ES2705925T3 - Espesantes no iónicos asociativos que contienen ciclohexiloles de alquilo, formulaciones que los contienen y sus usos - Google Patents
Espesantes no iónicos asociativos que contienen ciclohexiloles de alquilo, formulaciones que los contienen y sus usos Download PDFInfo
- Publication number
- ES2705925T3 ES2705925T3 ES12731136T ES12731136T ES2705925T3 ES 2705925 T3 ES2705925 T3 ES 2705925T3 ES 12731136 T ES12731136 T ES 12731136T ES 12731136 T ES12731136 T ES 12731136T ES 2705925 T3 ES2705925 T3 ES 2705925T3
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- ES
- Spain
- Prior art keywords
- weight
- carbon atoms
- formulation
- monomer
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 125000000217 alkyl group Chemical group 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 title claims description 58
- 238000009472 formulation Methods 0.000 title claims description 29
- 239000002562 thickening agent Substances 0.000 title description 22
- 239000004814 polyurethane Substances 0.000 claims abstract description 51
- 229920002635 polyurethane Polymers 0.000 claims abstract description 51
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 42
- 239000000178 monomer Substances 0.000 claims abstract description 32
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 18
- 238000009833 condensation Methods 0.000 claims abstract description 15
- 230000005494 condensation Effects 0.000 claims abstract description 15
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 13
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 13
- 239000003973 paint Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000013011 aqueous formulation Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 230000003115 biocidal effect Effects 0.000 claims description 8
- 239000003139 biocide Substances 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 230000008719 thickening Effects 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 239000002537 cosmetic Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 239000004922 lacquer Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 11
- 230000002209 hydrophobic effect Effects 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- -1 alkylene glycol Chemical compound 0.000 description 7
- 125000001165 hydrophobic group Chemical group 0.000 description 7
- 241000283986 Lepus Species 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 230000006399 behavior Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000013638 trimer Substances 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- OHTRJOZKRSVAOX-UHFFFAOYSA-N 1,3-diisocyanato-2-methylcyclohexane Chemical compound CC1C(N=C=O)CCCC1N=C=O OHTRJOZKRSVAOX-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 1
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- AVERNHDYEFYHIV-UHFFFAOYSA-N dodecan-5-ol Chemical compound CCCCCCCC(O)CCCC AVERNHDYEFYHIV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
- C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1155156A FR2976580B1 (fr) | 2011-06-14 | 2011-06-14 | Epaississants non ioniques associatifs contenant des alkyls cyclohexylols, formulations les contenant et leurs utilisations. |
| PCT/FR2012/051315 WO2012172249A1 (fr) | 2011-06-14 | 2012-06-12 | Epaississants non ioniques associatifs contenant des alkyls cyclohexylols, formulations les contenant et leurs utilisations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2705925T3 true ES2705925T3 (es) | 2019-03-27 |
