FI894212A - Pesticidal 2-hydrazine-pyrimidine derivatives - Google Patents

Pesticidal 2-hydrazine-pyrimidine derivatives Download PDF

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Publication number
FI894212A
FI894212A FI894212A FI894212A FI894212A FI 894212 A FI894212 A FI 894212A FI 894212 A FI894212 A FI 894212A FI 894212 A FI894212 A FI 894212A FI 894212 A FI894212 A FI 894212A
Authority
FI
Finland
Prior art keywords
alkyl
denotes
alkenyl
cycloalkyl
halogen
Prior art date
Application number
FI894212A
Other languages
Finnish (fi)
Swedish (sv)
Other versions
FI98914B (en
FI98914C (en
FI894212A0 (en
Inventor
Helmut Zondler
Adolf Hubele
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of FI894212A0 publication Critical patent/FI894212A0/en
Publication of FI894212A publication Critical patent/FI894212A/en
Publication of FI98914B publication Critical patent/FI98914B/en
Application granted granted Critical
Publication of FI98914C publication Critical patent/FI98914C/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32One oxygen, sulfur or nitrogen atom
    • C07D239/34One oxygen atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32One oxygen, sulfur or nitrogen atom
    • C07D239/42One nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D403/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D409/00Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

Compounds of the formula <IMAGE> in which: R1 denotes phenyl or phenyl which is monosubstituted to trisubstituted by R4; R2 denotes hydrogen, C1-C5-alkyl, C1-C5-alkyl substituted by the radicals OR5 or SR5, C3-C6-cycloalkyl, C3-C6-cycloalkyl monosubstituted to trisubstituted by C1-C4-alkyl or halogen, C2-C5-alkenyl, C2-C5-alkynyl or the formyl radical; R3 denotes hydrogen, C1-C4-alkyl, C1-C4-alkyl which is substituted by halogen, cyano or the radicals OR5 or SR5, C3-C6-cycloalkyl or C3-C6-cycloalkyl which is monosubstituted to trisubstituted by C1-C4-alkyl or halogen; R4 denotes halogen, C1-C3-alkyl, C1-C2-haloalkyl, C1-C3-alkoxy or C1-C3-haloalkoxy; R5 denotes hydrogen, C1-C5-alkyl, C3-C5-alkenyl, C3-C5-alkynyl or the radical (CH2)n-X-C1-C3-alkyl; R7 denotes the group -NH2, <IMAGE> or <IMAGE>; R8 denotes hydrogen, C1-C3-alkyl or C1-C3-haloalkyl; R9 denotes hydrogen, C1-C8-alkyl, C1-C3-alkyl substituted by hydroxyl, OR12, SR12 or N(R12)2, C3-C6-cycloalkyl, cyclopropyl substituted by SR12, C3-C10-alkenyl, C1-C3-haloalkyl, phenyl, phenyl which is monosubstituted to trisubstituted by halogen, C1-C3-alkyl, C1-C3-alkoxy, C1-C3-haloalkoxy, C1-C2-haloalkyl, hydroxyl, nitro, cyano, amino or dimethylamino, 1- or 2-naphthyl, 1-, 2- or 3-pyridyl, <IMAGE> or <IMAGE>; R8 and R9, together with the carbon atom in the radical R7, form a saturated or unsaturated ring consisting of 4 to 7 carbon atoms; R10 denotes CH(R8)R9, phenyl, C3-C5-alkenyl, C3-C5-alkynyl or cyanoalkyl having 2 or 3 carbon atoms in the alkyl radical; R11 denotes hydrogen, C1-C5-alkyl, C3-C5-alkenyl, C3-C5-alkynyl or cyanoalkyl having 2 or 3 carbon atoms in the alkyl radical; R12 denotes CH3 or C2H5; X denotes oxygen or sulphur; Z denotes O, S, NH or NCH3; and n denotes 1 to 3; including their acid addition salts and metal salt complexes, have useful microbicidal properties. The novel active compounds can be employed in plant protection for preventing the attack of crop plants by phytopathogenic microorganisms or by harmful insects and for controlling these pests.
FI894212A 1988-09-09 1989-09-06 Pesticidal 2-hydrazine-pyrimidine derivatives FI98914C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CH337188 1988-09-09
CH337188 1988-09-09
CH257989 1989-07-11
CH257989 1989-07-11

