ES420493A1 - Process for the preparation of thiazolesulphenamides - Google Patents

Process for the preparation of thiazolesulphenamides

Info

Publication number
ES420493A1
ES420493A1 ES420493A ES420493A ES420493A1 ES 420493 A1 ES420493 A1 ES 420493A1 ES 420493 A ES420493 A ES 420493A ES 420493 A ES420493 A ES 420493A ES 420493 A1 ES420493 A1 ES 420493A1
Authority
ES
Spain
Prior art keywords
carbon atoms
alkyl
general formula
alkyloxy
radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES420493A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of ES420493A1 publication Critical patent/ES420493A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/76—Sulfur atoms attached to a second hetero atom
    • C07D277/80—Sulfur atoms attached to a second hetero atom to a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/36—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • C08K5/47—Thiazoles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedure for preparing thiazolsulfenamides, of general formula: **(See formula)** wherein: R1 and R2, identical or different, represent a hydrogen atom, a halogen atom, an alkyl or alkyloxy radical comprising from 1 to 5 carbon atoms, an aryl radical comprising from 6 to 12 carbon atoms, optionally substituted by one or more halogen, nitro group, alkyl or alkyloxy radicals that comprise from 5 carbon atoms, or together form a divalent radical of the general formula: **(See formula)** wherein R', R ", R''' 7 R'''', identical or different, represent a hydrogen atom, a halogen atom, a nitro group, an alkyl or alkyloxy radical comprising 1 to 5 carbon atoms, an aryl radical comprising 6 to 12 carbon atoms, as defined for R1 and R2, R3 and R4, identical or different, designate a hydrogen atom, branched or linear alkyl radicals comprising of 1 to 20 carbon atoms, cycloalkyl radicals comprising from 5 to 12 carbon atoms; arylalkyl radicals comprising from 7 to 15 carbon atoms, or together with the nitrogen atom to which they bind, form a heterocycle comprising from 5 to 7 rings and from 1 to 3 heteroatoms taken from the group consisting of nitrogen, oxide and sulfur, optionally substituted by alkyl or alkyloxy groups comprising 1 to 5 carbon atoms; characterized in that it comprises reacting a dithiazolyl-2 disulfide, 2'of general formula: **(See formula)** with a nitrogenous compound of general formula: **(See formula)** R1, R2, R3 and R4 having the meanings given above, in the presence of oxygen or a gas containing it and of a catalyst of copper or its derivatives other than complexes of copper and phthalocyanines. (Machine-translation by Google Translate, not legally binding)
ES420493A 1972-11-13 1973-11-13 Process for the preparation of thiazolesulphenamides Expired ES420493A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7240187A FR2206761A5 (en) 1972-11-13 1972-11-13

Publications (1)

Publication Number Publication Date
ES420493A1 true ES420493A1 (en) 1976-04-01

Family

ID=9107070

Family Applications (1)

Application Number Title Priority Date Filing Date
ES420493A Expired ES420493A1 (en) 1972-11-13 1973-11-13 Process for the preparation of thiazolesulphenamides

Country Status (16)

Country Link
JP (1) JPS49133372A (en)
AU (1) AU474746B2 (en)
BE (1) BE807204A (en)
BR (1) BR7308864D0 (en)
CA (1) CA1014161A (en)
CH (1) CH581124A5 (en)
DD (1) DD107466A5 (en)
DE (1) DE2356686A1 (en)
ES (1) ES420493A1 (en)
FR (1) FR2206761A5 (en)
GB (1) GB1407917A (en)
IT (1) IT1033071B (en)
NL (1) NL7315144A (en)
PL (1) PL89545B1 (en)
SU (1) SU543350A3 (en)
ZA (1) ZA738587B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4182873A (en) 1972-10-04 1980-01-08 Rhone-Poulenc S.A. Process for the preparation of thiazolesulphenamides
ZA807138B (en) * 1979-11-23 1981-11-25 Monsanto Europe Sa Process for the production of sulphenamides
DE3113298A1 (en) * 1981-04-02 1982-10-21 Akzo Gmbh, 5600 Wuppertal METHOD FOR PRODUCING DITHIAZOLYL DISULFIDES
DE3325724A1 (en) * 1983-07-16 1985-01-24 Akzo Gmbh, 5600 Wuppertal METHOD FOR PRODUCING THIAZOLYL-2 SULFENAMIDES
DE3430435A1 (en) * 1984-08-18 1986-02-27 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING BENZOTHIAZOLYL SULFEN AMIDES

Also Published As

Publication number Publication date
ZA738587B (en) 1974-09-25
CH581124A5 (en) 1976-10-29
CA1014161A (en) 1977-07-19
GB1407917A (en) 1975-10-01
BE807204A (en) 1974-05-13
AU474746B2 (en) 1976-07-29
JPS49133372A (en) 1974-12-21
SU543350A3 (en) 1977-01-15
FR2206761A5 (en) 1974-06-07
BR7308864D0 (en) 1974-08-22
AU6230673A (en) 1975-05-08
NL7315144A (en) 1974-05-15
DE2356686A1 (en) 1974-05-16
PL89545B1 (en) 1976-11-30
IT1033071B (en) 1979-07-10
DD107466A5 (en) 1974-08-05

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