ES480880A1 - Un procedimiento de preparacion de tetrazinas sustituidas. - Google Patents

Un procedimiento de preparacion de tetrazinas sustituidas.

Info

Publication number
ES480880A1
ES480880A1 ES480880A ES480880A ES480880A1 ES 480880 A1 ES480880 A1 ES 480880A1 ES 480880 A ES480880 A ES 480880A ES 480880 A ES480880 A ES 480880A ES 480880 A1 ES480880 A1 ES 480880A1
Authority
ES
Spain
Prior art keywords
carbon atoms
groups
substituted
larvicidal
ovicidal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES480880A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fisons Ltd
Original Assignee
Fisons Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fisons Ltd filed Critical Fisons Ltd
Publication of ES480880A1 publication Critical patent/ES480880A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01—Five-membered rings
    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C07D285/12—1,3,4-Thiadiazoles; Hydrogenated 1,3,4-thiadiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D257/08—Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un procedimiento de preparación de tetrazinas sustituidas de la fórmula-01 (I): **(Fórmula-01)** o de la fórmula-02 (II): **(Fórmula-02)** (en donde R1, R2 y R4 que pueden ser iguales o diferentes representan cada uno hidrógeno, fenilo, alcohilo de 1 a 6 átomos de carbono o alquenilo o alquinilo de 3 a 6 átomos de carbono, cada uno de cuyos grupos fenilo, alcohilo, alquenilo o alquinilo puede estar sin sustituir o sustituido por uno o más átomos de halógeno, grupos hidroxi, grupos ciano, grupos carboxi, grupos alcoxicarbonilo de 2 a 5 átomos de carbono o grupos alcoxi de 1 a 4 átomos de carbono; o R1 y R2 conjuntamente representan un enlace sencillo; R3 representa alcohilo de 1 a 6 átomos de carbono, fenilo o fenilalcohilo de 7 a 10 átomos de carbono; cada uno de los cuales puede estar sin sustituir o sustituido por uno o más átomos de carbono, grupos nitro, grupos ciano, grupos mercapto o grupos alcohilmercapto de 1 a 4 átomos de carbono; y R6 representa un grupo fenilo sustituido en al menos la posición 2 por flúor, cloro, bromo o yodo), procedimiento que comprende hacer reaccionar una hidrazina de la fórmula R1NH- NHR2 con una hidrazina sustituida de fórmula-03 (III): **(Fórmula-03)** (en donde cada X representa un grupo eliminable), o con una sal de tiadiazolio de la fórmula- 04 (VI): **(Fórmula-04)** (donde X- representa un anión), para dar un compuesto de fórmula R1NHN=CHR6, que luego se alcohila en presencia de una base de metal alcalino, o para dar un compuesto de fórmula R1NHN=G (Hal), que luego se dimeriza, y opcionalmente oxidar el producto de dihidrotetrazina de fórmula-01 o fórmula-02 para dar un compuesto de fórmula-01 en que R1 y R2 representan conjuntamente un enlace sencillo.
ES480880A 1978-05-25 1979-05-24 Un procedimiento de preparacion de tetrazinas sustituidas. Expired ES480880A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2230678 1978-05-25

Publications (1)

Publication Number Publication Date
ES480880A1 true ES480880A1 (es) 1980-08-16

Family

ID=10177257

Family Applications (1)

Application Number Title Priority Date Filing Date
ES480880A Expired ES480880A1 (es) 1978-05-25 1979-05-24 Un procedimiento de preparacion de tetrazinas sustituidas.

Country Status (13)

