ES8107145A1 - Procedimiento para la sintesis de derivados de acido ciclo- propancarboxilico opticamente activos - Google Patents

Procedimiento para la sintesis de derivados de acido ciclo- propancarboxilico opticamente activos

Info

Publication number
ES8107145A1
ES8107145A1 ES487505A ES487505A ES8107145A1 ES 8107145 A1 ES8107145 A1 ES 8107145A1 ES 487505 A ES487505 A ES 487505A ES 487505 A ES487505 A ES 487505A ES 8107145 A1 ES8107145 A1 ES 8107145A1
Authority
ES
Spain
Prior art keywords
optically active
acid salts
cyclobutane
preparation
sulfonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES487505A
Other languages
English (en)
Other versions
ES487505A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES8107145A1 publication Critical patent/ES8107145A1/es
Publication of ES487505A0 publication Critical patent/ES487505A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PROCEDIMIENTO DE OBTENCION DE DERIVADOS DEL ACIDO CICLOPROPANCARBOXILICO. CONSISTE EN HACER REACCIONAR UNA CICLOBUTANONA DE FORMULA GENERAL (I) CON UNA SAL DE ACIDO SULFUROSO DE UNA BASE A, OPTICAMENTE ACTIVA, EN UNA MEZCLA DE SALES DE ACIDO SULFONICO DIASTEROMERICAS DE FORMULA (II). LA REACCION TIENE LUGAR A UNA TEMPERATURA COMPRENDIDA ENTRE 0 Y 100GC EN PRESENCIA DE UN DISOLVENTE ORGANICO INERTE Y EN PRESENCIA DE AGUA Y DE ANHIDRIDO SULFUROSO. LA SEPARACION DE LAS SALES DIASTEREOMERICAS SE EFECTUA POR CRISTALIZACION FRACCIONADA EN PRESENCIA DE UN DISOLVENTE ORGANICO INERTE. OBTENCION DE INSECTICIDAS O EMPLEO DIRECTO COMO ANTIPARASITARIOS. *FORMULA*
ES487505A 1978-12-15 1979-12-15 Procedimiento para la sintesis de derivados de acido ciclo- propancarboxilico opticamente activos Granted ES487505A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1278478 1978-12-15

Publications (2)

Publication Number Publication Date
ES8107145A1 true ES8107145A1 (es) 1980-12-16
ES487505A0 ES487505A0 (es) 1980-12-16

Family

ID=4386366

Family Applications (1)

Application Number Title Priority Date Filing Date
ES487505A Granted ES487505A0 (es) 1978-12-15 1979-12-15 Procedimiento para la sintesis de derivados de acido ciclo- propancarboxilico opticamente activos

Country Status (19)

Country Link
US (2) US4299967A (es)
EP (1) EP0012722B1 (es)
JP (1) JPS5932455B2 (es)
AT (1) ATE468T1 (es)
BR (1) BR7908212A (es)
CA (1) CA1136636A (es)
CS (1) CS214680B2 (es)
DD (1) DD151930A5 (es)
DE (1) DE2961566D1 (es)
DK (1) DK160546C (es)
ES (1) ES487505A0 (es)
FI (1) FI793891A (es)
GR (1) GR72730B (es)
HU (1) HU184619B (es)
IL (1) IL58963A (es)
MX (1) MX6292E (es)
NO (2) NO150957C (es)
PL (1) PL220431A2 (es)
ZA (1) ZA796855B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2499071A1 (fr) * 1981-02-05 1982-08-06 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique substitue en 3 par une chaine vinylique, leur procede de preparation et leur application comme agents parfumants
EP0074856A3 (en) * 1981-09-16 1984-02-01 Glaxo Group Limited Resolution of racemic bicycloheptenones
US4845272A (en) * 1987-07-10 1989-07-04 Kuraray Co., Ltd. Process for the optical resolution of (±)-cis or (±)-trans-permethric acid
US5807482A (en) * 1997-10-31 1998-09-15 Uop Llc Chiral stationary phase based on yohimbinic acid
KR19990084855A (ko) * 1998-05-12 1999-12-06 성재갑 시스-퍼메스린산의 광학적 분할방법
DE19960914A1 (de) * 1998-12-28 2000-06-29 Luk Getriebe Systeme Gmbh Umschlingungsmittel
CN101296917A (zh) * 2005-10-24 2008-10-29 霍夫曼-拉罗奇有限公司 由法沃斯基重排制备环状缩酮化酮及该方法在制备葡糖激酶活化剂70中的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1051454A (en) * 1975-05-21 1979-03-27 Marinus J. Van Den Brink Process for the preparation of cyclobutanones
GB1571581A (en) * 1976-01-06 1980-07-16 Shell Int Research Process for the preparation of 2-halocyclobutanones and cyclopropane carbolic acids derived therefrom
DE2654062A1 (de) * 1976-08-26 1978-03-23 Bayer Ag Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeuren
SE441179B (sv) * 1976-09-21 1985-09-16 Roussel Uclaf Nya cyklopropankarboxylsyror med polyhalogenerad substituent, sett for framstellning derav samt anvendning derav i pesticidkompositioner
FI780930A (fi) * 1977-03-31 1978-10-01 Ciba Geigy Ag Foerfarande foer framstaellning av 2-(2'2'2'-trihalogenetyl)-4-halogencyklobutan-1-oner de medelst foerfarandet framstaellda produkterna och deras anvaendning samt de foer deras framstaellning anvaenda mellanprodukterna
EP0002206A1 (de) * 1977-11-24 1979-06-13 Ciba-Geigy Ag Halogenierte Buttersäurechloride, Verfahren zu deren Herstellung und ihre Verwendung als Zwischenprodukte zur Herstellung von Schädlingsbekämpfungsmitteln
US4255351A (en) * 1978-03-14 1981-03-10 Ciba-Geigy Corporation Sulfonic acid esters of 2,2,2-trichloroethylhydroxycyclobutanones

Also Published As

Publication number Publication date
US4299967A (en) 1981-11-10
NO150240C (no) 1984-09-12
NO150240B (no) 1984-06-04
NO150957C (no) 1985-01-16
GR72730B (es) 1983-12-01
HU184619B (en) 1984-09-28
BR7908212A (pt) 1980-08-26
NO802540L (no) 1980-06-17
CS214680B2 (en) 1982-05-28
DK160546B (da) 1991-03-25
DK533579A (da) 1980-06-16
DD151930A5 (de) 1981-11-11
ES487505A0 (es) 1980-12-16
US4335057A (en) 1982-06-15
PL220431A2 (es) 1980-10-06
CA1136636A (en) 1982-11-30
DK160546C (da) 1991-09-30
MX6292E (es) 1985-03-18
NO794102L (no) 1980-06-17
ZA796855B (en) 1980-12-31
FI793891A (fi) 1980-06-16
IL58963A0 (en) 1980-03-31
IL58963A (en) 1983-09-30
NO150957B (no) 1984-10-08
JPS5932455B2 (ja) 1984-08-09
EP0012722A1 (de) 1980-06-25
ATE468T1 (de) 1981-12-15
EP0012722B1 (de) 1981-12-09
DE2961566D1 (en) 1982-02-04
JPS5585541A (en) 1980-06-27

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