ES455841A1 - Procedimiento para preparar composiciones insecticidas a ba-se de ditiofo-fatos-(-fonatos) de formamidina. - Google Patents
Procedimiento para preparar composiciones insecticidas a ba-se de ditiofo-fatos-(-fonatos) de formamidina.Info
- Publication number
- ES455841A1 ES455841A1 ES455841A ES455841A ES455841A1 ES 455841 A1 ES455841 A1 ES 455841A1 ES 455841 A ES455841 A ES 455841A ES 455841 A ES455841 A ES 455841A ES 455841 A1 ES455841 A1 ES 455841A1
- Authority
- ES
- Spain
- Prior art keywords
- insecticides
- dithiophosphates
- formamidine
- phosphonates
- certain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002917 insecticide Substances 0.000 title abstract 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 title 1
- OYBGEXUEOLSKAN-UHFFFAOYSA-N dihydroxy-sulfanyl-sulfanylidene-lambda5-phosphane methanimidamide Chemical class NC=N.OP(O)(S)=S OYBGEXUEOLSKAN-UHFFFAOYSA-N 0.000 title 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4075—Esters with hydroxyalkyl compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedimiento para preparar composiciones insecticidas a base de ditiofos-fatos(-fonatos) de formamidina, de fórmula: **(Fórmula 1)** en la que R1 es alquilo inferior o alcoxi inferior, R2 es alcoxi inferior o alcoxi inferior metilito-sustituido, R3 es **(Fórmula 2)** R4 y R5 son alquilo inferior, m es 1 ó 2 y n es 0 o un entero e 1 a 4; caracterizado porque comprende las etapas de: (a) hacer reaccionar una amina de fórmula R3H en donde R3 se define como anteriormente, con dimetilacetal de N,N-dimetilformamida, para formar el correspondiente N-formilacetal de fórmula R3-CH(OCH3)2; (b) hacer reaccionar el N-formilacetal r4sultante con una cloroalquilamida de fórmula NH2-CO-(CH2)mCl en donde m se define como anteriormente, para formar una formamidina de fórmula: R3-CH=N-CO-(CH2)mCl; (c) hacer reaccionar la formamidina resultante con ditiofosfato o -fosfonato.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/657,438 US4045557A (en) | 1976-02-12 | 1976-02-12 | Certain formamidine dithiophosphates and phosphonates and their use as insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES455841A1 true ES455841A1 (es) | 1978-06-16 |
Family
ID=24637186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES455841A Expired ES455841A1 (es) | 1976-02-12 | 1977-02-11 | Procedimiento para preparar composiciones insecticidas a ba-se de ditiofo-fatos-(-fonatos) de formamidina. |
Country Status (27)
| Country | Link |
|---|---|
| US (3) | US4045557A (es) |
| JP (1) | JPS5297917A (es) |
| AR (1) | AR217419A1 (es) |
| AU (1) | AU510093B2 (es) |
| BE (1) | BE851194A (es) |
| BR (1) | BR7700593A (es) |
| CA (1) | CA1084053A (es) |
| CS (1) | CS193568B2 (es) |
| DD (1) | DD129150A5 (es) |
| DE (1) | DE2704894A1 (es) |
| DK (1) | DK143345C (es) |
| ES (1) | ES455841A1 (es) |
| FR (1) | FR2340953A1 (es) |
| GB (1) | GB1527461A (es) |
| GR (1) | GR66142B (es) |
| GT (1) | GT197744730A (es) |
| IL (1) | IL51423A (es) |
| IN (1) | IN145421B (es) |
| IT (1) | IT1083156B (es) |
| NL (1) | NL7701475A (es) |
| NZ (1) | NZ183294A (es) |
| PH (1) | PH14169A (es) |
| PL (1) | PL104429B1 (es) |
| PT (1) | PT66187B (es) |
| SU (1) | SU667109A3 (es) |
| TR (1) | TR19080A (es) |
| ZA (1) | ZA77818B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2242078A (en) * | 1990-02-13 | 1991-09-18 | Keith Roberts | Connector with transparent body |
| JP2546525Y2 (ja) * | 1992-12-07 | 1997-09-03 | 株式会社カナメ | 重ね形屋根の改修構造 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL293677A (es) * | 1962-06-06 | |||
| BE639481A (es) * | 1963-11-08 | |||
| US3833600A (en) * | 1968-12-10 | 1974-09-03 | Ciba Geigy Ag | Dithiophosphates |
