ES8400387A1 - Procedimiento para preparar metilaminas. - Google Patents
Procedimiento para preparar metilaminas.Info
- Publication number
- ES8400387A1 ES8400387A1 ES515786A ES515786A ES8400387A1 ES 8400387 A1 ES8400387 A1 ES 8400387A1 ES 515786 A ES515786 A ES 515786A ES 515786 A ES515786 A ES 515786A ES 8400387 A1 ES8400387 A1 ES 8400387A1
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- methylamines
- manufacture
- binderless zeolite
- selective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000003956 methylamines Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR METILAMINAS.SE HACE REACCIONAR METANOL Y/O DIMETILETER CON AMONIACO, SOBRE UN CATALIZADOR QUE COMPRENDE ZEOLITA A, SIN AGLUTINANTE, EN LA FORMA ALCALINOTERREA O EN LA FORMA DE CALCIO; EL CATALIZADOR TIENE UN CONTENIDO EN METAL ALCALINO INFERIOR AL 4. DICHO CATALIZADOR ES ENVEJECIDO ANTES DE UTILIZARSE EN EL PROCESO. LA REACCION SE EFECTUA A UNA TEMPERATURA COMPRENDIDA ENTRE 325 A 400JC Y A UNA VELOCIDAD ESPACIAL HORARIA DE PESO DE ALCOHOL DEL ORDEN DE 0,2 A 0,75 HR-1 Y CON UNA RELACION N/R DE 0,5 A 2.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8128322 | 1981-09-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES515786A0 ES515786A0 (es) | 1983-11-01 |
ES8400387A1 true ES8400387A1 (es) | 1983-11-01 |
Family
ID=10524604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES515786A Expired ES8400387A1 (es) | 1981-09-18 | 1982-09-17 | Procedimiento para preparar metilaminas. |
Country Status (8)
Country | Link |
---|---|
US (1) | US4436938A (es) |
EP (1) | EP0076034B1 (es) |
JP (1) | JPS5869846A (es) |
AU (1) | AU562049B2 (es) |
CA (1) | CA1211759A (es) |
DE (1) | DE3263547D1 (es) |
ES (1) | ES8400387A1 (es) |
ZA (1) | ZA826475B (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57169445A (en) * | 1981-04-10 | 1982-10-19 | Nitto Chem Ind Co Ltd | Preparation of methylamine |
GB8303051D0 (en) * | 1983-02-04 | 1983-03-09 | Ici Plc | Inhibition and regeneration of deactivated catalysts |
JPS6045550A (ja) * | 1983-08-22 | 1985-03-12 | Nitto Chem Ind Co Ltd | メチルアミン類の製造法 |
DE3577434D1 (en) * | 1984-11-16 | 1990-06-07 | Du Pont | Dimethylaminsynthesekatalysator. |
US4737592A (en) * | 1984-11-16 | 1988-04-12 | E. I. Du Pont De Nemours And Company | Selected chabazite zeolites as catalysts for conversion of methanol and ammonia to diemethylamine |
US4602112A (en) * | 1984-11-16 | 1986-07-22 | E. I. Du Pont De Nemours And Company | Zeolite H-ZK-5 as catalyst for conversion of methanol and ammonia to dimethylamine |
US4806689A (en) * | 1984-11-16 | 1989-02-21 | E. I. Du Pont De Nemours And Company | Zeolite Rho as catalyst for conversion of methanol and ammonia to dimethylamine |
US4683334A (en) * | 1985-04-30 | 1987-07-28 | E. I. Du Pont De Nemours & Company | Modified 8-ring zeolites as catalysts for conversion of methanol and ammonia to dimethylamine |
US4814503A (en) * | 1986-06-27 | 1989-03-21 | E. I. Du Pont De Nemours And Company | Zeolite rho and ZK-5 catalysts for conversion of methanol and ammonia to dimethylamine |
US4918233A (en) * | 1986-07-08 | 1990-04-17 | Air Products And Chemicals, Inc. | Production of ethylenediamine from monoethanolamine and ammonia |
