ES2625454T3 - Procedimiento para la obtención de complejos metálicos de 3,7-diaza-biciclo[3,3,1]nonano - Google Patents
Procedimiento para la obtención de complejos metálicos de 3,7-diaza-biciclo[3,3,1]nonano Download PDFInfo
- Publication number
- ES2625454T3 ES2625454T3 ES11701766.5T ES11701766T ES2625454T3 ES 2625454 T3 ES2625454 T3 ES 2625454T3 ES 11701766 T ES11701766 T ES 11701766T ES 2625454 T3 ES2625454 T3 ES 2625454T3
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- dimethyl
- diazabicyclo
- nonan
- pyridyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 46
- 239000002184 metal Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 46
- PTPQJKANBKHDPM-UHFFFAOYSA-N 3,7-diazabicyclo[3.3.1]nonane Chemical compound C1NCC2CNCC1C2 PTPQJKANBKHDPM-UHFFFAOYSA-N 0.000 title description 4
- 239000003446 ligand Substances 0.000 claims abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 150000002696 manganese Chemical class 0.000 claims abstract description 13
- 239000011572 manganese Substances 0.000 claims abstract description 9
- 239000011541 reaction mixture Substances 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000001450 anions Chemical class 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- 230000007935 neutral effect Effects 0.000 claims abstract description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract 9
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims abstract 4
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims abstract 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims abstract 2
- 150000003839 salts Chemical class 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 19
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 16
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 9
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 9
- 238000010668 complexation reaction Methods 0.000 claims description 8
- 150000002576 ketones Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- XQKKMNJIYUIGPJ-UHFFFAOYSA-N 3,7-dimethyl-2,4-dipyridin-2-yl-3,7-diazabicyclo[3.3.1]nonane-1,2-dicarboxylic acid Chemical compound CN1CC2CC(C1)(C(N(C2C3=CC=CC=N3)C)(C4=CC=CC=N4)C(=O)O)C(=O)O XQKKMNJIYUIGPJ-UHFFFAOYSA-N 0.000 claims description 2
- KDIBBUJMKNHFRI-UHFFFAOYSA-N 7-methyl-9-oxo-2,4-dipyridin-2-yl-3-(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,2-dicarboxylic acid Chemical compound CN1CC2C(N(C(C(C1)(C2=O)C(=O)O)(C3=CC=CC=N3)C(=O)O)CC4=CC=CC=N4)C5=CC=CC=N5 KDIBBUJMKNHFRI-UHFFFAOYSA-N 0.000 claims description 2
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 2
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 2
- 235000002867 manganese chloride Nutrition 0.000 claims description 2
- 239000011565 manganese chloride Substances 0.000 claims description 2
- 125000001814 trioxo-lambda(7)-chloranyloxy group Chemical group *OCl(=O)(=O)=O 0.000 claims 1
- 230000000630 rising effect Effects 0.000 abstract description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 16
- 238000001914 filtration Methods 0.000 description 11
- 239000012065 filter cake Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000004076 pyridyl group Chemical group 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- -1 preferably OH " Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- WOXFMYVTSLAQMO-UHFFFAOYSA-N 2-Pyridinemethanamine Chemical compound NCC1=CC=CC=N1 WOXFMYVTSLAQMO-UHFFFAOYSA-N 0.000 description 1
- QVGHOZYNEIGZGK-UHFFFAOYSA-N 3-methyl-9-oxo-2,4-dipyridin-2-yl-7-(pyridin-2-ylmethyl)-3,7-diazabicyclo[3.3.1]nonane-1,2-dicarboxylic acid Chemical compound CN1C(C2CN(CC(C2=O)(C1(C3=CC=CC=N3)C(=O)O)C(=O)O)CC4=CC=CC=N4)C5=CC=CC=N5 QVGHOZYNEIGZGK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910021135 KPF6 Inorganic materials 0.000 description 1
- 238000006683 Mannich reaction Methods 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004680 hydrogen peroxides Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
- 239000007966 viscous suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010007059A DE102010007059A1 (de) | 2010-02-06 | 2010-02-06 | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplexen |
| DE102010007059 | 2010-02-06 | ||
