ES265563A1 - Process for the manufacture of cyclohexanol - Google Patents
Process for the manufacture of cyclohexanolInfo
- Publication number
- ES265563A1 ES265563A1 ES0265563A ES265563A ES265563A1 ES 265563 A1 ES265563 A1 ES 265563A1 ES 0265563 A ES0265563 A ES 0265563A ES 265563 A ES265563 A ES 265563A ES 265563 A1 ES265563 A1 ES 265563A1
- Authority
- ES
- Spain
- Prior art keywords
- groups
- cyclohexanol
- manufacture
- cation exchange
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Abstract
A process for the manufacture of cyclohexanol by hydration in the liquid phase comprises hydrating cyclohexene in the presence of water and about 0.1 to 1.0% of emulsifier on a strongly acid cation exchange resin (i.e. containing sulphonic or phosphoric acid groups) at a temperature above 100 DEG C. and at elevated pressure in a closed system. Preferred emulsifiers are non-cation active e.g. ethoxylated ricinoleic acid, ethylphenol glycolether or alkylarylpolyether alcohol. Preferred cation exchange resins are those having a polystyrene matrix and sulpho groups as active groups. Examples are furnished. Apparatus for carrying out the process is described.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH269660A CH376904A (en) | 1960-03-10 | 1960-03-10 | Process for the production of cyclohexanol |
Publications (1)
Publication Number | Publication Date |
---|---|
ES265563A1 true ES265563A1 (en) | 1961-07-01 |
Family
ID=4239521
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0265563A Expired ES265563A1 (en) | 1960-03-10 | 1961-03-10 | Process for the manufacture of cyclohexanol |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE600833A (en) |
CH (1) | CH376904A (en) |
ES (1) | ES265563A1 (en) |
GB (1) | GB918406A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6059217B2 (en) * | 1980-12-25 | 1985-12-24 | 東亜燃料工業株式会社 | Method for producing secondary alcohol |
US4595786A (en) * | 1984-11-27 | 1986-06-17 | E. I. Du Pont De Nemours And Company | Hydration of cyclohexene in presence of perfluorosulfonic acid polymer |
DE3682658D1 (en) * | 1985-11-19 | 1992-01-09 | Sumitomo Chemical Co | METHOD OF PRODUCING CYCLOAL CANOLES. |
JP4685314B2 (en) * | 1999-12-28 | 2011-05-18 | 旭化成ケミカルズ株式会社 | Method for producing cyclohexanol |
CN113694556A (en) * | 2021-09-30 | 2021-11-26 | 杭州浥能科技有限公司 | Energy-saving device and method for separating cyclohexanol in hydration method |
-
1960
- 1960-03-10 CH CH269660A patent/CH376904A/en unknown
-
1961
- 1961-03-02 BE BE600833A patent/BE600833A/en unknown
- 1961-03-09 GB GB8688/61A patent/GB918406A/en not_active Expired
- 1961-03-10 ES ES0265563A patent/ES265563A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB918406A (en) | 1963-02-13 |
CH376904A (en) | 1964-04-30 |
BE600833A (en) | 1961-07-03 |
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