Publications (4)

Publication Number Publication Date
FI894212A0 FI894212A0 (en) 1989-09-06
FI894212A true FI894212A (en) 1990-03-10
FI98914B FI98914B (en) 1997-05-30
FI98914C FI98914C (en) 1997-09-10

Family

ID=25690828

Family Applications (1)

Application Number Title Priority Date Filing Date
FI894212A FI98914C (en) 1988-09-09 1989-09-06 Pesticidal 2-hydrazine-pyrimidine derivatives

Country Status (15)

Country Link
EP (1) EP0358609B1 (en)
JP (1) JP2832544B2 (en)
AT (1) ATE140699T1 (en)
AU (1) AU626913B2 (en)
BR (1) BR8904485A (en)
DE (1) DE58909704D1 (en)
DK (1) DK170336B1 (en)
ES (1) ES2090045T3 (en)
FI (1) FI98914C (en)
GR (1) GR3020621T3 (en)
HU (1) HU207998B (en)
IE (1) IE72462B1 (en)
IL (1) IL91556A (en)
NZ (1) NZ230592A (en)
PT (1) PT91648B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3881320D1 (en) * 1987-09-28 1993-07-01 Ciba Geigy Ag PEST CONTROL.
TR25912A (en) * 1989-03-22 1993-11-01 Ciba Geigy Ag 2-ANILIN-PRIMIDIN DERIVATIVES ARE OBTAINED FROM THESE SUBSTANCES AND THEIR USE IN THE FIGHT AGAINST PESTS
JPH0859628A (en) * 1994-08-26 1996-03-05 Sumitomo Chem Co Ltd Production of pyrimidine derivative

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL38815A0 (en) * 1971-03-05 1972-04-27 Ciba Geigy Ag Iodoethynyl compounds,their manufacture and their use
JPS55151570A (en) * 1979-05-15 1980-11-26 Takeda Chem Ind Ltd Pyrimidine derivatives, their preparation and antimicrobial for agriculture
DE3441935A1 (en) * 1984-11-16 1986-05-28 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING 2,4-DIHYDROXYPYRIMIDINES
JPH0784445B2 (en) * 1986-12-03 1995-09-13 クミアイ化学工業株式会社 Pyrimidine derivatives and agricultural and horticultural fungicides
US4929726A (en) * 1988-02-09 1990-05-29 Georgia State University Foundation, Inc. Novel diazines and their method of preparation
TR25912A (en) * 1989-03-22 1993-11-01 Ciba Geigy Ag 2-ANILIN-PRIMIDIN DERIVATIVES ARE OBTAINED FROM THESE SUBSTANCES AND THEIR USE IN THE FIGHT AGAINST PESTS
DE4017460A1 (en) * 1989-10-10 1991-04-18 Bayer Ag New substd. sulphonyl-amidino hydrazone(s) - are defoliants, desiccants and weed killers

Also Published As

Publication number Publication date
IE892881L (en) 1990-03-09
HUT51604A (en) 1990-05-28
HU207998B (en) 1993-07-28
NZ230592A (en) 1992-02-25
EP0358609A3 (en) 1990-10-10
GR3020621T3 (en) 1996-10-31
DK444189D0 (en) 1989-09-08
IL91556A0 (en) 1990-04-29
FI98914B (en) 1997-05-30
JPH02115174A (en) 1990-04-27
PT91648B (en) 1995-05-31
FI98914C (en) 1997-09-10
DK170336B1 (en) 1995-08-07
PT91648A (en) 1990-03-30
ATE140699T1 (en) 1996-08-15
EP0358609A2 (en) 1990-03-14
AU626913B2 (en) 1992-08-13
AU4119289A (en) 1990-03-15
DK444189A (en) 1990-03-10
IL91556A (en) 1994-01-25
IE72462B1 (en) 1997-04-09
FI894212A0 (en) 1989-09-06
EP0358609B1 (en) 1996-07-24
BR8904485A (en) 1990-04-24
JP2832544B2 (en) 1998-12-09
ES2090045T3 (en) 1996-10-16
DE58909704D1 (en) 1996-08-29

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Legal Events

Date Code Title Description
BB Publication of examined application
GB Transfer or assigment of application

Owner name: NOVARTIS AG

MM Patent lapsed
MM Patent lapsed

Owner name: NOVARTIS AG