| PCT/EP2011/000404 WO2011095308A1 (de) | 2010-02-06 | 2011-01-28 | Verfahren zur herstellung von 3,7-diaza-bicyclo[3.3.1]nonan-metallkomplexen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2625454T3 true ES2625454T3 (es) | 2017-07-19 |
Family
ID=43640199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11701766.5T Active ES2625454T3 (es) | 2010-02-06 | 2011-01-28 | Procedimiento para la obtención de complejos metálicos de 3,7-diaza-biciclo[3,3,1]nonano |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20130072685A1 (ja) |
| EP (1) | EP2531505B1 (ja) |
| JP (1) | JP5648815B2 (ja) |
| DE (1) | DE102010007059A1 (ja) |
| ES (1) | ES2625454T3 (ja) |
| PL (1) | PL2531505T3 (ja) |
| WO (1) | WO2011095308A1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012015826A1 (de) | 2012-08-09 | 2014-02-13 | Clariant International Ltd. | Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen |
| DE102013004428A1 (de) | 2013-03-15 | 2014-09-18 | Clariant International Ltd. | Verfahren zum Waschen und Reinigen von Textilien |
| EP2857486A1 (en) | 2013-10-07 | 2015-04-08 | WeylChem Switzerland AG | Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes |
| EP2857485A1 (en) | 2013-10-07 | 2015-04-08 | WeylChem Switzerland AG | Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes |
| EP2857487A1 (en) | 2013-10-07 | 2015-04-08 | WeylChem Switzerland AG | Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes |
| CN103602268B (zh) * | 2013-10-10 | 2015-09-02 | 中钞油墨有限公司 | 环保型催干剂及其油墨组合物 |
| DE102013019269A1 (de) | 2013-11-15 | 2015-06-03 | Weylchem Switzerland Ag | Geschirrspülmittel sowie dessen Verwendung |
| EP3296353B1 (de) | 2016-09-19 | 2022-01-26 | Daw Se | Lösemittelhaltige beschichtungsmasse für lackbeschichtungen |
| EP3296372B1 (de) | 2016-09-19 | 2020-03-04 | Daw Se | Lösemittelhaltige beschichtungsmasse |
| CN110156087B (zh) * | 2019-05-11 | 2021-11-12 | 内蒙古师范大学 | 一种硫属化合物Fe(tren)GaSbS4及其合成方法 |
| EP3744799A1 (de) | 2019-05-29 | 2020-12-02 | STO SE & Co. KGaA | Lösemittelhaltige beschichtungsmasse für lasur- und lackbeschichtungen |
| EP3744800A1 (de) | 2019-05-29 | 2020-12-02 | STO SE & Co. KGaA | Lösemittelhaltige emulgierte alkydharz-beschichtungsmasse für lasur- und lackbeschichtungen |
| CA3226054A1 (en) | 2021-07-09 | 2023-01-12 | Umicore | Novel bispidone ligands and transition metal complexes thereof |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000060045A1 (en) | 1999-04-01 | 2000-10-12 | The Procter & Gamble Company | Transition metal bleaching agents |
| GB0004990D0 (en) * | 2000-03-01 | 2000-04-19 | Unilever Plc | Composition and method for bleaching a substrate |
| WO2001016271A1 (en) * | 1999-09-01 | 2001-03-08 | Unilever Plc | Composition and method for bleaching a substrate |
| GB0030673D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0030877D0 (en) * | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
| BR0311561A (pt) | 2002-06-06 | 2005-04-12 | Unilever Nv | Complexo de metal de transição de um ligante, e, ligante livre |
| GB0325430D0 (en) | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0413058D0 (en) * | 2004-06-11 | 2004-07-14 | Unilever Plc | Bleaching composition |
| DE102005027619A1 (de) | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| EP2038356B8 (en) | 2006-07-07 | 2011-06-22 | Unilever PLC | Liquid hardening |
| DE102008064009A1 (de) * | 2008-12-19 | 2010-06-24 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metall-Komplexen |
-
2010
- 2010-02-06 DE DE102010007059A patent/DE102010007059A1/de not_active Withdrawn
-
2011
- 2011-01-28 ES ES11701766.5T patent/ES2625454T3/es active Active
- 2011-01-28 WO PCT/EP2011/000404 patent/WO2011095308A1/de active Application Filing
- 2011-01-28 PL PL11701766T patent/PL2531505T3/pl unknown
- 2011-01-28 US US13/575,747 patent/US20130072685A1/en not_active Abandoned
- 2011-01-28 EP EP11701766.5A patent/EP2531505B1/de active Active
- 2011-01-28 JP JP2012551540A patent/JP5648815B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013518840A (ja) | 2013-05-23 |
| DE102010007059A1 (de) | 2011-08-11 |
| JP5648815B2 (ja) | 2015-01-07 |
| WO2011095308A1 (de) | 2011-08-11 |
| EP2531505B1 (de) | 2017-03-15 |
| US20130072685A1 (en) | 2013-03-21 |
| PL2531505T3 (pl) | 2017-09-29 |
| EP2531505A1 (de) | 2012-12-12 |
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