ES477053A2 - Mejoras introducidas en el objeto de la patente principal procedimiento de preparacion de nuevos esteres de acidos ciclopropano-carboxilicos que comprenden un sustituyente po-lihalogenado. - Google Patents
Mejoras introducidas en el objeto de la patente principal procedimiento de preparacion de nuevos esteres de acidos ciclopropano-carboxilicos que comprenden un sustituyente po-lihalogenado.Info
- Publication number
- ES477053A2 ES477053A2 ES477053A ES477053A ES477053A2 ES 477053 A2 ES477053 A2 ES 477053A2 ES 477053 A ES477053 A ES 477053A ES 477053 A ES477053 A ES 477053A ES 477053 A2 ES477053 A2 ES 477053A2
- Authority
- ES
- Spain
- Prior art keywords
- carboxylate
- dimethyl
- cyclopropane
- polyhalogenated
- substituent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical class OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 title 1
- 125000001424 substituent group Polymers 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 2
- ICONUAUUNBOTBQ-UBNQGINQSA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1R,3S)-2,2-dimethyl-3-(1,2,2,2-tetrabromoethyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O ICONUAUUNBOTBQ-UBNQGINQSA-N 0.000 abstract 1
- ICONUAUUNBOTBQ-NDQFZYFBSA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(1,2,2,2-tetrabromoethyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O ICONUAUUNBOTBQ-NDQFZYFBSA-N 0.000 abstract 1
- VQHJWDTTWVEXFE-CMIFXSJHSA-N [(R)-cyano-(3-phenoxyphenyl)methyl] (1R,3R)-3-(1,2-dibromo-2,2-dichloroethyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1([C@@H]([C@H]1C(C(Br)(Cl)Cl)Br)C(=O)O[C@H](C1=CC(=CC=C1)OC1=CC=CC=C1)C#N)C VQHJWDTTWVEXFE-CMIFXSJHSA-N 0.000 abstract 1
- VQHJWDTTWVEXFE-CJPNDHRQSA-N [(S)-cyano-(3-phenoxyphenyl)methyl] (1R,3R)-3-(1,2-dibromo-2,2-dichloroethyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C(Br)C(Cl)(Cl)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 VQHJWDTTWVEXFE-CJPNDHRQSA-N 0.000 abstract 1
- IBMSWRXODJRVOH-KAKFPZCNSA-N [(S)-cyano-(3-phenoxyphenyl)methyl] (1R,3S)-2,2-dimethyl-3-(1,2,2,2-tetrachloroethyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C(Cl)C(Cl)(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 IBMSWRXODJRVOH-KAKFPZCNSA-N 0.000 abstract 1
- HCYYREFJDAPNRT-KAKFPZCNSA-N [(S)-cyano-(3-phenoxyphenyl)methyl] (1R,3S)-3-(2,2-dibromo-1,2-dichloroethyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1([C@@H]([C@@H]1C(C(Cl)(Br)Br)Cl)C(=O)O[C@@H](C1=CC(=CC=C1)OC1=CC=CC=C1)C#N)C HCYYREFJDAPNRT-KAKFPZCNSA-N 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
- C07D209/49—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/10—Organic substances
- A23K20/105—Aliphatic or alicyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/275—Nitriles; Isonitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/60—Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/04—Saturated compounds having a carboxyl group bound to a three or four-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/93—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems condensed with a ring other than six-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Polymers & Plastics (AREA)
- Animal Behavior & Ethology (AREA)
- Pest Control & Pesticides (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Food Science & Technology (AREA)
- Animal Husbandry (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Agronomy & Crop Science (AREA)
- Medicinal Chemistry (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Indole Compounds (AREA)
Abstract
Procedimiento de preparación de nuevos ésteres de ácidos ciclopropanocarboxílicos que comprenden un sustituyente polihalogenado, en forma de isómero A, del isómero B, o en forma de mezcla de estos isómeros. Se ha indicado en la patente principal que los ésteres pueden existir en numerosas formas isómeras. En efecto, los ácidos ciclopropano-carboxílicos que forman la parte ácida de los ésteres de fórmula I poseen, en general, tres carbonos asimétricos, a saber, los carbonos asimétricos en las posiciones 1 y 3 del ciclo ciclopropánico y el carbono asimétrico en la posición 1'' de la cadena lateral etílica polihalogenada fijada en la posición 3. Se ha indicado igualmente en la patente principal que el alcohol ROH que constituye la parte alcohólica de los ésteres puede contener uno o varios carbonos asimétricos y/o uno o varios enlaces dobles dando lugar a una isomería E/Z.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7807780A FR2419932A2 (fr) | 1978-03-17 | 1978-03-17 | Nouveaux esters d'acides cyclopropane carboxyliques comportant un substituant polyhalogene, procede de preparation et compositions insecticides les renfermant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES477053A2 true ES477053A2 (es) | 1979-07-01 |
Family
