ES465826A1 - Procedimiento para efectuar la etilacion de benceno. - Google Patents
Procedimiento para efectuar la etilacion de benceno.Info
- Publication number
- ES465826A1 ES465826A1 ES465826A ES465826A ES465826A1 ES 465826 A1 ES465826 A1 ES 465826A1 ES 465826 A ES465826 A ES 465826A ES 465826 A ES465826 A ES 465826A ES 465826 A1 ES465826 A1 ES 465826A1
- Authority
- ES
- Spain
- Prior art keywords
- manufacture
- ethyl benzene
- benzene
- diluent
- reacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 title 2
- 238000004519 manufacturing process Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/909—Heat considerations
- Y10S585/911—Heat considerations introducing, maintaining, or removing heat by atypical procedure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/949—Miscellaneous considerations
- Y10S585/95—Prevention or removal of corrosion or solid deposits
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para efectuar la etilación de bencenoque comprende poner en contacto bencenobajo condiciones de conversióncon un etileno mezclado con una cantidad al menos equimolar de un hidrocarburo diluyente inerteen presencia de un catalizador que comprende una zeolita de aluminosilicato cristalinola cual zeolita está caracterizada por una relación entre sílice y alúmina de al menos aproximadamente 12y un índice de restricción dentro del intervalo aproximado de 1 a 12para producir etilbenceno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/767,855 US4107224A (en) | 1977-02-11 | 1977-02-11 | Manufacture of ethyl benzene |
Publications (1)
Publication Number | Publication Date |
---|---|
ES465826A1 true ES465826A1 (es) | 1978-09-16 |
Family
ID=25080790
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES465826A Expired ES465826A1 (es) | 1977-02-11 | 1978-01-07 | Procedimiento para efectuar la etilacion de benceno. |
Country Status (12)
Country | Link |
---|---|
US (1) | US4107224A (es) |
JP (1) | JPS53101314A (es) |
AU (1) | AU518433B2 (es) |
BE (1) | BE863221A (es) |
BR (1) | BR7800792A (es) |
CA (1) | CA1088105A (es) |
DE (1) | DE2756221A1 (es) |
ES (1) | ES465826A1 (es) |
GB (1) | GB1586631A (es) |
IT (1) | IT1093704B (es) |
MX (1) | MX147446A (es) |
NL (1) | NL187477C (es) |
Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
YU34122B (en) * | 1965-03-30 | 1978-12-31 | Ciba Geigy Ag | Process for preparing phenylthiourea compounds |
US4117024A (en) * | 1977-07-29 | 1978-09-26 | Mobil Oil Corporation | Ethylation of aromatic compounds |
DE3066664D1 (en) * | 1979-02-21 | 1984-03-29 | Mobil Oil Corp | Crystalline zeolitic material, synthesis and use thereof |
US4520220A (en) * | 1982-02-22 | 1985-05-28 | Cosden Technology, Inc. | Alkylation of aromatics employing silicalite catalysts |
US4447664A (en) * | 1982-09-23 | 1984-05-08 | The Dow Chemical Company | Integrated Fischer-Tropsch and aromatic alkylation process |
US5233112A (en) * | 1987-08-31 | 1993-08-03 | Mobil Oil Corp | Catalytic conversion over specially synthesized crystalline porous chalcogenides |
US5147838A (en) * | 1987-08-31 | 1992-09-15 | Mobil Oil Corporation | Temperature programmed synthesis or crystalline porous chalcogenides |
WO1989007586A1 (en) * | 1988-02-19 | 1989-08-24 | Mobil Oil Corporation | Process for the production of gasoline from fuel gas and catalytic reformate |
