FI20020784A - Extraction of valuable nickel and cobalt fractions from flotation enrichment concentrates from sulfide ore using chloride-based oxidative pressure leaching in sulfuric acid - Google Patents

Extraction of valuable nickel and cobalt fractions from flotation enrichment concentrates from sulfide ore using chloride-based oxidative pressure leaching in sulfuric acid Download PDF

Info

Publication number
FI20020784A
FI20020784A FI20020784A FI20020784A FI20020784A FI 20020784 A FI20020784 A FI 20020784A FI 20020784 A FI20020784 A FI 20020784A FI 20020784 A FI20020784 A FI 20020784A FI 20020784 A FI20020784 A FI 20020784A
Authority
FI
Finland
Prior art keywords
nickel
extraction
chloride
sulfuric acid
cobalt
Prior art date
Application number
FI20020784A
Other languages
Finnish (fi)
Swedish (sv)
Other versions
FI123376B (en
Inventor
Derek G E Kerfoot
Eberhard Krause
Bruce John Love
Avinash Singhal
Original Assignee
Inco Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inco Ltd filed Critical Inco Ltd
Publication of FI20020784A publication Critical patent/FI20020784A/en
Application granted granted Critical
Publication of FI123376B publication Critical patent/FI123376B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0453Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0407Leaching processes
    • C22B23/0415Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/0423Halogenated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0407Leaching processes
    • C22B23/0415Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/043Sulfurated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

A hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate. The process involves forming a slurry of the sulfidic flotation concentrate in an acid solution, and subjecting the slurried flotation concentrate to a chlorine leach at atmospheric pressure followed by an oxidative pressure leach. After liquid-solids separation and purification of the concentrate resulting in the removal of copper and cobalt, the nickel-containing solution is directly treated by electrowinning to recover nickel cathode therefrom.
FI20020784A 2000-09-18 2002-04-23 Extraction of valuable nickel and cobalt fractions from flotation enrichment concentrates from sulfide ore using chloride-based oxidative pressure leaching in sulfuric acid FI123376B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US66447500 2000-09-18
US09/664,475 US6428604B1 (en) 2000-09-18 2000-09-18 Hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate
CA0100227 2001-02-26
PCT/CA2001/000227 WO2002024966A1 (en) 2000-09-18 2001-02-26 Recovery of nickel and cobalt values from a sulfidic flotation concentrate by chloride assisted oxidative pressure leaching in sulfuric acid

Publications (2)

Publication Number Publication Date
FI20020784A true FI20020784A (en) 2002-04-23
FI123376B FI123376B (en) 2013-03-15

Family

ID=24666118

Family Applications (1)

Application Number Title Priority Date Filing Date
FI20020784A FI123376B (en) 2000-09-18 2002-04-23 Extraction of valuable nickel and cobalt fractions from flotation enrichment concentrates from sulfide ore using chloride-based oxidative pressure leaching in sulfuric acid

Country Status (13)

