ES442985A1 - Procedure for the preparation of fungicide metallic salts. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for the preparation of fungicide metallic salts. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES442985A1 ES442985A1 ES442985A ES442985A ES442985A1 ES 442985 A1 ES442985 A1 ES 442985A1 ES 442985 A ES442985 A ES 442985A ES 442985 A ES442985 A ES 442985A ES 442985 A1 ES442985 A1 ES 442985A1
- Authority
- ES
- Spain
- Prior art keywords
- formula
- substituted
- preparation
- bisdithiocarbamate
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 3
- 230000000855 fungicidal effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000417 fungicide Substances 0.000 title 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 4
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 3
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 2
- 239000012990 dithiocarbamate Substances 0.000 abstract 2
- 150000002357 guanidines Chemical class 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- -1 hydroxy, amino Chemical group 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 2
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical class [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 1
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
- 125000004953 trihalomethyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
- C07D295/21—Radicals derived from sulfur analogues of carbonic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Process for the preparation of metal fungicidal salts, particularly for the preparation of an alkylene (or phenylene) bisdithiocarbamate/alkyl (or dialkyl) dithiocarbamate of ammonium, substituted ammonium, phosphonium and/or substituted phosphonium/metal, characterized in that it comprises reacting, in dissolution, (1) at least one C2-C6 alkylene (or phenylene) bisdithiocarbamate or one N, N'-substituted bisdithiocarbamate in which the two nitrogen atoms are each attached to two groups -CH2CH2- to form a heterocycle of six members; (2) at least one dithiocarbamate in which the nitrogen atom is optionally substituted by one or two saturated hydrocarbon groups that can be linked together to form a heterocycle; (3) at least one of the following: (a) an amine of the formula **(See formula)** (b) a guanidine salt, an N-alkyl substituted guanidine salt or a salt of the formula **(See formula)** (c) a salt of the formula **(See formula)** in which formulas X represents an anion and R1, R2, R3 and R4 each represent hydrogen, a saturated hydrocarbon group having up to 20 carbon atoms and optionally containing up to 3 substituents chosen from hydroxy, amino, alkynyl and halogen, a phenyl, naphthyl, benzyl or phenethyl group each optionally containing up to 3 substituents chosen from methyl, ethyl, methoxy, ethoxy, fluoro, chloro, bromo, iodo, nitro and trihalomethyl, with the proviso that in the formulas of (a) and (b) above R1 and R2 can be joined together to form the group **(See formula)** where Z is a methylene group, an oxygen atom, or a nitrogen atom and n and m are integers from 1 to 4; and a valence greater than 1. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52779474A | 1974-11-27 | 1974-11-27 | |
| US05/616,989 US4079146A (en) | 1974-11-27 | 1975-09-26 | Metal salts of mixed dithiocarbamic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES442985A1 true ES442985A1 (en) | 1977-10-16 |
Family
ID=27062515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES442985A Expired ES442985A1 (en) | 1974-11-27 | 1975-11-26 | Procedure for the preparation of fungicide metallic salts. (Machine-translation by Google Translate, not legally binding) |
Country Status (11)
| Country | Link |
|---|---|
| AU (1) | AU8705575A (en) |
| BR (1) | BR7507773A (en) |
| DD (1) | DD123755A5 (en) |
| DE (1) | DE2550451A1 (en) |
| ES (1) | ES442985A1 (en) |
| FR (1) | FR2292703A1 (en) |
| GR (1) | GR58542B (en) |
| IL (1) | IL48535A0 (en) |
| IT (1) | IT1051307B (en) |
| NL (1) | NL7513886A (en) |
| OA (1) | OA05173A (en) |
-
1975
- 1975-11-10 DD DD189370A patent/DD123755A5/xx unknown
- 1975-11-10 DE DE19752550451 patent/DE2550451A1/en active Pending
- 1975-11-24 OA OA55674A patent/OA05173A/en unknown
- 1975-11-24 GR GR49446A patent/GR58542B/en unknown
- 1975-11-25 BR BR7507773*A patent/BR7507773A/en unknown
- 1975-11-25 IL IL48535A patent/IL48535A0/en unknown
- 1975-11-26 ES ES442985A patent/ES442985A1/en not_active Expired
- 1975-11-26 FR FR7536194A patent/FR2292703A1/en not_active Withdrawn
- 1975-11-27 NL NL7513886A patent/NL7513886A/en unknown
- 1975-11-27 IT IT69932/75A patent/IT1051307B/en active
- 1975-11-27 AU AU87055/75A patent/AU8705575A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IL48535A0 (en) | 1976-01-30 |
| BR7507773A (en) | 1976-08-10 |
| OA05173A (en) | 1981-01-31 |
| GR58542B (en) | 1977-11-05 |
| DD123755A5 (en) | 1977-01-12 |
| FR2292703A1 (en) | 1976-06-25 |
| DE2550451A1 (en) | 1976-08-12 |
| IT1051307B (en) | 1981-04-21 |
| NL7513886A (en) | 1976-05-31 |
| AU8705575A (en) | 1977-06-02 |
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