Family
ID=46420449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12731136T Active ES2705925T3 (es) | 2011-06-14 | 2012-06-12 | Espesantes no iónicos asociativos que contienen ciclohexiloles de alquilo, formulaciones que los contienen y sus usos |
Country Status (16)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2976579B1 (fr) * | 2011-06-14 | 2013-07-05 | Coatex Sas | Epaississants non ioniques associatifs contenant des alkyls cyclohexylols, formulations les contenant et leurs utilisations |
| IN2014DE02424A (cg-RX-API-DMAC10.html) * | 2013-10-28 | 2015-07-10 | Rohm & Haas | |
| CN106349113B (zh) * | 2015-07-16 | 2017-12-26 | 中国石油化工股份有限公司 | 一种疏水单体及基于该单体的钻井堵漏用水凝胶 |
| FR3039833B1 (fr) * | 2015-08-05 | 2017-09-01 | Coatex Sas | Agent epaississant pour systemes aqueux, formulations le contenant et utilisations |
| FR3064530A1 (fr) | 2017-03-31 | 2018-10-05 | Saint-Gobain Glass France | Ensemble vitre lumineux |
| CN110785448A (zh) * | 2017-04-13 | 2020-02-11 | 毕克化学有限公司 | 适合作为增稠剂的聚合物 |
| CN112225877A (zh) * | 2020-09-04 | 2021-01-15 | 华南理工大学 | 一种三官能度异氰酸酯改性聚氨酯增稠剂及其制备方法 |
| FR3139824B1 (fr) | 2022-09-15 | 2026-05-01 | Coatex Sas | Copolymère uréthane cycloalkylé épaississant |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE501624C2 (sv) | 1992-09-15 | 1995-04-03 | Berol Nobel Ab | Polyuretan, dess användning och vattenburen färg innehållande polyuretanen som förtjockare |
| DE4327481A1 (de) | 1993-08-16 | 1995-02-23 | Bayer Ag | Als Verdickungsmittel geeignete Polyurethane und ihre Verwendung zur Verdickung wäßriger Systeme |
| JPH07112948A (ja) * | 1993-10-15 | 1995-05-02 | New Japan Chem Co Ltd | ４−アルキルシクロヘキサノール異性体混合物の製造方法 |
| DE19503281A1 (de) * | 1995-02-02 | 1996-08-08 | Bayer Ag | Als Verdickungsmittel für wäßrige Systeme geeignete Polyurethane |
| TW460508B (en) * | 1997-05-02 | 2001-10-21 | Rohm & Haas | Aqueous composition comprising a mixed surfactant/associative thickener, its use in a formulated composition, and method for enhancing thickening efficiency of aqueous composition |
| US6111146A (en) | 1997-09-03 | 2000-08-29 | Rayborn; Randy L. | Alkyl cyclohexanol alkoxylates and method for making same |
| JP2000072699A (ja) * | 1998-09-01 | 2000-03-07 | Mitsui Chemicals Inc | 高純度アルキルシクロヘキサノールの製造方法 |
| KR100613969B1 (ko) | 1998-12-17 | 2006-08-18 | 가부시키가이샤 시세이도 | 화장료 조성물 |
| ID28969A (id) * | 1998-12-18 | 2001-07-19 | Dow Chemical Co | Dispersi-dispersi poliuretan encer yang berguna untuk menyiapkan polimer-polimer dengan sifat-sifat resistansi kelembaban yang ditingkatkan |
| UA53729C2 (uk) * | 2000-02-03 | 2003-02-17 | Інститут Хімії Високомолекулярних Сполук Нан України | Спосіб одержання іономерних водорозчинних поліуретанів |
| ATE366783T1 (de) * | 2000-05-19 | 2007-08-15 | Akzo Nobel Coatings Int Bv | Wässrige vernetzbare bindemittelzusammensetzung und beschichtungs-, lack- oder dichtmittel- zusammensetzung, die diese bindemittelzusammensetzung beinhaltet |
| DE10111792A1 (de) | 2001-03-12 | 2002-09-26 | Borchers Gmbh | Neue Polyurethane und ihre Verwendung zur Verdickung wässriger Systeme |
| FR2826014B1 (fr) | 2001-06-19 | 2007-04-13 | Coatex Sas | Epaississants non ioniques pour compositions pigmentaires, notamment pour peintures, assurant la compatibilite pigmentaire, et leurs applications |
| US20030050388A1 (en) * | 2001-09-06 | 2003-03-13 | Strickland Debra S. | Aqueous coating composition |