Country Link
US (1) US4237127A (es)
EP (1) EP0005912B1 (es)
JP (1) JPS54154770A (es)
AU (1) AU527130B2 (es)
BR (1) BR7903187A (es)
CA (1) CA1102327A (es)
CY (1) CY1243A (es)
DE (1) DE2963331D1 (es)
ES (1) ES480880A1 (es)
IL (1) IL57345A (es)
MY (1) MY8500594A (es)
SG (1) SG23984G (es)
ZA (1) ZA792477B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0029657A3 (en) * 1979-11-16 1981-08-26 Fbc Limited Pesticidal tetrazines, their use and compositions, processes for their preparation and preparation intermediates
ES2018817B3 (es) * 1986-06-05 1991-05-16 Shell Int Research Derivados de tetrazina plaguicidas.
GB8713849D0 (en) * 1987-06-13 1987-07-15 Schering Agrochemicals Ltd Acaricidal formulation
JPH02160705A (ja) * 1988-12-13 1990-06-20 Shionogi & Co Ltd 懸濁流動性殺ダニ剤
HU212613B (en) * 1993-07-21 1996-09-30 Chinoin Gyogyszer Es Vegyeszet Tetrazine-derivatives, process for production of the compounds, acaricidal,larvicidal and ovicidal compositions containing the compounds as active ingredient and process for their production and their use
CO5160333A1 (es) * 1999-06-21 2002-05-30 Novartis Ag Derivados de tetrazina pesticidamente activos y composicion que los contine
DE10013914A1 (de) 2000-03-21 2001-09-27 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10055941A1 (de) 2000-11-10 2002-05-23 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10353281A1 (de) 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
DE102007045922A1 (de) 2007-09-26 2009-04-02 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
EP2127522A1 (de) 2008-05-29 2009-12-02 Bayer CropScience AG Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
EP2382865A1 (de) 2010-04-28 2011-11-02 Bayer CropScience AG Synergistische Wirkstoffkombinationen
IT1402153B1 (it) 2010-10-08 2013-08-28 Uni Degli Studi Camerino Composizione comprendente un larvicida fotoattivabile
JP5718107B2 (ja) * 2011-03-10 2015-05-13 日本曹達株式会社 コナダニ防除剤
CN103012302B (zh) * 2012-12-31 2016-02-10 南通宝叶化工有限公司 一种四螨嗪的生产工艺
CN105130962B (zh) * 2015-09-06 2017-09-26 浙江博仕达作物科技有限公司 一种四嗪吡唑类杀螨剂
CN105061399B (zh) * 2015-09-06 2017-03-22 青岛科技大学 一种含氟四嗪吡啶类化合物及其用途
CN108473447A (zh) * 2015-11-30 2018-08-31 勃艮第大学 制备官能化的1,2,4,5-四嗪化合物的方法
WO2017106427A1 (en) * 2015-12-15 2017-06-22 Joseph Fox Methods for inducing bioorthogonal reactivity
US11485987B2 (en) 2015-12-15 2022-11-01 University Of Delaware Methods for inducing bioorthogonal reactivity
CN108863838A (zh) * 2018-06-09 2018-11-23 石家庄市绿丰化工有限公司 一种合成双(α:2-氯苯亚甲基)肼的方法
CN114163392B (zh) * 2020-09-11 2024-03-12 江苏优嘉植物保护有限公司 一种四螨嗪的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1052877A (es) * 1962-12-03
ZA73911B (en) * 1972-03-15 1973-11-28 Minnesota Mining & Mfg Electrographic development process
US3860588A (en) * 1973-07-23 1975-01-14 Shell Oil Co Dihydrotetrazine herbicides
US3860589A (en) * 1973-07-23 1975-01-14 Shell Oil Co Tetrazine herbicides
US3863010A (en) * 1973-09-28 1975-01-28 American Cyanamid Co Compositions of matter and method of use of phenyl and substituted phenyl tetrazines
SU498300A1 (ru) 1973-11-27 1976-01-05 Институт Органической Химии Ан Украинской Сср Способ получени производных 3,6-диарил-симм-тетразина

Also Published As

Publication number Publication date
ZA792477B (en) 1980-06-25
US4237127A (en) 1980-12-02
CY1243A (en) 1984-06-29
IL57345A (en) 1983-11-30
EP0005912A1 (en) 1979-12-12
DE2963331D1 (en) 1982-09-02
AU4740679A (en) 1979-11-29
SG23984G (en) 1985-01-04
AU527130B2 (en) 1983-02-17
MY8500594A (en) 1985-12-31
EP0005912B1 (en) 1982-07-14
JPH0127068B2 (es) 1989-05-26
JPS54154770A (en) 1979-12-06
CA1102327A (en) 1981-06-02
IL57345A0 (en) 1979-09-30
BR7903187A (pt) 1979-12-11

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