US4874896A (en) * | 1987-12-23 | 1989-10-17 | Uop | Process for the production of alkylamines |
JP2896787B2 (ja) * | 1988-05-20 | 1999-05-31 | 三菱レイヨン株式会社 | ゼオライト触媒の活性維持法 |
US5399769A (en) * | 1993-07-01 | 1995-03-21 | Air Products And Chemicals, Inc. | Preparation of methylamines using shape selective chabazites |
TW360628B (en) * | 1994-05-11 | 1999-06-11 | Mitsui Chemicals Inc | Process for the preparation of methylamines |
TWI234556B (en) * | 1997-07-23 | 2005-06-21 | Mitsubishi Gas Chemical Co | Catalysts for methanol conversion reactions |
JP4221532B2 (ja) * | 1998-06-26 | 2009-02-12 | 三菱瓦斯化学株式会社 | メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法 |
JP4168214B2 (ja) | 1998-10-15 | 2008-10-22 | 三菱瓦斯化学株式会社 | メチルアミン製造触媒及び該触媒の製造方法 |
CN104718025B (zh) | 2012-10-15 | 2017-05-10 | 三菱瓦斯化学株式会社 | 甲胺类制造用催化剂的制造方法和甲胺类的制造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882243A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US2982612A (en) | 1959-01-26 | 1961-05-02 | Union Carbide Corp | Process for producing sodium zeolite a |
US3119658A (en) | 1960-12-28 | 1964-01-28 | Wallace W Schulz | Aluminum cladding dissolution |
US3384667A (en) | 1964-04-28 | 1968-05-21 | Mobil Oil Corp | Production of primary and secondary amines |
US4082805A (en) * | 1974-11-01 | 1978-04-04 | Mobil Oil Corporation | Production of aliphatic amines utilizing a crystalline aluminosilicate catalyst of zsm-5, zsm-11 or zsm-21 |
JPS52124000A (en) | 1976-04-09 | 1977-10-18 | Grace W R & Co | Method of making 4a and 5a aluminosilicate zeolite extrusions |
US4191709A (en) | 1978-02-06 | 1980-03-04 | Imperial Chemical Industries Limited | Manufacture of amines from alcohols with zeolite FU-1 catalysts |
BE875674A (fr) | 1978-04-21 | 1979-10-18 | Ici Ltd | Production d'amines |
GB2019394B (en) * | 1978-04-21 | 1982-09-02 | Ici Ltd | Manufacture of amines |
US4254061A (en) * | 1979-09-11 | 1981-03-03 | E. I. Du Pont De Nemours And Company | Preparation of monomethylamine |
US4374273A (en) | 1981-04-28 | 1983-02-15 | E. I. Du Pont De Nemours And Company | Method for production of methylamines |
-
1982
- 1982-08-25 EP EP82304482A patent/EP0076034B1/en not_active Expired
- 1982-08-25 DE DE8282304482T patent/DE3263547D1/de not_active Expired
- 1982-08-31 US US06/413,443 patent/US4436938A/en not_active Expired - Fee Related
- 1982-09-02 AU AU87957/82A patent/AU562049B2/en not_active Ceased
- 1982-09-03 ZA ZA826475A patent/ZA826475B/xx unknown
- 1982-09-17 ES ES515786A patent/ES8400387A1/es not_active Expired
- 1982-09-17 CA CA000411687A patent/CA1211759A/en not_active Expired
- 1982-09-18 JP JP57163050A patent/JPS5869846A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
CA1211759A (en) | 1986-09-23 |
ZA826475B (en) | 1983-09-28 |
US4436938A (en) | 1984-03-13 |
AU8795782A (en) | 1983-03-24 |
AU562049B2 (en) | 1987-05-28 |
EP0076034B1 (en) | 1985-05-15 |
ES515786A0 (es) | 1983-11-01 |
EP0076034A1 (en) | 1983-04-06 |
JPS5869846A (ja) | 1983-04-26 |
DE3263547D1 (en) | 1985-06-20 |
JPH038331B2 (es) | 1991-02-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19970303 |