| DE10306243A1 (de) * | 2003-02-14 | 2004-08-26 | Bayer Ag | Einkomponenten-Beschichtungssysteme |
| DE102004008015A1 (de) * | 2004-02-19 | 2005-09-08 | Cognis Deutschland Gmbh & Co. Kg | Verdickungsmittel für Polyurethanbasis |
| EP1908743A4 (en) * | 2005-07-26 | 2010-09-29 | Mitsubishi Gas Chemical Co | (ALKYLPHENYL) ALKYLCYCLOHEXAN AND METHOD FOR THE PRODUCTION OF (ALKYLPHENYL) ALKYLCYCLOHEXAN OR ALKYLBIOPHENYL |
| DE102006023001A1 (de) * | 2006-05-17 | 2007-11-22 | Cognis Ip Management Gmbh | Verdickungsmittel auf Polyurethanbasis |
| DE102007059858A1 (de) * | 2007-12-12 | 2009-06-18 | Bayer Materialscience Ag | Energiewandler hergestellt aus filmbildenden wässrigen Polymer-Dispersionen, insbesondere Polyurethan-Dispersionen |
| FR2949783B1 (fr) * | 2009-09-10 | 2012-08-17 | Coatex Sas | Polyurethanes associatifs a base de cardanol, epaississants associatifs correspondants et leurs utilisations. |
| ES2487465T1 (es) * | 2011-05-19 | 2014-08-20 | Tigenix, S.A.U. | Poblaciones celulares que tienen actividad immunoreguladora, método para la preparación y usos |
| FR2976579B1 (fr) * | 2011-06-14 | 2013-07-05 | Coatex Sas | Epaississants non ioniques associatifs contenant des alkyls cyclohexylols, formulations les contenant et leurs utilisations |
-
2011
- 2011-06-14 FR FR1155156A patent/FR2976580B1/fr not_active Expired - Fee Related
-
2012
- 2012-06-12 RU RU2014100913/05A patent/RU2602101C2/ru active
- 2012-06-12 WO PCT/FR2012/051315 patent/WO2012172249A1/fr not_active Ceased
- 2012-06-12 JP JP2014515259A patent/JP6452442B2/ja not_active Expired - Fee Related
- 2012-06-12 SG SG2013084728A patent/SG194987A1/en unknown
- 2012-06-12 CN CN201280022025.0A patent/CN103517930B/zh not_active Expired - Fee Related
- 2012-06-12 PL PL12731136T patent/PL2721084T3/pl unknown
- 2012-06-12 BR BR112013027437-9A patent/BR112013027437B1/pt not_active IP Right Cessation
- 2012-06-12 MX MX2013014290A patent/MX337544B/es active IP Right Grant
- 2012-06-12 AU AU2012270208A patent/AU2012270208B2/en not_active Ceased
- 2012-06-12 KR KR1020147000827A patent/KR101960118B1/ko not_active Expired - Fee Related
- 2012-06-12 EP EP12731136.3A patent/EP2721084B1/fr not_active Not-in-force
- 2012-06-12 ES ES12731136T patent/ES2705925T3/es active Active
- 2012-06-12 CA CA2834310A patent/CA2834310C/fr active Active
- 2012-06-13 US US13/495,080 patent/US8895630B2/en active Active
-
2013
- 2013-11-11 ZA ZA2013/08462A patent/ZA201308462B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2014100913A (ru) | 2015-07-20 |
| MX2013014290A (es) | 2014-03-21 |
| AU2012270208A1 (en) | 2013-11-21 |
| SG194987A1 (en) | 2013-12-30 |
| US8895630B2 (en) | 2014-11-25 |
| EP2721084A1 (fr) | 2014-04-23 |
| AU2012270208B2 (en) | 2015-08-20 |
| RU2602101C2 (ru) | 2016-11-10 |
| CA2834310A1 (fr) | 2012-12-20 |
| FR2976580A1 (fr) | 2012-12-21 |
| MX337544B (es) | 2016-03-10 |
| CN103517930A (zh) | 2014-01-15 |
| KR101960118B1 (ko) | 2019-03-19 |
| CN103517930B (zh) | 2015-09-02 |
| KR20140039286A (ko) | 2014-04-01 |
| JP2014523934A (ja) | 2014-09-18 |
| WO2012172249A1 (fr) | 2012-12-20 |
| BR112013027437B1 (pt) | 2020-11-17 |
| CA2834310C (fr) | 2019-10-29 |
| PL2721084T3 (pl) | 2019-02-28 |
| ZA201308462B (en) | 2015-03-25 |
| JP6452442B2 (ja) | 2019-01-16 |
| EP2721084B1 (fr) | 2018-10-17 |
| FR2976580B1 (fr) | 2013-05-31 |
| BR112013027437A2 (pt) | 2017-01-31 |
| US20120322896A1 (en) | 2012-12-20 |
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