ES2607231B1 - Method of disinfection of water by over-oxygenation by microalgae in waterproof systems - Google Patents

Method of disinfection of water by over-oxygenation by microalgae in waterproof systems Download PDF

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Publication number
ES2607231B1
ES2607231B1 ES201500719A ES201500719A ES2607231B1 ES 2607231 B1 ES2607231 B1 ES 2607231B1 ES 201500719 A ES201500719 A ES 201500719A ES 201500719 A ES201500719 A ES 201500719A ES 2607231 B1 ES2607231 B1 ES 2607231B1
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water
microalgae
disinfection
oxygenation
over
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ES2607231A1 (en
Inventor
Laura POZO MORALES
Manuel FRANCO TOVAR
Dolores GARVI HIGUERAS
Julián LEBRATO MARTÍNEZ
Jean Claude BACCOU
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Universidad de Sevilla
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Universidad de Sevilla
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

El objeto de la presente invención es un método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos. Este método está orientado para la sobreoxigenación del agua a través de la generación y crecimiento de microalgas para la desinfección de aguas.#La invención se encuadra en el campo del tratamiento de aguas, siendo viable su uso tanto para aguas residuales como para aguas de consumo.The object of the present invention is a method of disinfection of water by over-oxygenation by microalgae in waterproof systems. This method is oriented to the oxygenate of water through the generation and growth of microalgae for water disinfection. # The invention falls within the field of water treatment, its use being viable for both wastewater and drinking water .

Description

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DESCRIPCIÓNDESCRIPTION

Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos.Method of disinfection of water by over-oxygenation by microalgae in waterproof systems.

Objeto de la invenciónObject of the invention

El objeto de la presente invención es un método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos. Este método está orientado para la sobreoxigenación del agua a través de la generación y crecimiento de microalgas para la desinfección de aguas.The object of the present invention is a method of disinfection of water by over-oxygenation by microalgae in waterproof systems. This method is oriented to the oxygenation of water through the generation and growth of microalgae for water disinfection.

La invención se encuadra en el campo del tratamiento de aguas, siendo viable su uso tanto para aguas residuales como para aguas de consumo. Se encuadra en el sector técnico de procesos de tratamientos de aguas, más concretamente en el relativo a los sistemas biológicos de eliminación de patógenos y materia orgánica.The invention falls within the field of water treatment, its use being viable for both wastewater and drinking water. It is part of the technical sector of water treatment processes, more specifically in that related to biological systems for the elimination of pathogens and organic matter.

Estado de la técnicaState of the art

El método que se propone parte de referencias bibliográficas sobre sistemas cerrados basados en la acción de microalgas (Baccou, 2000; Lavoie, 1985).The proposed method is based on bibliographic references on closed systems based on the action of microalgae (Baccou, 2000; Lavoie, 1985).

Se tiene conocimiento de la existencia en la actualidad de diferentes procedimientos destinados al tratamiento de aguas, los cuales se encuentran parcialmente reflejados en un número indeterminado de patentes relativas a sus procedimientos, máquinas y aparatos utilizados de forma general para la obtención del fin perseguido.There is knowledge of the existence at present of different procedures for water treatment, which are partially reflected in an indeterminate number of patents relating to their procedures, machines and equipment used in general for obtaining the intended purpose.

Sin embargo, después de realizar un estudio de la información, no se conoce la existencia de un procedimiento de tratamiento similar que permita la eliminación de patógenos y materia orgánica en aguas. Se ha realizado una revisión de los documentos citados a continuación y que podrían afectar a la novedad de dicha invención, y no se han detectado coincidencias que puedan afectarle.However, after conducting a study of the information, the existence of a similar treatment procedure that allows the elimination of pathogens and organic matter in water is unknown. A review of the documents cited below and that could affect the novelty of said invention has been carried out, and no matches that may affect it have been detected.

ReferenciasReferences

- CU 21089 A 19820328. PROCEDURE FOR THE CULTURE OF MICROALGAE IN SEWAGE FROM FORAGE YEAST- CU 21089 TO 19820328. PROCEDURE FOR THE CULTURE OF MICROALGAE IN SEWAGE FROM FORAGE YEAST

- JP 2002316179 A 20021029. SEWAGE TREATMENT SYSTEM AND SEWAGE TREATMENT STRUCTURE. PROBLEM TO BE SOL VED- JP 2002316179 TO 20021029. SEWAGE TREATMENT SYSTEM AND SEWAGE TREATMENT STRUCTURE. PROBLEM TO BE SOL VED

- JP 86351997 A 19880305. SYSTEM FOR MIXING AND TREATING NIGHT SOIL AND GARBAGE. PURPOSE- JP 86351997 A 19880305. SYSTEM FOR MIXING AND TREATING NIGHT SOIL AND GARBAGE. PURPOSE

- JP 2009056408 A 20090319. METHOD AND APPARATUS FOR FIXING CARBON DIOXIDE AND PRODUCING FRESH WATER SIMULTANEOUSLY. PROBLEM TO BE SOLVED- JP 2009056408 A 20090319. METHOD AND APPARATUS FOR FIXING CARBON DIOXIDE AND PRODUCING FRESH WATER SIMULTANEOUSLY. PROBLEM TO BE SOLVED

- DE 10024547 A 1 20011220. Prncess for biological cleaning of sewage or sludge and waste has heat provided by primary solar ca/lector with heat storage to maintain substrate heat on fluctuations from primary supply.- DE 10024547 A 1 20011220. Prncess for biological cleaning of sewage or sludge and waste has heat provided by primary solar ca / reader with heat storage to maintain substrate heat on fluctuations from primary supply.

