ES462351A1 - Procedimiento para la produccion de e-caprolactama - Google Patents
Procedimiento para la produccion de e-caprolactamaInfo
- Publication number
- ES462351A1 ES462351A1 ES462351A ES462351A ES462351A1 ES 462351 A1 ES462351 A1 ES 462351A1 ES 462351 A ES462351 A ES 462351A ES 462351 A ES462351 A ES 462351A ES 462351 A1 ES462351 A1 ES 462351A1
- Authority
- ES
- Spain
- Prior art keywords
- cyclohexanone oxime
- distillation
- caprolactam
- producing
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedimiento para la producción de epsilon-caprolactama, caracterizado porque comprende transponer ciclohexanonoximas en fase gaseosa, en presencia de un catalizador conteniendo boro, en lecho fluidificado, a una temperatura de 250 a 400ºC, bajo introducción, en forma líquida, de residuos de la destilación de ciclohexanonoxima en una cantidad de 5 hasta 500 veces la cantidad de ciclohexanonoxima en forma vaporizada y, como mínimo, 50 veces la cantidad de gas inerte, tal como nitrógeno.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762641381 DE2641381A1 (de) | 1976-09-15 | 1976-09-15 | Verwendung von rueckstaenden der cyclohexanonoximdestillation zur herstellung von epsilon-caprolactam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES462351A1 true ES462351A1 (es) | 1979-01-01 |
Family
ID=5987895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES462351A Expired ES462351A1 (es) | 1976-09-15 | 1977-09-14 | Procedimiento para la produccion de e-caprolactama |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4141896A (es) |
| JP (1) | JPS5337686A (es) |
| BE (1) | BE858715A (es) |
| BR (1) | BR7706122A (es) |
| DD (1) | DD132789A5 (es) |
| DE (1) | DE2641381A1 (es) |
| ES (1) | ES462351A1 (es) |
| FR (1) | FR2364901A1 (es) |
| GB (1) | GB1536256A (es) |
| NL (1) | NL7710152A (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2844880A1 (de) * | 1978-10-14 | 1980-04-30 | Basf Ag | Verfahren zur herstellung von epsilon -caprolactam durch katalytische umlagerung von cyclohexanonoxim |
| DE3524394A1 (de) * | 1985-07-09 | 1987-01-15 | Basf Ag | Verfahren zur gewinnung von caprolactam durch spaltung von oligomeren des caprolactams |
| JPS62281856A (ja) * | 1986-02-27 | 1987-12-07 | Sumitomo Chem Co Ltd | ε−カプロラクタムの製造法 |
| NL1003564C2 (nl) * | 1996-07-11 | 1998-01-15 | Dsm Nv | Werkwijze voor het scheiden van een ketoxim of aldoxim van een amide. |
| EP1036589A3 (en) * | 1999-03-16 | 2000-12-13 | Sumitomo Chemical Company, Limited | Apparatus and process for producing Epsilon-caprolactam |
| EP1985609B1 (en) * | 2007-03-29 | 2010-09-01 | Sumitomo Chemical Company, Limited | Method for recovering cyclohexanone oxime |
| DE102008060340A1 (de) | 2008-12-03 | 2010-06-10 | Wolfgang F. Prof. Dr. Hölderich | Herstellung von Lactamen und Carbonsäureamide durch Beckmann-Umlagerung von Oximen in Gegenwart von Nb-Katalysatoren |
| DE102015005238A1 (de) | 2015-04-24 | 2016-10-27 | Wolfgang Hölderich | Herstellung von Lactamen durch Beckmann-Umlagerung von Oximen |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1195318B (de) * | 1961-06-10 | 1965-06-24 | Basf Ag | Verfahren zur Herstellung von Lactamen durch katalytische Umlagerung von cyclischen Ketoximen |
| DE1670816B2 (de) * | 1967-03-03 | 1976-09-02 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von lactam |
| DE1670860C3 (de) * | 1967-04-25 | 1974-06-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Lactamen |
| DE1670875A1 (de) * | 1967-06-02 | 1971-02-18 | Bayer Ag | Verfahren zur Herstellung von Lactamen |
-
1976
- 1976-09-15 DE DE19762641381 patent/DE2641381A1/de not_active Withdrawn
-
1977
- 1977-09-09 US US05/832,008 patent/US4141896A/en not_active Expired - Lifetime
- 1977-09-12 DD DD7700200977A patent/DD132789A5/xx unknown
- 1977-09-14 GB GB38323/77A patent/GB1536256A/en not_active Expired
- 1977-09-14 JP JP11004977A patent/JPS5337686A/ja active Pending
- 1977-09-14 ES ES462351A patent/ES462351A1/es not_active Expired
- 1977-09-14 BR BR7706122A patent/BR7706122A/pt unknown
- 1977-09-15 FR FR7727918A patent/FR2364901A1/fr active Granted
- 1977-09-15 BE BE180920A patent/BE858715A/xx unknown
- 1977-09-15 NL NL7710152A patent/NL7710152A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7710152A (nl) | 1978-03-17 |
| BE858715A (fr) | 1978-03-15 |
| JPS5337686A (en) | 1978-04-06 |
| DD132789A5 (de) | 1978-11-01 |
| DE2641381A1 (de) | 1978-03-16 |
| FR2364901A1 (fr) | 1978-04-14 |
| US4141896A (en) | 1979-02-27 |
| FR2364901B1 (es) | 1982-07-16 |
| GB1536256A (en) | 1978-12-20 |
| BR7706122A (pt) | 1978-07-04 |
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