US4950827A (en) * | 1988-03-28 | 1990-08-21 | Institute Of Gas Technology | Oxidative coupling of aliphatic and alicyclic hydrocarbons with aliphatic and alicyclic substituted aromatic hydrocarbons |
US5003119A (en) * | 1988-05-09 | 1991-03-26 | Lummus Crest, Inc. | Manufacture of alkylbenzenes |
US4992607A (en) * | 1989-03-20 | 1991-02-12 | Mobil Oil Corporation | Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate |
US5262576A (en) * | 1989-03-23 | 1993-11-16 | Chemical Research & Licensing Company | Method for the alkylation of organic aromatic compounds |
US4922053A (en) * | 1989-05-24 | 1990-05-01 | Fina Technology, Inc. | Process for ethylbenzene production |
US5073653A (en) * | 1989-06-23 | 1991-12-17 | Fina Technology, Inc. | Aromatic alkylation processes |
US5030786A (en) * | 1989-06-23 | 1991-07-09 | Fina Technology, Inc. | Liquid phase aromatic conversion process |
US5196623A (en) * | 1989-06-23 | 1993-03-23 | Fina Technology, Inc. | Aromatic alkylation process employing zeolite omega catalyst |
FR2662438B1 (fr) * | 1990-05-22 | 1993-10-29 | Institut Francais Petrole | Procede de production d'alkylbenzenes utilisant des catalyseurs a base de zeolithe y desaluminee. |
US5120890A (en) * | 1990-12-31 | 1992-06-09 | Uop | Process for reducing benzene content in gasoline |
US5476823A (en) * | 1993-05-28 | 1995-12-19 | Mobil Oil Corp. | Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof |
FR2706888A1 (en) * | 1993-06-25 | 1994-12-30 | Inst Francais Du Petrole | Process for the alkylation of aromatic compounds |
US5430211A (en) * | 1993-10-29 | 1995-07-04 | The Dow Chemical Company | Process of preparing ethylbenzene or substituted derivatives thereof |
CN1043421C (zh) * | 1993-12-12 | 1999-05-19 | 抚顺石油化工公司石油二厂 | 稀乙烯与甲苯反应制取对甲基乙苯工艺方法 |
CN1041399C (zh) * | 1994-12-30 | 1998-12-30 | 中国石油化工总公司 | 一种含稀土的结晶硅酸铝沸石 |
US5744686A (en) * | 1995-09-20 | 1998-04-28 | Uop | Process for the removal of nitrogen compounds from an aromatic hydrocarbon stream |
US5942650A (en) * | 1995-09-20 | 1999-08-24 | Uop Llc | Process for the removal of nitrogen compounds from an aromatic stream |
US5856607A (en) * | 1996-05-03 | 1999-01-05 | Amoco Corporation | Process for production of ethylbenzene frome dilute ethylene streams |
CN1048655C (zh) * | 1996-06-24 | 2000-01-26 | 中国石油化工总公司 | 一种烷基化催化剂及其应用 |
US5900518A (en) * | 1996-10-30 | 1999-05-04 | Fina Technology, Inc. | Heat integration in alkylation/transalkylation process |
US5955642A (en) * | 1996-10-30 | 1999-09-21 | Fina Technology, Inc. | Gas phase alkylation-liquid transalkylation process |
US5847255A (en) * | 1997-05-21 | 1998-12-08 | Fina Technology, Inc. | Gas phase alkylation-liquid phase transalkylation process |
US6043402A (en) * | 1997-06-16 | 2000-03-28 | Uop Llc | Method for minimizing diarylalkane formation in alkylation-transalkylation process using zeolite beta |
US5877370A (en) * | 1997-06-16 | 1999-03-02 | Uop Llc | Method for minimizing diarylalkane formation in alkylation of aromatics by olefins by zeolite beta |
US6479721B1 (en) | 1997-06-16 | 2002-11-12 | Uop Llc | Alkylation process operating at low olefin ratios |
US5880320A (en) * | 1997-08-05 | 1999-03-09 | Netzer; David | Combination process for manufacturing ethylene ethylbenzene and styrene |
US5907073A (en) * | 1998-02-24 | 1999-05-25 | Fina Technology, Inc. | Aromatic alkylation process |
US6057485A (en) * | 1998-11-17 | 2000-05-02 | Fina Technology, Inc. | Gas phase alkylation with split load of catalyst |