Country Link
US (2) US6428604B1 (en)
EP (1) EP1325165B1 (en)
JP (1) JP3946633B2 (en)
CN (1) CN1210417C (en)
AT (1) ATE338833T1 (en)
AU (1) AU774519B2 (en)
BR (1) BR0107217A (en)
CA (1) CA2376883C (en)
DE (1) DE60122914T2 (en)
FI (1) FI123376B (en)
RU (1) RU2221881C1 (en)
WO (1) WO2002024966A1 (en)
ZA (1) ZA200202941B (en)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60116323D1 (en) * 2000-07-25 2006-02-02 Phelps Dodge Corp Phoenix PROCESS FOR OBTAINING COPPER FROM SULPHIDE ORCHES USING FINE GRINDING AND EXTRACTION UNDER PRESSURE AT MEDIUM HIGH TEMPERATURES
US6428604B1 (en) * 2000-09-18 2002-08-06 Inco Limited Hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate
US7476308B2 (en) * 2001-07-25 2009-01-13 Phelps Dodge Corporation Process for multiple stage direct electrowinning of copper
US20050126923A1 (en) * 2001-07-25 2005-06-16 Phelps Dodge Corporation Process for recovery of copper from copper-bearing material using medium temperature pressure leaching, direct electrowinning and solvent/solution extraction
US6863825B2 (en) 2003-01-29 2005-03-08 Union Oil Company Of California Process for removing arsenic from aqueous streams
US20040156765A1 (en) * 2003-02-12 2004-08-12 Nichromet Extraction Inc. Gold and silver recovery from polymetallic sulfides by treatment with halogens
CN100420760C (en) * 2004-05-21 2008-09-24 Wmc资源有限公司 Recovery of nickel
US7736487B2 (en) 2004-10-29 2010-06-15 Freeport-Mcmoran Corporation Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction
EA010942B1 (en) * 2004-10-29 2008-12-30 Фелпс Додж Корпорейшн Process for recovery of copper from copper-bearing material
JP2008540834A (en) * 2005-05-13 2008-11-20 ビーエイチピー・ビリトン・エスエスエム・テクノロジー・ピーティーワイ・リミテッド An improved method for heap leaching of nickel-containing ores
EA014105B1 (en) * 2005-10-03 2010-10-29 Ототек Оюй Processing of nickel ore or concentrates with sodium chloride
BRPI0505544B1 (en) * 2005-11-10 2014-02-04 COMBINED Leaching Process
US7572317B2 (en) * 2005-11-10 2009-08-11 Barrick Gold Corporation Thiosulfate generation in situ in precious metal recovery
US8066874B2 (en) 2006-12-28 2011-11-29 Molycorp Minerals, Llc Apparatus for treating a flow of an aqueous solution containing arsenic
US20080308429A1 (en) * 2007-06-18 2008-12-18 Cvrd Inco Limited Method for improving cathode morphology
US7998441B2 (en) * 2007-09-20 2011-08-16 Cvrd Inco Limited Method for selective removal of cadmium
US8252087B2 (en) 2007-10-31 2012-08-28 Molycorp Minerals, Llc Process and apparatus for treating a gas containing a contaminant
US8349764B2 (en) 2007-10-31 2013-01-08 Molycorp Minerals, Llc Composition for treating a fluid
CN101760616B (en) * 2008-12-02 2011-08-10 中国恩菲工程技术有限公司 Leaching method of cobalt-containing ore
CN101705371B (en) * 2009-11-20 2011-04-06 北京矿冶研究总院 Method for extracting cobalt from copper-cobalt sulfide ore
RU2444573C2 (en) * 2010-01-20 2012-03-10 Открытое акционерное общество "Кольская горно-металлургическая компания" Manufacturing method of concentrate of precious metals from sulphide copper-nickel raw material
CA2788369A1 (en) * 2010-01-28 2011-08-04 Mcmaster University Nanoparticle flotation collectors
FI122188B (en) * 2010-03-18 2011-09-30 Outotec Oyj Hydrometallurgical process for the production of metallic nickel
JP5445777B2 (en) * 2010-07-28 2014-03-19 住友金属鉱山株式会社 Method for producing ferronickel smelting raw material from low-grade nickel oxide ore
CN102002586B (en) * 2010-12-04 2012-09-26 金川集团有限公司 Nickel-containing high-cobalt sulfide leaching technology
PT2668303T (en) * 2011-01-25 2019-07-15 Univ Queensland Improved method of ore processing
US10662503B2 (en) * 2011-01-25 2020-05-26 The University Of Queensland Method of ore processing using mixture including acidic leach solution and oxidizing agent
US9233863B2 (en) 2011-04-13 2016-01-12 Molycorp Minerals, Llc Rare earth removal of hydrated and hydroxyl species
CN102206834B (en) * 2011-05-03 2012-12-26 四川省尼科国润新材料有限公司 Method for directly producing electrolytic nickel by using low nickel matte
CN102367175A (en) * 2011-07-01 2012-03-07 王嘉兴 Method for preparing copper sulphide, copper hydroxide and sodium chloride from waste copper sludge
