ES8207117A1 - Procedimiento para la obtencion de metilformiato - Google Patents
Procedimiento para la obtencion de metilformiatoInfo
- Publication number
- ES8207117A1 ES8207117A1 ES505910A ES505910A ES8207117A1 ES 8207117 A1 ES8207117 A1 ES 8207117A1 ES 505910 A ES505910 A ES 505910A ES 505910 A ES505910 A ES 505910A ES 8207117 A1 ES8207117 A1 ES 8207117A1
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- alkaline earth
- methyl formiate
- alkali metal
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/11—Lithium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE METILFORMIATO. CONSISTE EN HACER REACCIONAR METANOL CON MONOXIDO DE CARBONO EN PESENCIA DE UN ALCOHOLATO ALCALINO O ALCALINO-TERREO A UNA TEMPERATURA DE 30 A 150 GRADOS CENTIGRADOS Y UNA PRESION DE 50 A 300 BAR. LA REACCION TIENE LUGAR EN PRESENCIA DE UNA SUSTANCIA FORMADORA DE COMPLEJO NO IONICO, TAL COMO COMPUESTOS CICLICOS O ACICLICOS DE ESTRUCTURA -(-O-CH2-CH2)N- EN QUE N VALE DE 2 A 12. COMO ALCOHOLATO ALCALINO SE EMPLEA EL METILATO DE SODIO. LA CANTIDAD DE CATALIZADOR OSCILA ENTRE 0,001 Y 0,01 MOL DE ALCOHOLATO POR MOL DE METANOL.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803037089 DE3037089A1 (de) | 1980-10-01 | 1980-10-01 | Verfahren zur herstellung von methylformiat |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8207117A1 true ES8207117A1 (es) | 1982-09-01 |
ES505910A0 ES505910A0 (es) | 1982-09-01 |
Family
ID=6113357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES505910A Granted ES505910A0 (es) | 1980-10-01 | 1981-09-30 | Procedimiento para la obtencion de metilformiato |
Country Status (6)
Country | Link |
---|---|
US (1) | US4994603A (es) |
EP (1) | EP0048891B1 (es) |
JP (1) | JPS5788145A (es) |
CA (1) | CA1157479A (es) |
DE (2) | DE3037089A1 (es) |
ES (1) | ES505910A0 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3221239C3 (de) * | 1982-06-04 | 1990-09-13 | Oleg Alekseevic Tagaev | Verfahren zur herstellung von methylformiat |
FR2528830B1 (fr) * | 1982-06-18 | 1985-07-26 | Tagaev Oleg | Procede d'obtention du formiate de methyle |
DE3621362A1 (de) * | 1986-06-26 | 1988-01-28 | Basf Ag | Verfahren zur herstellung von alkylformiaten |
US4935395A (en) * | 1986-12-19 | 1990-06-19 | Associated Universities, Inc. | Homogeneous catalyst formulations for methanol production |
CN1039711C (zh) * | 1993-04-10 | 1998-09-09 | 中国科学院成都有机化学研究所 | 甲酸甲酯的生产方法及设备 |
DE9307391U1 (de) * | 1993-04-26 | 1993-09-30 | Textilma Ag, Hergiswil | Fachbildevorrichtung für eine Webmaschine |
CN1048656C (zh) * | 1996-03-21 | 2000-01-26 | 厦门大学 | 负载型强碱液膜甲醇羰化制甲酸甲酯催化剂及其制备方法 |
DE19935038A1 (de) | 1999-07-26 | 2001-02-01 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Methylformiat |
US6781014B1 (en) | 1999-11-01 | 2004-08-24 | Acetex (Cyprus) Limited | Methanol plant retrofit for manufacture of acetic acid |
US6274096B1 (en) | 1999-11-01 | 2001-08-14 | Acetex (Cyprus) Limited | Methanol plant retrofit |
EP1180511B1 (en) * | 2000-02-25 | 2009-09-09 | Nippon Steel Corporation | Process for preparation of formate esters or methanol and catalyst therefor |
US6531630B2 (en) | 2000-12-29 | 2003-03-11 | Kenneth Ebenes Vidalin | Bimodal acetic acid manufacture |
US20050027195A1 (en) * | 2003-08-01 | 2005-02-03 | Assaf Govari | Calibration data compression |
US20050059839A1 (en) * | 2003-09-15 | 2005-03-17 | The Regents Of The University Of California | Process and catalysts for the oxidation of methanol and/or ethanol |
US6956134B2 (en) * | 2004-01-08 | 2005-10-18 | The Regents Of The University Of California | Oxidation of methanol and/or dimethyl ether using supported molybdenum-containing heteropolyacid catalysts |
US20180086683A1 (en) * | 2016-09-29 | 2018-03-29 | Richard Sapienza | Small scale production of methoxy compounds |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1147214B (de) * | 1961-03-16 | 1963-04-18 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Ameisensaeuremethylester |
NL6406290A (es) * | 1964-06-04 | 1965-12-06 | ||
GB1511961A (en) * | 1976-03-12 | 1978-05-24 | Ucb Sa | Process for the production of methyl formate |
DD207460A3 (de) * | 1982-04-08 | 1984-02-29 | Oleg A Tagaev | Verfahren fuer die herstellung von methylformiat |
DE3221239C3 (de) * | 1982-06-04 | 1990-09-13 | Oleg Alekseevic Tagaev | Verfahren zur herstellung von methylformiat |
-
1980
- 1980-10-01 DE DE19803037089 patent/DE3037089A1/de not_active Withdrawn
-
1981
- 1981-09-04 US US06/299,544 patent/US4994603A/en not_active Expired - Fee Related
- 1981-09-09 CA CA000385522A patent/CA1157479A/en not_active Expired
- 1981-09-16 DE DE8181107281T patent/DE3161037D1/de not_active Expired
- 1981-09-16 EP EP81107281A patent/EP0048891B1/de not_active Expired
- 1981-09-30 ES ES505910A patent/ES505910A0/es active Granted
- 1981-09-30 JP JP56154051A patent/JPS5788145A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
US4994603A (en) | 1991-02-19 |
DE3037089A1 (de) | 1982-05-06 |
EP0048891B1 (de) | 1983-09-28 |
CA1157479A (en) | 1983-11-22 |
EP0048891A1 (de) | 1982-04-07 |
ES505910A0 (es) | 1982-09-01 |
DE3161037D1 (en) | 1983-11-03 |
JPH0161097B2 (es) | 1989-12-27 |
JPS5788145A (en) | 1982-06-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19990503 |