ID=9205947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES477053A Expired ES477053A2 (es) | 1978-03-17 | 1979-01-22 | Mejoras introducidas en el objeto de la patente principal procedimiento de preparacion de nuevos esteres de acidos ciclopropano-carboxilicos que comprenden un sustituyente po-lihalogenado. |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS54128549A (es) |
| AT (1) | AT364676B (es) |
| BE (1) | BE873201R (es) |
| CH (1) | CH638179A5 (es) |
| DD (1) | DD143849A6 (es) |
| DE (1) | DE2903268A1 (es) |
| ES (1) | ES477053A2 (es) |
| FR (1) | FR2419932A2 (es) |
| GB (1) | GB2016447B (es) |
| GR (1) | GR72819B (es) |
| IE (1) | IE47990B1 (es) |
| IT (1) | IT1188819B (es) |
| LU (1) | LU80798A1 (es) |
| NL (1) | NL7901518A (es) |
| PH (1) | PH15709A (es) |
| PL (1) | PL222529A1 (es) |
| YU (1) | YU6879A (es) |
| ZA (1) | ZA79786B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2471187A1 (fr) * | 1979-12-10 | 1981-06-19 | Roussel Uclaf | Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud |
| FR2484256B1 (fr) * | 1979-06-29 | 1986-10-24 | Roussel Uclaf | Procede de lutte contre les parasites des animaux a sang chaud |
| FR2472570A1 (fr) * | 1979-07-31 | 1981-07-03 | Roussel Uclaf | Procede de preparation du (1,5) 6,6-dimethyl 4-hydroxy 3-oxa bicylo(3.1.0.)hexan-2-one et de ses ethers en position 4, sous toutes leurs formes stereoisomeres |
| FR2470602A1 (fr) * | 1979-12-04 | 1981-06-12 | Roussel Uclaf | A titre de produit destine a la lutte contre les acariens parasites des animaux, le 1r, cis 2,2-dimethyl 3-(2,2-dichlorovinyl) cyclopropane-1-carboxylate de (s) a-cyano 3-phenoxy benzyle |
| DE3004092A1 (de) * | 1980-02-05 | 1981-08-13 | Bayer Ag, 5090 Leverkusen | Substituierte 3-(1,2-dibrom-alkyl)- 2,2-dimethyl-cyclopropan-1-carbonsaeureester, verfahren sowie zwischenprodukte zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln |
| WO1981002892A1 (en) * | 1980-04-10 | 1981-10-15 | Dainippon Jochugiku Kk | Cyclopropanecarboxylic acid ester derivatives,process for their preparation,and insecticidal and acaricidal composition containing such as effective ingredients |
| CA1159150A (en) * | 1980-10-20 | 1983-12-20 | Richard L. Wilkinson | Video recorder-playback machine |
| EP0312124A3 (en) * | 1982-11-22 | 1989-09-13 | E.I. Du Pont De Nemours And Company | Process for the preparation of optically-active cyanomethyl esters |
| GB9105694D0 (en) * | 1991-03-18 | 1991-05-01 | Hand Peter Animal Health | Control of sea lice in salmon |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE446527B (sv) * | 1976-09-21 | 1986-09-22 | Roussel Uclaf | Nya cyklopropankarboxylsyraestrar med en polyhalogenerad substituent, sett for framstellning derav samt anvendning derav i pesticidkompositioner |
| TR20113A (tr) * | 1977-02-11 | 1980-08-07 | Ciba Geigy Ag | Yeni esterler |
| US4498846A (en) * | 1983-06-20 | 1985-02-12 | Deere & Company | Stroke control valve |
-
1978
- 1978-03-17 FR FR7807780A patent/FR2419932A2/fr active Granted
- 1978-12-29 BE BE192666A patent/BE873201R/xx not_active IP Right Cessation
-
1979
- 1979-01-15 YU YU00068/79A patent/YU6879A/xx unknown
- 1979-01-16 LU LU80798A patent/LU80798A1/xx unknown
- 1979-01-22 ES ES477053A patent/ES477053A2/es not_active Expired
- 1979-01-29 DE DE19792903268 patent/DE2903268A1/de not_active Ceased
- 1979-01-31 GB GB7903310A patent/GB2016447B/en not_active Expired
- 1979-02-06 JP JP1192379A patent/JPS54128549A/ja active Pending
- 1979-02-08 IE IE240/79A patent/IE47990B1/en not_active IP Right Cessation
- 1979-02-10 PL PL22252979A patent/PL222529A1/xx unknown
- 1979-02-20 DD DD79211129A patent/DD143849A6/de not_active IP Right Cessation
- 1979-02-20 ZA ZA79786A patent/ZA79786B/xx unknown
- 1979-02-26 NL NL7901518A patent/NL7901518A/xx not_active Application Discontinuation
- 1979-03-06 AT AT0169679A patent/AT364676B/de not_active IP Right Cessation
- 1979-03-14 IT IT48345/79A patent/IT1188819B/it active
- 1979-03-14 GR GR58597A patent/GR72819B/el unknown
- 1979-03-16 CH CH253079A patent/CH638179A5/fr not_active IP Right Cessation
- 1979-05-22 PH PH22535A patent/PH15709A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54128549A (en) | 1979-10-05 |
| FR2419932A2 (fr) | 1979-10-12 |
| IT1188819B (it) | 1988-01-28 |
| DE2903268A1 (de) | 1979-09-27 |
| IE47990B1 (en) | 1984-08-22 |
| PH15709A (en) | 1983-03-14 |
| CH638179A5 (fr) | 1983-09-15 |
| AT364676B (de) | 1981-11-10 |
| LU80798A1 (fr) | 1979-09-07 |
| ZA79786B (en) | 1980-02-27 |
| PL222529A1 (es) | 1980-09-08 |
| BE873201R (fr) | 1979-06-29 |
| GB2016447B (en) | 1982-08-04 |
| DD143849A6 (de) | 1980-09-17 |
| ATA169679A (de) | 1981-04-15 |
| IE790240L (en) | 1979-09-17 |
| YU6879A (en) | 1983-10-31 |
| FR2419932B2 (es) | 1981-05-22 |
| GR72819B (es) | 1983-12-06 |
| GB2016447A (en) | 1979-09-26 |
| NL7901518A (nl) | 1979-09-19 |
| IT7948345A0 (it) | 1979-03-14 |
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