CN102367179A (en) * 2011-07-01 2012-03-07 王嘉兴 Method for preparing copper sulfide, cupric chloride and sodium chloride from waste residue copper sludge
CN102344163A (en) * 2011-07-01 2012-02-08 王嘉兴 Method for preparing cupric sulfide, copper carbonate and sodium chloride from waste residue copper sludge
CN102344118A (en) * 2011-07-01 2012-02-08 王嘉兴 Method for preparing copper sulfide, copper hydroxide and sodium chloride by waste residue copper sludge
CN102367176A (en) * 2011-07-01 2012-03-07 王嘉兴 Method for preparing copper sulphide, cupric phosphate and sodium phosphate from waste copper sludge
CN102367173A (en) * 2011-07-01 2012-03-07 王嘉兴 Method for preparing copper sulphide and sodium chloride by utilizing waste residue copper sludge
FI20110279A0 (en) 2011-08-29 2011-08-29 Outotec Oyj A method for recovering metals from material containing them
CN103958416B (en) * 2011-12-26 2016-04-13 住友金属矿山株式会社 The manufacture method of rose vitriol
JP5842684B2 (en) * 2012-03-13 2016-01-13 住友金属鉱山株式会社 Hydrometallurgical process
JP5424139B2 (en) * 2012-03-19 2014-02-26 住友金属鉱山株式会社 Method for producing hematite for iron making
FI124883B (en) 2012-12-20 2015-03-13 Outotec Oyj Method and apparatus for acid granulation of metallic rock
CN103272700B (en) * 2013-06-07 2014-11-05 浙江华友钴业股份有限公司 Method for flotation and recycling of copper and cobalt from copper-cobalt ore acid leached smelt slag
CN103386359A (en) * 2013-07-19 2013-11-13 广州有色金属研究院 Beneficiation method for copper oxide cobalt ores
JP5440823B1 (en) * 2013-09-18 2014-03-12 住友金属鉱山株式会社 Method for producing hematite for iron making
CN103725887A (en) * 2013-12-13 2014-04-16 金川集团股份有限公司 Method for leaching copper sponge
BR112016020631A2 (en) 2014-03-07 2018-05-15 Secure Natural Resources Llc cerium (iv) oxide with exceptional arsenic removal properties
JP5884870B1 (en) * 2014-08-13 2016-03-15 住友金属鉱山株式会社 How to recover nickel
US10457565B2 (en) 2014-09-18 2019-10-29 Sumitomo Metal Mining Co., Ltd. Production method for hematite for iron production
CN107429311B (en) * 2014-12-19 2019-09-03 Fl史密斯公司 Method for Rapid Leaching chalcopyrite
RU2613823C1 (en) * 2015-12-18 2017-03-21 Федеральное государственное бюджетное учреждение науки Институт химии и технологии редких элементов и минерального сырья им. И.В. Тананаева Кольского научного центра Российской академии наук (ИХТРЭМС КНЦ РАН) Method for precious metals concentrate production from copper-nickel converter matte
WO2017197417A1 (en) * 2016-05-09 2017-11-16 Mintek Method of recovering a target metal
JP7062996B2 (en) * 2017-03-29 2022-05-09 住友金属鉱山株式会社 A method for storing and quantifying a solution containing thionic acid, and a method for preparing a sample solution containing thionic acid and its preparation.
JP6957974B2 (en) * 2017-05-23 2021-11-02 住友金属鉱山株式会社 Chlorine leaching method, electronickel manufacturing method
KR20200060695A (en) * 2017-06-08 2020-06-01 어반 마이닝 피티와이 엘티디 Method for recovery of cobalt, lithium and other metals from waste lithium-based batteries and other supplies
CN108118149B (en) * 2017-12-14 2019-07-19 中南大学 A method of power battery anode material presoma is prepared with nickel sulfide concentrate
CN108103311A (en) * 2017-12-14 2018-06-01 中南大学 A kind of Wet-smelting method of cupro-nickel composite ore
AU2019428963B2 (en) * 2019-02-13 2023-08-03 KEMCO (Korea Energy Materials Company) Economical method, using combination of wet and dry processes, for smelting nickel from nickel sulfide ores
CN112680602A (en) * 2020-12-18 2021-04-20 衢州华友钴新材料有限公司 Treatment method for improving leaching efficiency of copper-containing sulfide ore
CN113957264A (en) * 2021-09-13 2022-01-21 广东邦普循环科技有限公司 Method for preparing nickel sulfate from low grade nickel matte
CN116568831A (en) * 2021-11-26 2023-08-08 深圳市坤鹏冶金工程技术有限公司 Method for extracting nickel sulfate from high nickel matte
WO2024103106A1 (en) * 2022-11-14 2024-05-23 Hydromet WA Pty Limited "method for the preferential leach of value metals from sulphide concentrates"
CN115818739B (en) * 2022-12-22 2024-07-09 广西中伟新能源科技有限公司 Method for preparing nickel sulfate by using high nickel matte