US6090991A (en) * | 1999-02-27 | 2000-07-18 | Fina Technology, Inc. | Gas phase alkylation method and catalyst |
US6268542B1 (en) | 1999-08-23 | 2001-07-31 | Fina Technology, Inc. | Multi-phase alkylation-transalkylation process |
FR2808523B1 (fr) * | 2000-05-02 | 2002-08-16 | Inst Francais Du Petrole | Procede de production conjointe ou non de monoakylaromatiques, dialkyl aromatiques et trialkyl aromatiques |
US7371911B2 (en) * | 2005-02-25 | 2008-05-13 | Fina Technology, Inc. | Critical phase alkylation and transalkylation process in the presence of a beta zeolite |
US6486371B1 (en) * | 2000-11-28 | 2002-11-26 | Fina Technology, Inc. | Multistage reaction system with interstage sparger systems |
US6376729B1 (en) | 2000-12-04 | 2002-04-23 | Fina Technology, Inc. | Multi-phase alkylation process |
GB0106269D0 (en) * | 2001-03-14 | 2001-05-02 | Auntiegravity Ltd | Improvements in noise cancellation |
US6783659B2 (en) | 2001-11-16 | 2004-08-31 | Chevron Phillips Chemical Company, L.P. | Process to produce a dilute ethylene stream and a dilute propylene stream |
US6995295B2 (en) * | 2002-09-23 | 2006-02-07 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
US7238843B2 (en) * | 2003-02-28 | 2007-07-03 | Abb Lummus Global, Inc. | Process for the production of alkylaromatics |
FR2854628B1 (fr) * | 2003-05-07 | 2005-06-24 | Inst Francais Du Petrole | Procede de production de phenylalcanes en presence d'un catalyseur solide acide dont la desactivation est retardee |
US7141710B2 (en) * | 2003-11-25 | 2006-11-28 | Exxonmobil Chemical Patents Inc. | Aromatics alkylation process |
US6894201B1 (en) | 2003-12-19 | 2005-05-17 | Uop Llc | Process and apparatus for the removal of nitrogen compounds from a fluid stream |
US7205448B2 (en) * | 2003-12-19 | 2007-04-17 | Uop Llc | Process for the removal of nitrogen compounds from a fluid stream |
CN100348562C (zh) * | 2004-09-06 | 2007-11-14 | 中国科学院大连化学物理研究所 | 一种自热式低浓度乙烯与苯烃化生产乙基苯的方法 |
CN1315761C (zh) * | 2004-12-23 | 2007-05-16 | 中国科学院大连化学物理研究所 | 一种催化干气中乙烯与苯分离制备乙基苯的方法 |
CN1319915C (zh) * | 2005-10-19 | 2007-06-06 | 大连理工大学 | 一种苯与干气烃化制乙苯节能方法 |
US7501547B2 (en) * | 2006-05-10 | 2009-03-10 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
US7737314B2 (en) * | 2007-02-12 | 2010-06-15 | Exxonmobil Chemical Patents Inc. | Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein |
EP2105429A1 (en) * | 2008-03-20 | 2009-09-30 | Uop Llc | Process and apparatus for alkylation or aromatic with olefin using impure aromatic recycle |
CN101768043B (zh) * | 2008-12-31 | 2013-09-25 | 中国科学院大连化学物理研究所 | 一种稀乙烯与苯反应制乙苯的方法 |
US8889937B2 (en) | 2011-06-09 | 2014-11-18 | Uop Llc | Process for producing one or more alkylated aromatics |
NL2007874C2 (en) | 2011-11-25 | 2013-05-28 | Progression Industry B V | The application of chemical compounds presents a styrene production process in a fuel. |
AU2013207783B2 (en) | 2012-01-13 | 2017-07-13 | Lummus Technology Llc | Process for providing C2 hydrocarbons via oxidative coupling of methane and for separating hydrocarbon compounds |
EP2855005A2 (en) | 2012-05-24 | 2015-04-08 | Siluria Technologies, Inc. | Oxidative coupling of methane systems and methods |
US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
WO2014089479A1 (en) | 2012-12-07 | 2014-06-12 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
EP3074119B1 (en) | 2013-11-27 | 2019-01-09 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
