ES468499A1 - Un procedimiento para la recuperacion de catalizadores y di-solventes en un metodo para la obtencion de acido tereftali-co - Google Patents
Un procedimiento para la recuperacion de catalizadores y di-solventes en un metodo para la obtencion de acido tereftali-coInfo
- Publication number
- ES468499A1 ES468499A1 ES468499A ES468499A ES468499A1 ES 468499 A1 ES468499 A1 ES 468499A1 ES 468499 A ES468499 A ES 468499A ES 468499 A ES468499 A ES 468499A ES 468499 A1 ES468499 A1 ES 468499A1
- Authority
- ES
- Spain
- Prior art keywords
- oxidation
- acetic acid
- mother
- water
- partially
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para la recuperación de catalizadores y disolventes en un método para la obtención de ácido tereftálico, esencialmente del tipo que comprende la oxidación de para-xileno en solución de ácido acético y en presencia de un sistema catalítico a base de manganeso, cobalto y bromo, con lo que se forma agua durante la oxidación, siendo la cantidad de agua en la mezcla de oxidación líquida inferior al 10% en peso con respecto al ácido acético, con lo que se separa ácido tereftálico sólido de las aguas madres y con lo que se extrae de la zona de oxidación un líquido que se obtiene condensando los vapores liberados durante la oxidación y que está constituido, fundamentalmente, por ácido acético y agua; caracterizado porque comprende reducir la cantidad de sólidos suspendidos en las aguas madres a menos del 0,30% y de preferencia a menos del 0,05% en peso, con respecto a las aguas madres, y porque sucesivamente dichas aguas madres se anhidrifican parcialmente, por medio de una destilación para reducir la cantidad de agua en las aguas madres parcialmente anhidrificadas por debajo de, por lo menos, el 5% en peso, con respecto al ácido acético, con lo que una porción del licor parcialmente anhidrificado, conteniendo por lo menos el 50% del sistema catalítico, presente en las aguas madres originales, se recicla a la zona de oxidación, alimentándose la porción restante del licor parcialmente anhidrificado como una purga a los tratamientos usuales para la separación y la regeneración del catalizador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2205877A IT1075688B (it) | 1977-04-04 | 1977-04-04 | Metodo per il recupero del catalizzatore e del solvente dal liquido madre di un processo per la sintesi dell'acido tereftalico |
IT22408/77A IT1075317B (it) | 1977-04-13 | 1977-04-13 | Metodo per l'anidrificazione del solvente e per il ricupero del sottoprodotto acetato di metile in un processo di sintesi dell'acido tereftalico |
Publications (1)
Publication Number | Publication Date |
---|---|
ES468499A1 true ES468499A1 (es) | 1979-01-01 |
Family
ID=26328080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES468499A Expired ES468499A1 (es) | 1977-04-04 | 1978-04-03 | Un procedimiento para la recuperacion de catalizadores y di-solventes en un metodo para la obtencion de acido tereftali-co |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS53127430A (es) |
BR (1) | BR7802069A (es) |
DE (1) | DE2814448A1 (es) |
ES (1) | ES468499A1 (es) |
FR (1) | FR2386511A1 (es) |
GB (1) | GB1593117A (es) |
IN (1) | IN148106B (es) |
MX (1) | MX148713A (es) |
NL (1) | NL188282C (es) |
SU (1) | SU1217250A3 (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1129759B (it) * | 1980-01-23 | 1986-06-11 | Montedison Spa | Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico |
US4334086A (en) * | 1981-03-16 | 1982-06-08 | Labofina S.A. | Production of terephthalic acid |
MX9701355A (es) * | 1994-08-23 | 1997-05-31 | Ici Plc | Deshidratacion de acido acetico mediante destilacion azeotropica en la produccion de un acido aromatico. |
US6150553A (en) * | 1998-08-11 | 2000-11-21 | E. I. Du Pont De Nemours And Company | Method for recovering methyl acetate and residual acetic acid in the production acid of pure terephthalic acid |
CN1236835C (zh) * | 2001-02-27 | 2006-01-18 | 三菱化学株式会社 | 共沸蒸馏方法 |
US7361784B2 (en) * | 2004-09-02 | 2008-04-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7504535B2 (en) | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7572936B2 (en) | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7683210B2 (en) | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7582793B2 (en) | 2004-09-02 | 2009-09-01 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7381836B2 (en) | 2004-09-02 | 2008-06-03 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7741515B2 (en) | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7910769B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7507857B2 (en) | 2004-09-02 | 2009-03-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7568361B2 (en) | 2004-09-02 | 2009-08-04 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7589231B2 (en) | 2004-09-02 | 2009-09-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7884232B2 (en) | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA793870A (en) * | 1964-12-14 | 1968-09-03 | Berthoux Jean | Procede d'oxydation d'hydrocarbures aromatiques |
US3557173A (en) * | 1968-05-09 | 1971-01-19 | Sinclair Research Inc | Process for recovering cobalt acetate |
DE2104909A1 (en) * | 1971-02-03 | 1972-09-07 | Chemische Fabrik Kalk GmbH, 5000 Köln | Terephthalic acid prodn - by para-xylene oxidn with oxygen using cobalt and bromine compound catalysts |
US3761474A (en) * | 1971-03-22 | 1973-09-25 | Fmc Corp | Purification of crude cyanuric acid |
JPS5328420B2 (es) * | 1973-04-05 | 1978-08-15 | ||
JPS5328421B2 (es) * | 1973-05-15 | 1978-08-15 | ||
JPS5328901B2 (es) * | 1973-07-28 | 1978-08-17 | ||
FR2304255A7 (fr) * | 1975-03-13 | 1976-10-08 | Inst Francais Du Petrole | Procede de fabrication d'acide terephtalique par oxydation du paraxylene |
-
1978
- 1978-03-30 NL NLAANVRAGE7803368,A patent/NL188282C/xx not_active IP Right Cessation
- 1978-03-31 FR FR7809488A patent/FR2386511A1/fr active Granted
- 1978-04-03 ES ES468499A patent/ES468499A1/es not_active Expired
- 1978-04-03 MX MX172975A patent/MX148713A/es unknown
- 1978-04-03 SU SU782600750A patent/SU1217250A3/ru active
- 1978-04-03 BR BR7802069A patent/BR7802069A/pt unknown
- 1978-04-03 GB GB12977/78A patent/GB1593117A/en not_active Expired
- 1978-04-03 IN IN356/CAL/78A patent/IN148106B/en unknown
- 1978-04-03 JP JP3817578A patent/JPS53127430A/ja active Granted
- 1978-04-04 DE DE19782814448 patent/DE2814448A1/de active Granted
Also Published As
Publication number | Publication date |
---|---|
DE2814448A1 (de) | 1978-10-12 |
FR2386511A1 (fr) | 1978-11-03 |
FR2386511B1 (es) | 1980-07-25 |
DE2814448C2 (es) | 1991-05-23 |
GB1593117A (en) | 1981-07-15 |
NL188282C (nl) | 1992-05-18 |
MX148713A (es) | 1983-06-06 |
SU1217250A3 (ru) | 1986-03-07 |
JPS53127430A (en) | 1978-11-07 |
IN148106B (es) | 1980-10-18 |
NL188282B (nl) | 1991-12-16 |
NL7803368A (nl) | 1978-10-06 |
JPS6241219B2 (es) | 1987-09-02 |
BR7802069A (pt) | 1979-01-23 |
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