

Family Applications (1)

Application Number Title Priority Date Filing Date
FI20070618A FI124294B (sv) 2007-08-16 2007-08-16 Förfarande för framställning av en väl dispergerande mikrokristallin titandioxidprodukt, produkt och användning av densamma

Country Status (7)

Country Link
US (1) US8182602B2 (sv)
EP (1) EP2178798B1 (sv)
JP (1) JP5351892B2 (sv)
AT (1) ATE554053T1 (sv)
BR (1) BRPI0815556B1 (sv)
FI (1) FI124294B (sv)
WO (1) WO2009022061A2 (sv)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI122244B (sv) * 2008-07-07 2011-10-31 Sachtleben Pigments Oy Förfarande för framställning av rutilformad titanoxid med liten kristallstorlek och produkt som tillverkats medelst förfarandet
CN103025664B (zh) * 2010-08-17 2014-11-12 堺化学工业株式会社 金红石型氧化钛粒子的分散体的制备方法
CN102580713B (zh) * 2012-01-18 2013-09-18 常州大学 一种二氧化钛/硅酸盐矿物纳米复合材料的制备方法
CN105038327A (zh) * 2014-11-26 2015-11-11 安徽池州博源非金属矿研发中心有限公司 一种白云石复合钛白粉的制备方法
US10703913B2 (en) 2015-12-25 2020-07-07 Shiseido Company, Ltd. Titanium dioxide powder and cosmetic formulated therewith
EP3436530A1 (en) 2016-03-29 2019-02-06 Venator P&A Finland Oy A method for treating titanium dioxide particles, a titanium dioxide particle and uses of the same
CN106018294B (zh) * 2016-06-22 2019-07-26 攀钢集团攀枝花钢铁研究院有限公司 一种检测纳米二氧化钛随角异色性能的方法
JP6939766B2 (ja) * 2018-12-27 2021-09-22 Ｊｆｅスチール株式会社 方向性電磁鋼板用焼鈍分離剤および方向性電磁鋼板の製造方法
JP6939767B2 (ja) 2018-12-27 2021-09-22 Ｊｆｅスチール株式会社 方向性電磁鋼板用焼鈍分離剤および方向性電磁鋼板の製造方法
WO2020150909A1 (zh) 2019-01-22 2020-07-30 成都千砺金科技创新有限公司 一种自拟合纳米催化污水处理剂的生产方法
CN113387383B (zh) * 2021-05-24 2022-10-28 龙佰四川钛业有限公司 一种高流动性钛白粉闪干料的生产方法
CN117089226B (zh) * 2023-10-17 2024-02-02 成都先进金属材料产业技术研究院股份有限公司 一种提高涂料用钛白粉耐候性的包膜方法

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
US2448683A (en) * 1944-02-09 1948-09-07 Du Pont Titanium oxide production
CA962142A (en) * 1971-06-07 1975-02-04 Canadian Titanium Pigments Limited Ultra-violet screener
FI57124C (fi) 1978-04-19 1980-06-10 Kemira Oy Ytbelagt titandioxidpigment och foerfarande foer dess framstaellning
FI62130C (fi) * 1980-07-18 1982-11-10 Kemira Oy Ytbelagt titandioxidpigment och foerfarande foer framstaellning daerav
US4753829A (en) 1986-11-19 1988-06-28 Basf Corporation Opalescent automotive paint compositions containing microtitanium dioxide pigment
FI89900C (sv) * 1990-03-01 1993-12-10 Kemira Oy Nytt framställningsförfarande av titandioxid
JP4084463B2 (ja) * 1998-06-05 2008-04-30 道雄 松村 光触媒用酸化チタン粉末
US6440383B1 (en) * 1999-06-24 2002-08-27 Altair Nanomaterials Inc. Processing aqueous titanium chloride solutions to ultrafine titanium dioxide
US6528568B2 (en) * 2001-02-23 2003-03-04 Millennium Inorganic Chemicals, Inc. Method for manufacturing high opacity, durable pigment
DE10205920A1 (de) 2002-02-12 2003-08-21 Itn Nanovation Gmbh Nanoskaliger Rutil, sowie Verfahren zu dessen Herstellung
US20050232851A1 (en) 2003-11-13 2005-10-20 Jan Prochazka Process to make rutile pigment from aqueous titanium solutions
JP2005187543A (ja) 2003-12-24 2005-07-14 Kansai Paint Co Ltd 熱硬化型メタリック粉体塗料組成物及びメタリック粉体塗膜形成方法
FI117754B (sv) * 2004-02-06 2007-02-15 Kemira Pigments Oy Titanoxidprodukt, förfarande för framställning därav och dess användning som fotokatalyt
KR100977349B1 (ko) * 2005-09-30 2010-08-20 사까이가가꾸고오교가부시끼가이샤 루틸형 미립자 산화티탄의 제조 방법

Also Published As

Publication number Publication date
JP5351892B2 (ja) 2013-11-27
EP2178798B1 (en) 2012-04-18
FI124294B (sv) 2014-06-13
ATE554053T1 (de) 2012-05-15
BRPI0815556A8 (pt) 2018-04-03
BRPI0815556A2 (pt) 2015-02-18
US8182602B2 (en) 2012-05-22
US20110192322A1 (en) 2011-08-11
JP2010536689A (ja) 2010-12-02
BRPI0815556B1 (pt) 2018-10-30
FI20070618A0 (sv) 2007-08-16
WO2009022061A2 (en) 2009-02-19
EP2178798A2 (en) 2010-04-28
WO2009022061A3 (en) 2009-09-11

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