ES420493A1 - Process for the preparation of thiazolesulphenamides - Google Patents
Process for the preparation of thiazolesulphenamidesInfo
- Publication number
- ES420493A1 ES420493A1 ES420493A ES420493A ES420493A1 ES 420493 A1 ES420493 A1 ES 420493A1 ES 420493 A ES420493 A ES 420493A ES 420493 A ES420493 A ES 420493A ES 420493 A1 ES420493 A1 ES 420493A1
- Authority
- ES
- Spain
- Prior art keywords
- carbon atoms
- alkyl
- general formula
- alkyloxy
- radicals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
- C07D277/76—Sulfur atoms attached to a second hetero atom
- C07D277/80—Sulfur atoms attached to a second hetero atom to a nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D277/36—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedure for preparing thiazolsulfenamides, of general formula: **(See formula)** wherein: R1 and R2, identical or different, represent a hydrogen atom, a halogen atom, an alkyl or alkyloxy radical comprising from 1 to 5 carbon atoms, an aryl radical comprising from 6 to 12 carbon atoms, optionally substituted by one or more halogen, nitro group, alkyl or alkyloxy radicals that comprise from 5 carbon atoms, or together form a divalent radical of the general formula: **(See formula)** wherein R', R ", R''' 7 R'''', identical or different, represent a hydrogen atom, a halogen atom, a nitro group, an alkyl or alkyloxy radical comprising 1 to 5 carbon atoms, an aryl radical comprising 6 to 12 carbon atoms, as defined for R1 and R2, R3 and R4, identical or different, designate a hydrogen atom, branched or linear alkyl radicals comprising of 1 to 20 carbon atoms, cycloalkyl radicals comprising from 5 to 12 carbon atoms; arylalkyl radicals comprising from 7 to 15 carbon atoms, or together with the nitrogen atom to which they bind, form a heterocycle comprising from 5 to 7 rings and from 1 to 3 heteroatoms taken from the group consisting of nitrogen, oxide and sulfur, optionally substituted by alkyl or alkyloxy groups comprising 1 to 5 carbon atoms; characterized in that it comprises reacting a dithiazolyl-2 disulfide, 2'of general formula: **(See formula)** with a nitrogenous compound of general formula: **(See formula)** R1, R2, R3 and R4 having the meanings given above, in the presence of oxygen or a gas containing it and of a catalyst of copper or its derivatives other than complexes of copper and phthalocyanines. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7240187A FR2206761A5 (en) | 1972-11-13 | 1972-11-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES420493A1 true ES420493A1 (en) | 1976-04-01 |
Family
ID=9107070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES420493A Expired ES420493A1 (en) | 1972-11-13 | 1973-11-13 | Process for the preparation of thiazolesulphenamides |
Country Status (16)
Country | Link |
---|---|
JP (1) | JPS49133372A (en) |
AU (1) | AU474746B2 (en) |
BE (1) | BE807204A (en) |
BR (1) | BR7308864D0 (en) |
CA (1) | CA1014161A (en) |
CH (1) | CH581124A5 (en) |
DD (1) | DD107466A5 (en) |
DE (1) | DE2356686A1 (en) |
ES (1) | ES420493A1 (en) |
FR (1) | FR2206761A5 (en) |
GB (1) | GB1407917A (en) |
IT (1) | IT1033071B (en) |
NL (1) | NL7315144A (en) |
PL (1) | PL89545B1 (en) |
SU (1) | SU543350A3 (en) |
ZA (1) | ZA738587B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4182873A (en) | 1972-10-04 | 1980-01-08 | Rhone-Poulenc S.A. | Process for the preparation of thiazolesulphenamides |
ZA807138B (en) * | 1979-11-23 | 1981-11-25 | Monsanto Europe Sa | Process for the production of sulphenamides |
DE3113298A1 (en) * | 1981-04-02 | 1982-10-21 | Akzo Gmbh, 5600 Wuppertal | METHOD FOR PRODUCING DITHIAZOLYL DISULFIDES |
DE3325724A1 (en) * | 1983-07-16 | 1985-01-24 | Akzo Gmbh, 5600 Wuppertal | METHOD FOR PRODUCING THIAZOLYL-2 SULFENAMIDES |
DE3430435A1 (en) * | 1984-08-18 | 1986-02-27 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING BENZOTHIAZOLYL SULFEN AMIDES |
-
1972
- 1972-11-13 FR FR7240187A patent/FR2206761A5/fr not_active Expired
-
1973
- 1973-11-05 NL NL7315144A patent/NL7315144A/xx not_active Application Discontinuation
- 1973-11-08 AU AU62306/73A patent/AU474746B2/en not_active Expired
- 1973-11-08 JP JP48125037A patent/JPS49133372A/ja active Pending
- 1973-11-08 ZA ZA738587A patent/ZA738587B/en unknown
- 1973-11-09 DD DD174562*A patent/DD107466A5/xx unknown
- 1973-11-10 PL PL1973166451A patent/PL89545B1/en unknown
- 1973-11-12 BR BR8864/73A patent/BR7308864D0/en unknown
- 1973-11-12 GB GB5234673A patent/GB1407917A/en not_active Expired
- 1973-11-12 BE BE137652A patent/BE807204A/en unknown
- 1973-11-12 CH CH1584973A patent/CH581124A5/xx not_active IP Right Cessation
- 1973-11-12 SU SU1969062A patent/SU543350A3/en active
- 1973-11-13 DE DE2356686A patent/DE2356686A1/en active Pending
- 1973-11-13 IT IT31267/73A patent/IT1033071B/en active
- 1973-11-13 ES ES420493A patent/ES420493A1/en not_active Expired
- 1973-11-13 CA CA185,589A patent/CA1014161A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
PL89545B1 (en) | 1976-11-30 |
BE807204A (en) | 1974-05-13 |
JPS49133372A (en) | 1974-12-21 |
FR2206761A5 (en) | 1974-06-07 |
NL7315144A (en) | 1974-05-15 |
CA1014161A (en) | 1977-07-19 |
IT1033071B (en) | 1979-07-10 |
ZA738587B (en) | 1974-09-25 |
BR7308864D0 (en) | 1974-08-22 |
CH581124A5 (en) | 1976-10-29 |
DD107466A5 (en) | 1974-08-05 |
DE2356686A1 (en) | 1974-05-16 |
AU474746B2 (en) | 1976-07-29 |
AU6230673A (en) | 1975-05-08 |
GB1407917A (en) | 1975-10-01 |
SU543350A3 (en) | 1977-01-15 |
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