| DE1812497C3 (de) * | 1967-12-13 | 1978-04-13 | Ciba-Geigy Ag, Basel (Schweiz) | N-Phosphinothioyl-thiomethyl-carbonyl-piperidine, Verfahren zu ihrer Herstellung und diese enthaltende Mittel |
| JPS5527882B1 (es) * | 1970-05-13 | 1980-07-24 | ||
| BE789614A (fr) * | 1971-10-04 | 1973-04-03 | Ciba Geigy | Esters phosphoriques utilisables contre les insectes |
| US3966921A (en) * | 1972-03-17 | 1976-06-29 | Ciba-Geigy Corporation | Certain pesticidal phosphorus containing amidines |
| DE2445555A1 (de) * | 1974-09-24 | 1976-04-01 | Bayer Ag | S- eckige klammer auf isoureidocarbonylmethyl eckige klammer zu-(thiono) (di)thiolphosphor(phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung sowie ihre verwendung als insektizide und akarizide |
| US3984410A (en) * | 1975-12-10 | 1976-10-05 | Stauffer Chemical Company | Isourea acetylphosphate insecticides |
-
1976
- 1976-02-12 US US05/657,438 patent/US4045557A/en not_active Expired - Lifetime
-
1977
- 1977-01-08 TR TR19080A patent/TR19080A/xx unknown
- 1977-01-17 GT GT197744730A patent/GT197744730A/es unknown
- 1977-01-18 GB GB1910/77A patent/GB1527461A/en not_active Expired
- 1977-01-31 BR BR7700593A patent/BR7700593A/pt unknown
- 1977-01-31 JP JP888277A patent/JPS5297917A/ja active Pending
- 1977-01-31 SU SU772444304A patent/SU667109A3/ru active
- 1977-02-03 PH PH19418A patent/PH14169A/en unknown
- 1977-02-05 DE DE19772704894 patent/DE2704894A1/de not_active Withdrawn
- 1977-02-08 BE BE2055656A patent/BE851194A/xx unknown
- 1977-02-09 CA CA271,377A patent/CA1084053A/en not_active Expired
- 1977-02-10 IN IN193/CAL/77A patent/IN145421B/en unknown
- 1977-02-10 IT IT47992/77A patent/IT1083156B/it active
- 1977-02-10 FR FR7703741A patent/FR2340953A1/fr active Granted
- 1977-02-10 NZ NZ183294A patent/NZ183294A/xx unknown
- 1977-02-10 AU AU22163/77A patent/AU510093B2/en not_active Expired
- 1977-02-11 PT PT66187A patent/PT66187B/pt unknown
- 1977-02-11 IL IL51423A patent/IL51423A/xx unknown
- 1977-02-11 PL PL1977195943A patent/PL104429B1/pl unknown
- 1977-02-11 CS CS77928A patent/CS193568B2/cs unknown
- 1977-02-11 DD DD7700197343A patent/DD129150A5/xx unknown
- 1977-02-11 NL NL7701475A patent/NL7701475A/xx not_active Application Discontinuation
- 1977-02-11 ZA ZA770818A patent/ZA77818B/xx unknown
- 1977-02-11 AR AR266517A patent/AR217419A1/es active
- 1977-02-11 GR GR52773A patent/GR66142B/el unknown
- 1977-02-11 DK DK59877A patent/DK143345C/da active
- 1977-02-11 ES ES455841A patent/ES455841A1/es not_active Expired
- 1977-07-25 US US05/818,478 patent/US4115560A/en not_active Expired - Lifetime
- 1977-07-25 US US05/818,477 patent/US4115556A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| PT66187A (en) | 1977-03-01 |
| GB1527461A (en) | 1978-10-04 |
| DK143345C (da) | 1981-12-07 |
| PH14169A (en) | 1981-03-19 |
| IT1083156B (it) | 1985-05-21 |
| FR2340953B1 (es) | 1980-07-11 |
| DK143345B (da) | 1981-08-10 |
| PT66187B (en) | 1978-07-11 |
| IL51423A (en) | 1980-03-31 |
| PL104429B1 (pl) | 1979-08-31 |
| US4115556A (en) | 1978-09-19 |
| NL7701475A (nl) | 1977-08-16 |
| DD129150A5 (de) | 1978-01-04 |
| US4045557A (en) | 1977-08-30 |
| ZA77818B (en) | 1977-12-28 |
| CS193568B2 (en) | 1979-10-31 |
| CA1084053A (en) | 1980-08-19 |
| AU2216377A (en) | 1978-08-17 |
| US4115560A (en) | 1978-09-19 |
| AU510093B2 (en) | 1980-06-05 |
| TR19080A (tr) | 1978-05-01 |
| GT197744730A (es) | 1978-07-11 |
| AR217419A1 (es) | 1980-03-31 |
| FR2340953A1 (fr) | 1977-09-09 |
| IL51423A0 (en) | 1977-04-29 |
| NZ183294A (en) | 1978-07-28 |
| DE2704894A1 (de) | 1977-08-18 |
| SU667109A3 (ru) | 1979-06-05 |
| BE851194A (nl) | 1977-08-08 |
| JPS5297917A (en) | 1977-08-17 |
| IN145421B (es) | 1978-10-07 |
| GR66142B (es) | 1981-01-19 |
| BR7700593A (pt) | 1977-10-04 |
| DK59877A (da) | 1977-08-13 |
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