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4039406A (en) 1973-08-10 1977-08-02 Noranda Mines Limited Recovering copper from concentrates with insoluble sulfate forming leach
JPS50115614A (en) * 1974-02-16 1975-09-10
US3981962A (en) * 1975-06-30 1976-09-21 The United States Of America As Represented By The Secretary Of The Interior Decomposition leach of sulfide ores with chlorine and oxygen
CA1092056A (en) 1977-10-11 1980-12-23 Victor A. Ettel Electrowinning cell with bagged anode
CA1107678A (en) 1978-04-12 1981-08-25 Kohur N. Subramanian Nickel recovery from sulfur-deficient mattes
CA1125228A (en) 1979-10-10 1982-06-08 Daniel P. Young Process for electrowinning nickel or cobalt
US4384940A (en) * 1982-01-21 1983-05-24 Inco Limited Chlorine leaching of nickel-cobalt-iron sulphides
NO833784L (en) * 1983-10-18 1985-04-19 Thomas Thomassen AUTOCLAV CHLORINE CLUTCH OF COPPER SULFIDE CONCENTRATES
EP0248518B1 (en) * 1986-04-24 1991-11-13 Falconbridge Limited Separation of nickel from copper in autoclave
CA2071626C (en) 1991-10-25 2001-08-14 Ian James Corrans Activation of a mineral species
US5431788A (en) 1993-06-28 1995-07-11 Cominco Engineering Services Ltd. Chloride assisted hydrometallurgical copper extraction
US5650057A (en) 1993-07-29 1997-07-22 Cominco Engineering Services Ltd. Chloride assisted hydrometallurgical extraction of metal
US5902474A (en) 1993-07-29 1999-05-11 Cominco Engineering Services Ltd. Chloride assisted hydrometallurgical extraction of metal
US5874055A (en) 1993-07-29 1999-02-23 Cominco Engineering Services Ltd. Chloride assisted hydrometallurgical extraction of metal
US5855858A (en) 1993-07-29 1999-01-05 Cominco Engineering Services Ltd. Process for the recovery of nickel and/or cobalt from an ore or concentrate
US5378262A (en) * 1994-03-22 1995-01-03 Inco Limited Process for the extraction and separation of nickel and/or cobalt
CA2137124C (en) * 1994-12-01 1999-03-16 Tao Xue Pressure leaching of nickel and cobalt sulphides with chlorine under controlled redox potential conditions
GB9503877D0 (en) 1995-02-27 1995-04-19 Sherritt Inc Recovery of copper from sulphidic concentrates
AUPN191395A0 (en) * 1995-03-22 1995-04-27 M.I.M. Holdings Limited Atmospheric mineral leaching process
AUPN476695A0 (en) 1995-08-14 1995-09-07 Dominion Mining Limited Method of processing a copper mineral species
FI98073C (en) * 1995-08-14 1997-04-10 Outokumpu Eng Oy Process for the hydrometallurgical recovery of nickel from two different types of nickel stone
JPH10140257A (en) 1996-11-07 1998-05-26 Sumitomo Metal Mining Co Ltd Wet refining method of nickel by chlorine leaching electrolytic extracting method
US5993514A (en) * 1997-10-24 1999-11-30 Dynatec Corporation Process for upgrading copper sulphide residues containing nickel and iron
US6428604B1 (en) * 2000-09-18 2002-08-06 Inco Limited Hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate

Also Published As

Publication number Publication date
JP2004509232A (en) 2004-03-25
EP1325165B1 (en) 2006-09-06
CA2376883A1 (en) 2002-03-28
CN1210417C (en) 2005-07-13
DE60122914T2 (en) 2007-04-26
WO2002024966A1 (en) 2002-03-28
RU2221881C1 (en) 2004-01-20
ATE338833T1 (en) 2006-09-15
EP1325165A1 (en) 2003-07-09
RU2002113102A (en) 2004-01-27
AU774519B2 (en) 2004-07-01
US20030033906A1 (en) 2003-02-20
US6428604B1 (en) 2002-08-06
JP3946633B2 (en) 2007-07-18
BR0107217A (en) 2002-07-09
ZA200202941B (en) 2003-04-15
CN1392902A (en) 2003-01-22
AU3716901A (en) 2002-04-02
FI123376B (en) 2013-03-15
CA2376883C (en) 2002-12-03
DE60122914D1 (en) 2006-10-19
US6569224B2 (en) 2003-05-27

Similar Documents

Publication Publication Date Title
FI20020784A (en) Extraction of valuable nickel and cobalt fractions from flotation enrichment concentrates from sulfide ore using chloride-based oxidative pressure leaching in sulfuric acid
AU2006298625B2 (en) Processing of nickel sulphide ore or concentrates with sodium chloride
AU2008200206B2 (en) Integrated hydrometallurgical and pyrometallurgical processing of base-metal sulphides
WO1996041029A3 (en) Chloride assisted hydrometallurgical extraction of nickel and cobalt from sulphide ores
EA200401443A1 (en) METHOD OF LEATHERING LATERITE NICKEL ORE AT ATMOSPHERIC PRESSURE
ATE256202T1 (en) ION EXCHANGE RESIN PROCESS FOR EXTRACTING NICKEL AND COBALT FROM OXIDE ORE LEACHING SLUDGE
MX2007005089A (en) Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solvent/solution extraction.
WO2009072908A3 (en) Gold recovery system and process therefor
GB1374851A (en) Hydrometallurgical process for extraction of copper and sulphur from copper-iron sulphides
ATE405681T1 (en) METHOD FOR EXTRACTING NICKEL AND COBALT FROM LATERITE ORE
JP2008115429A (en) Method for recovering silver in hydrometallurgical copper refining process
US3463710A (en) Electrolytic recovery of copper from copper cyanide leaching solutions
GB1407520A (en) Electrolytic hydrometallurgical process to recover copper from sulphide ore concentrates
KR20030043957A (en) Pressure leaching process for zinc
Sole et al. The potential for recovery of cobalt from copper leach solutions
IE37546B1 (en) Recovery of metals
EA009453B1 (en) Method for processing sulfide ores containing precious metals
AU2004257844B2 (en) Method for processing sulfide ores containing precious metals
Parkinson The Ni--Co Connection
Mas Comparison of conventional and carbon in pulp leaching processes in gold hydrometallurgy
Schwarz et al. Pressure leaching of nickel-copper leach residue
Wang Separation of Cu, Ni and Co from ammonia solution by solvent extraction
Fugleberg Processing of a black schist ore by leaching and flotation
TH36765A (en) Metal extraction by chloride-assisted metallurgical processes from sulphide or laterite minerals.
ECSP982625A (en) HYDROMETALLURGICAL METAL EXTRACTION FACILITATED WITH CHLORIDE

Legal Events

Date Code Title Description
FG Patent granted

Ref document number: 123376

Country of ref document: FI

Kind code of ref document: B

MM Patent lapsed