ES8400399A1 - Procedimiento perfeccionado de preparacion de soluciones organicas practicamente anhidras de acidos percarboxilicos. - Google Patents
Procedimiento perfeccionado de preparacion de soluciones organicas practicamente anhidras de acidos percarboxilicos.Info
- Publication number
- ES8400399A1 ES8400399A1 ES518941A ES518941A ES8400399A1 ES 8400399 A1 ES8400399 A1 ES 8400399A1 ES 518941 A ES518941 A ES 518941A ES 518941 A ES518941 A ES 518941A ES 8400399 A1 ES8400399 A1 ES 8400399A1
- Authority
- ES
- Spain
- Prior art keywords
- water
- distillation
- percarboxylic acids
- hydrogen peroxide
- distillation column
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 150000007513 acids Chemical class 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 238000004821 distillation Methods 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000010533 azeotropic distillation Methods 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
- C07C409/10—Cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PREFECCIONADO DE SOLUCIONES ORGANICAS PRACTICAMENTE ANHIDRAS DE ACIDOS PERCARBOXILICOS.SE HACEN REACCIONAR SOLUCIONES ACUOSAS DE PEROXIDO DE HIDROGENO CON ACIDOS CARBOXILICOS MISCIBLES EN AGUA, EN PRESENCIA DE UN CATALIZADOR Y EN UN DISOLVENTE ORGANICO QUE PERMITE LA ELIMINACION CONTINUA POR DESTILACION AZEOTROPICA DEL AGUA DEL MEDIO DE REACCION. PARA ELLO SE INYECTA EN CONTINUO, EN CABEZA, DURANTE LA MAYOR PARTE DE LA REACCION UNA CANTIDAD DE AGUA TAL QUE EL REFLUJO LIQUIDO TENGA UNA COMPOSICION APROXIMADA A LA DE LOS VAPORES DEL HETERO-AZEOTROPO-AGUA-DISOLVENTEORGANICO. COMO CATALIZADOR SE EMPLEA UN ACIDO FUERTE TAL COMO EL SULFURICO EMPLEADO EN UNA CANTIDAD DE 0,0005 A 0,010 MOLES POR MOL DE PEROXIDO DE HIDROGENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8200407A FR2519634B1 (fr) | 1982-01-13 | 1982-01-13 | Perfectionnement aux procedes de synthese des acides percaboxyliques |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8400399A1 true ES8400399A1 (es) | 1983-10-16 |
ES518941A0 ES518941A0 (es) | 1983-10-16 |
Family
ID=9269925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES518941A Granted ES518941A0 (es) | 1982-01-13 | 1983-01-12 | Procedimiento perfeccionado de preparacion de soluciones organicas practicamente anhidras de acidos percarboxilicos. |
Country Status (12)
Country | Link |
---|---|
US (1) | US4459240A (es) |
EP (1) | EP0083894B1 (es) |
JP (1) | JPS58113173A (es) |
KR (1) | KR870000547B1 (es) |
AU (1) | AU556244B2 (es) |
BR (1) | BR8300114A (es) |
CA (1) | CA1186329A (es) |
DE (1) | DE3262728D1 (es) |
ES (1) | ES518941A0 (es) |
FR (1) | FR2519634B1 (es) |
MX (1) | MX162207A (es) |
ZA (1) | ZA83195B (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2624507B1 (fr) * | 1987-12-11 | 1990-06-15 | Rhone Poulenc Chimie | Procede de preparation de derives aromatiques hydroxyles par la reaction de baeyer-villiger |
US5206425A (en) * | 1990-03-20 | 1993-04-27 | Ube Industries, Ltd. | Process for preparing perpropionic acid solution |
GB9100216D0 (en) * | 1991-01-05 | 1991-02-20 | Bp Chem Int Ltd | Process |
CN1034500C (zh) * | 1991-09-20 | 1997-04-09 | 艾尔夫·阿托彻姆公司 | 过丙酸的制备方法 |
FR2800291B1 (fr) * | 1999-10-29 | 2004-07-09 | Atofina | Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres |
FR2930449B1 (fr) | 2008-04-29 | 2010-04-23 | Arkema France | Composition d'acide perpropionique stable en milieu basique |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2814641A (en) * | 1956-07-31 | 1957-11-26 | Union Carbide Corp | Process for producing peracids from aliphatic carboxylic acids |
GB803159A (en) * | 1956-07-31 | 1958-10-22 | Union Carbide Corp | Process for producing peracids from aliphatic carboxylic acids |
FR1390068A (fr) * | 1963-07-05 | 1965-02-19 | Pittsburgh Plate Glass Co | Procédé perfectionné de préparation d'acides percarboxyliques |
FR2421168A1 (fr) * | 1978-03-28 | 1979-10-26 | Propylox Sa | Procede pour la fabrication de peracides carboxyliques |
FR2460927A1 (fr) * | 1979-07-09 | 1981-01-30 | Ugine Kuhlmann | Nouveau procede de preparation d'acides percarboxyliques |
FR2464947A1 (fr) * | 1979-09-07 | 1981-03-20 | Ugine Kuhlmann | Procede de fabrication d'acides percarboxyliques |
-
1982
- 1982-01-13 FR FR8200407A patent/FR2519634B1/fr not_active Expired
- 1982-12-06 KR KR8205452A patent/KR870000547B1/ko active
- 1982-12-15 US US06/450,002 patent/US4459240A/en not_active Expired - Lifetime
- 1982-12-21 CA CA000418184A patent/CA1186329A/fr not_active Expired
- 1982-12-28 JP JP57227882A patent/JPS58113173A/ja active Granted
- 1982-12-29 EP EP82402395A patent/EP0083894B1/fr not_active Expired
- 1982-12-29 DE DE8282402395T patent/DE3262728D1/de not_active Expired
-
1983
- 1983-01-11 MX MX195880A patent/MX162207A/es unknown
- 1983-01-12 AU AU10361/83A patent/AU556244B2/en not_active Expired
- 1983-01-12 ZA ZA83195A patent/ZA83195B/xx unknown
- 1983-01-12 BR BR8300114A patent/BR8300114A/pt not_active IP Right Cessation
- 1983-01-12 ES ES518941A patent/ES518941A0/es active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2519634B1 (fr) | 1986-09-12 |
AU1036183A (en) | 1983-07-21 |
BR8300114A (pt) | 1983-10-04 |
CA1186329A (fr) | 1985-04-30 |
JPH0150227B2 (es) | 1989-10-27 |
MX162207A (es) | 1991-04-08 |
JPS58113173A (ja) | 1983-07-05 |
FR2519634A1 (fr) | 1983-07-18 |
ZA83195B (en) | 1983-10-26 |
KR840002806A (ko) | 1984-07-21 |
AU556244B2 (en) | 1986-10-30 |
DE3262728D1 (en) | 1985-04-25 |
KR870000547B1 (ko) | 1987-03-18 |
US4459240A (en) | 1984-07-10 |
EP0083894A1 (fr) | 1983-07-20 |
ES518941A0 (es) | 1983-10-16 |
EP0083894B1 (fr) | 1985-03-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20040601 |