ES447873A1 - Process for the production of 2-aryl-2h-benzotriazoles - Google Patents

Process for the production of 2-aryl-2h-benzotriazoles

Info

Publication number
ES447873A1
ES447873A1 ES447873A ES447873A ES447873A1 ES 447873 A1 ES447873 A1 ES 447873A1 ES 447873 A ES447873 A ES 447873A ES 447873 A ES447873 A ES 447873A ES 447873 A1 ES447873 A1 ES 447873A1
Authority
ES
Spain
Prior art keywords
benzotriazoles
aryl
production
nitroazobenzene
cyclising
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES447873A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES447873A1 publication Critical patent/ES447873A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
    • C07D249/20—Benzotriazoles with aryl radicals directly attached in position 2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

2-Aryl-2H-benzotriazoles of the formula I are prepared by reducing a suitable o-nitroazobenzene with hydrogen in the form of a mixture in an aqueous alkaline medium at a pH greater than 10 in the presence of a noble metal hydrogenation catalyst, of Group VIII of the Periodic Table, or an oxide at 20 to 100 DEG C and 1 to 66 atmospheres, and cyclising the product. The meanings of the individual symbols are given in Claim 1. The compounds can be used as UV stabilisers. The process is environmentally friendly and gives high yields.
ES447873A 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles Expired ES447873A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57738375A 1975-05-14 1975-05-14

Publications (1)

Publication Number Publication Date
ES447873A1 true ES447873A1 (en) 1977-07-16

Family

ID=24308470

Family Applications (1)

Application Number Title Priority Date Filing Date
ES447873A Expired ES447873A1 (en) 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles

Country Status (9)

Country Link
JP (1) JPS6036429B2 (en)
BE (1) BE841768A (en)
BR (1) BR7603027A (en)
CH (1) CH615165A5 (en)
DE (1) DE2621006A1 (en)
ES (1) ES447873A1 (en)
FR (1) FR2311010A1 (en)
GB (1) GB1494825A (en)
NL (1) NL7605202A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1984002365A1 (en) * 1982-12-07 1984-06-21 Commw Scient Ind Res Org Use of substituted 2-(2'-hydroxyaryl)-2h-benzotriazolesulfonates as photostabilising agents for natural and synthetic fibres
JPS6471862A (en) * 1987-09-11 1989-03-16 Chemipro Kasei Kaisha Ltd Production of 2-phenylbenzotriazole
EP0363318B1 (en) * 1988-09-28 1994-03-02 Ciba-Geigy Ag Process for the preparation of benzotriazole derivatives
JPH02202880A (en) * 1989-01-31 1990-08-10 Kemipuro Kasei Kk Production of 2-phenylbenzotriazoles
JPH02202879A (en) * 1989-01-31 1990-08-10 Kemipuro Kasei Kk Production of 2-phenylbenzotriazoles
EP0419412B1 (en) * 1989-09-20 1993-11-10 Ciba-Geigy Ag Process for the preparation of benzotriazoles
CN112538055A (en) * 2020-12-11 2021-03-23 西安凯立新材料股份有限公司 Preparation method of benzotriazole ultraviolet absorbent
CN113480487B (en) * 2021-06-16 2022-12-02 三峡大学 Benzotriazole-containing fluorescent compound, and preparation method and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH529815A (en) * 1970-06-19 1972-10-31 Ciba Geigy Ag Use of 2- (2'-hydroxyphenyl) -benzotriazole compounds as light stabilizers
US3978074A (en) * 1973-11-21 1976-08-31 Uniroyal Inc. Method of making hydroxyarylbenzotriazoles and their N-oxides

Also Published As

Publication number Publication date
FR2311010B1 (en) 1978-05-19
FR2311010A1 (en) 1976-12-10
BE841768A (en) 1976-11-16
JPS6036429B2 (en) 1985-08-20
DE2621006A1 (en) 1976-12-02
BR7603027A (en) 1977-05-31
CH615165A5 (en) 1980-01-15
JPS51138676A (en) 1976-11-30
GB1494825A (en) 1977-12-14
NL7605202A (en) 1976-11-16

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