CN110655437B (zh) | 2014-01-08 | 2022-09-09 | 鲁玛斯技术有限责任公司 | 乙烯成液体的系统和方法 |
US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
CN105728017B (zh) * | 2014-12-08 | 2018-07-10 | 中国科学院大连化学物理研究所 | 一种无粘结剂zsm11分子筛催化剂的制备和应用 |
CN105983434B (zh) * | 2015-02-11 | 2019-07-05 | 中国科学院大连化学物理研究所 | 一种无粘结剂的zsm-11分子筛催化剂的制备方法和应用 |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
WO2016205411A2 (en) | 2015-06-16 | 2016-12-22 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
EP3362425B1 (en) | 2015-10-16 | 2020-10-28 | Lummus Technology LLC | Separation methods and systems for oxidative coupling of methane |
EP3442934A4 (en) | 2016-04-13 | 2019-12-11 | Siluria Technologies, Inc. | OXIDIZING COUPLING OF METHANE FOR THE PRODUCTION OF OLEFINS |
WO2018118105A1 (en) | 2016-12-19 | 2018-06-28 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
JP2020521811A (ja) | 2017-05-23 | 2020-07-27 | ラマス テクノロジー リミテッド ライアビリティ カンパニー | メタン酸化カップリングプロセスの統合 |
AU2018298234B2 (en) | 2017-07-07 | 2022-11-17 | Lummus Technology Llc | Systems and methods for the oxidative coupling of methane |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3436432A (en) * | 1968-03-29 | 1969-04-01 | Universal Oil Prod Co | Process for alkylation of aromatics using a halogen-containing aluminosilicate-alumina catalyst |
US3542892A (en) * | 1969-03-24 | 1970-11-24 | Universal Oil Prod Co | Separation process for olefinic oligomerization and aromatic alkylation |
GB1403329A (en) * | 1972-04-28 | 1975-08-28 | Mobil Oil Corp | Vapour-phase alkylation in presence of crystalline alumino silicate catalyst |
US3751506A (en) * | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst |
US3751504A (en) * | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation |
US3962364A (en) * | 1975-03-28 | 1976-06-08 | Mobil Oil Corporation | Alkylation in presence of phosphorus-modified crystalline luminosilicate catalyst |
US4016218A (en) * | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
-
1977
- 1977-02-11 US US05/767,855 patent/US4107224A/en not_active Expired - Lifetime
- 1977-11-22 CA CA291,517A patent/CA1088105A/en not_active Expired
- 1977-12-13 AU AU31509/77A patent/AU518433B2/en not_active Expired
- 1977-12-16 DE DE19772756221 patent/DE2756221A1/de active Granted
-
1978
- 1978-01-03 GB GB46/78A patent/GB1586631A/en not_active Expired
- 1978-01-07 ES ES465826A patent/ES465826A1/es not_active Expired
- 1978-01-23 BE BE184561A patent/BE863221A/xx not_active IP Right Cessation
- 1978-02-09 NL NLAANVRAGE7801494,A patent/NL187477C/xx not_active IP Right Cessation
- 1978-02-10 IT IT20169/78A patent/IT1093704B/it active
- 1978-02-10 MX MX172392A patent/MX147446A/es unknown
- 1978-02-10 BR BR7800792A patent/BR7800792A/pt unknown
- 1978-02-10 JP JP1365678A patent/JPS53101314A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
AU518433B2 (en) | 1981-10-01 |
GB1586631A (en) | 1981-03-25 |
NL187477C (nl) | 1991-10-16 |
US4107224A (en) | 1978-08-15 |
IT1093704B (it) | 1985-07-26 |
DE2756221C2 (es) | 1989-06-22 |
MX147446A (es) | 1982-12-03 |
AU3150977A (en) | 1979-06-21 |
NL7801494A (nl) | 1978-08-15 |
JPS53101314A (en) | 1978-09-04 |
DE2756221A1 (de) | 1978-08-17 |
IT7820169A0 (it) | 1978-02-10 |
BR7800792A (pt) | 1979-01-02 |
JPH0551571B2 (es) | 1993-08-03 |
BE863221A (fr) | 1978-07-24 |
CA1088105A (en) | 1980-10-21 |
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