ES2886084T3 - Procedimiento para la producción de coque y gas de pirólisis en un horno rotativo - Google Patents
Procedimiento para la producción de coque y gas de pirólisis en un horno rotativo Download PDFInfo
- Publication number
- ES2886084T3 ES2886084T3 ES18203090T ES18203090T ES2886084T3 ES 2886084 T3 ES2886084 T3 ES 2886084T3 ES 18203090 T ES18203090 T ES 18203090T ES 18203090 T ES18203090 T ES 18203090T ES 2886084 T3 ES2886084 T3 ES 2886084T3
- Authority
- ES
- Spain
- Prior art keywords
- coke
- rotary kiln
- bulk material
- pyrolysis
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000571 coke Substances 0.000 title claims abstract description 113
- 238000000034 method Methods 0.000 title claims abstract description 112
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 93
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000013590 bulk material Substances 0.000 claims abstract description 81
- 230000008569 process Effects 0.000 claims abstract description 81
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000007789 gas Substances 0.000 claims abstract description 63
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 32
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 28
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 229910001868 water Inorganic materials 0.000 claims abstract description 23
- 230000004913 activation Effects 0.000 claims abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 18
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 9
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000011049 filling Methods 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 28
- 229910052717 sulfur Inorganic materials 0.000 claims description 27
- 239000011593 sulfur Substances 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 22
- 239000000428 dust Substances 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 6
- 239000011269 tar Substances 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001994 activation Methods 0.000 description 15
- 238000001816 cooling Methods 0.000 description 15
- 239000003077 lignite Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- 239000003463 adsorbent Substances 0.000 description 7
- 239000003546 flue gas Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/30—Other processes in rotary ovens or retorts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102017125297.5A DE102017125297B4 (de) | 2017-10-27 | 2017-10-27 | Verfahren zur Herstellung von Koks und/oder Pyrolysegas in einem Drehrohrofen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2886084T3 true ES2886084T3 (es) | 2021-12-16 |
Family
ID=64082940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES18203090T Active ES2886084T3 (es) | 2017-10-27 | 2018-10-29 | Procedimiento para la producción de coque y gas de pirólisis en un horno rotativo |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP3476916B1 (pl) |
| DE (1) | DE102017125297B4 (pl) |
| DK (1) | DK3476916T3 (pl) |
| ES (1) | ES2886084T3 (pl) |
| HR (1) | HRP20211155T1 (pl) |
| HU (1) | HUE055626T2 (pl) |
| LT (1) | LT3476916T (pl) |
| PL (1) | PL3476916T3 (pl) |
| SI (1) | SI3476916T1 (pl) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115823593A (zh) * | 2022-12-08 | 2023-03-21 | 安徽省天助纺织科技集团股份有限公司 | 一种废旧纺织品气化处理装置及其处理方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI60402C (fi) * | 1978-11-28 | 1982-01-11 | Outokumpu Oy | Foerfarande och anordning foer framstaellning av koks eller aktivt kol fraon fuktig organisk substans |
| DE4235368A1 (de) * | 1991-10-21 | 1993-04-22 | Mitsui Mining Co Ltd | Verfahren zum herstellen von aktiviertem formkoks und durch dieses verfahren erhaltener formkoks und brenngas |
| DE19912154C5 (de) * | 1999-03-17 | 2007-02-01 | Carbotex Produktions-Und Veredelungsbetriebe Gmbh | Verfahren zur Herstellung von geformter Aktivkohle |
| DE102008039817A1 (de) * | 2008-08-22 | 2010-02-25 | Corina Projahn | Pyrolyseprodukt und seine Verwendung |
| JP5804971B2 (ja) * | 2012-02-24 | 2015-11-04 | 三菱重工業株式会社 | 改質石炭製造設備 |
| DE102012011549B4 (de) * | 2012-06-09 | 2023-02-23 | Dornier Power and Heat GmbH | Erzeugung eines Braunkohlenkoksstaubes |
| JP2014031548A (ja) * | 2012-08-03 | 2014-02-20 | Mitsubishi Heavy Ind Ltd | 銑鉄製造方法及びこれに使用する高炉設備 |
| JP5449479B2 (ja) * | 2012-08-06 | 2014-03-19 | 三菱重工業株式会社 | 石炭乾留装置及びこれを利用する改質石炭製造設備 |
| CN103693805B (zh) * | 2013-12-02 | 2014-12-10 | 陕西煤业化工技术研究院有限责任公司 | 一种煤热解废弃物的回收利用装置及方法 |
| DE102013113660A1 (de) * | 2013-12-06 | 2015-06-11 | Thyssenkrupp Ag | Verfahren und Koksgewinnungsanlage zur Behandlung von schwefelhaltigen Prozessrückständen aus der Erdölverarbeitung; Petrolkoks gebildet aus schwefelhaltigen Prozessrückständen |
-
2017
- 2017-10-27 DE DE102017125297.5A patent/DE102017125297B4/de active Active
-
2018
- 2018-10-29 PL PL18203090T patent/PL3476916T3/pl unknown
- 2018-10-29 SI SI201830336T patent/SI3476916T1/sl unknown
- 2018-10-29 HU HUE18203090A patent/HUE055626T2/hu unknown
- 2018-10-29 EP EP18203090.8A patent/EP3476916B1/de active Active
- 2018-10-29 LT LTEP18203090.8T patent/LT3476916T/lt unknown
- 2018-10-29 ES ES18203090T patent/ES2886084T3/es active Active
- 2018-10-29 DK DK18203090.8T patent/DK3476916T3/da active
-
2021
- 2021-07-20 HR HRP20211155TT patent/HRP20211155T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE102017125297B4 (de) | 2021-03-04 |
| EP3476916A1 (de) | 2019-05-01 |
| EP3476916B1 (de) | 2021-04-21 |
| LT3476916T (lt) | 2021-08-10 |
| SI3476916T1 (sl) | 2021-09-30 |
| DK3476916T3 (da) | 2021-07-26 |
| HUE055626T2 (hu) | 2021-12-28 |
| DE102017125297A1 (de) | 2019-05-02 |
| HRP20211155T1 (hr) | 2021-10-15 |
| PL3476916T3 (pl) | 2021-12-06 |
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