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- WO 2011098642 A1 20110818. INTEGRATED ENERGYHARNESSING SYSTEM.- WO 2011098642 A1 20110818. INTEGRATED ENERGYHARNESSING SYSTEM.

- JP2007532291 A 20071115.- JP2007532291 TO 20071115.

- CU 21090 A 19820328. PROCEDURE FOR THE CONTROLLED DOSIFICATION OF CARBON DIOXIDE IN MICROALGAE CULTURE.- CU 21090 TO 19820328. PROCEDURE FOR THE CONTROLLED DOSIFICATION OF CARBON DIOXIDE IN MICROALGAE CULTURE.

- DE 3428716 A 1 19860213. Process for the self-sufficient utilisation of waste, in particular in residential units, and apparatus for carrying out the same.- DE 3428716 A 1 19860213. Process for the self-sufficient utilization of waste, in particular in residential units, and apparatus for carrying out the same.

- CN 102923900 A 20130213. Solar energy assisted disinfection method and apparatus for composite artificial wetland.- CN 102923900 A 20130213. Solar energy assisted disinfection method and apparatus for composite artificial wetland.

- CN 202284172 U 20120627. Solarauxiliary disinfection apparatus forintegrated constructed wetlands.- CN 202284172 U 20120627. Solarauxiliary disinfection apparatus forintegrated constructed wetlands.

Descripción de la invenciónDescription of the invention

Estudiando los procesos que han sido utilizados clásicamente en sistemas artificiales de tratamientos de aguas, se desarrolla un sistema estanco con objeto de intensificar la acción del contenido de oxígeno disuelto.Studying the processes that have been used classically in artificial water treatment systems, a watertight system is developed in order to intensify the action of dissolved oxygen content.

A partir de un agua residual, a la cual únicamente se le ha aplicado un pretratamiento previo, se pretende obtener un agua apta para su reutilización, sin riesgo alguno para la salud y partiendo de un agua de consumo que contenga patógenos, se pretende asegurar su desinfección.From a wastewater, to which only a previous pretreatment has been applied, it is intended to obtain a water suitable for reuse, without any risk to health and starting from a drinking water containing pathogens, it is intended to ensure its disinfection.

Para ello la presente invención se centra en la reducción de materia orgánica y desinfección de las aguas mediante la utilización de formas reactivas de oxígeno sobresaturado, producto de la actividad fotosintética de las microalgas.For this purpose, the present invention focuses on the reduction of organic matter and water disinfection through the use of reactive forms of supersaturated oxygen, product of the photosynthetic activity of microalgae.

El método que se propone utiliza un reactor estanco para el tratamiento de aguas basado en la autodepuración que se da de forma natural en los medios acuáticos, debido al desarrollo de microalgas y a la radiación solar.The proposed method uses a sealed reactor for water treatment based on self-purification that occurs naturally in aquatic environments, due to the development of microalgae and solar radiation.

La presente invención describe la creación de un método de bajo coste para llevar a cabo la reducción de la materia orgánica y desinfección. Para ello, se compone de un sistema estanco, impermeable y transparente o translúcido que permite la incidencia prolongada de la radiación solar en la mayor parte de la masa de agua. Este sistema debe estar dotado de cierre hidráulico a entrada y salida, y encontrarse cerrado, de tal forma que el agua se esté en contacto directo con las paredes éste.The present invention describes the creation of a low cost method for carrying out the reduction of organic matter and disinfection. For this, it is composed of a waterproof, transparent and transparent or translucent system that allows the prolonged incidence of solar radiation in most of the body of water. This system must be equipped with hydraulic closure at the entrance and exit, and be closed, so that the water is in direct contact with the walls.

El oxígeno disuelto resultado de la actividad fotosintética de microalgas es retenido por la cubierta del sistema produciéndose una sobreoxigenación en el agua.The dissolved oxygen resulting from the photosynthetic activity of microalgae is retained by the cover of the system producing an oxygenate in the water.

El reactor debe permitir una limpieza y manejos eficaces, y una distribución que favorezca la homogeneidad del contenido. Además cabe la posibilidad de toma de muestras para su análisis, así como la introducción de sondas de medida para la adquisición de datos en continuo del contenido del reactor.The reactor must allow efficient cleaning and handling, and a distribution that favors the homogeneity of the content. In addition, it is possible to take samples for analysis, as well as the introduction of measurement probes for continuous data acquisition of reactor contents.

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Descripción del contenido de las figurasDescription of the content of the figures

Figura 1 y Figura 2. Vistas del sistema (1), que incluye dos tajaderas (2 y 3), una tubería flexible (4) que incluye una válvula antirretorno (6) y está conectada a una bomba hidráulica (5) y otra tubería rígida en la lado opuesto del canal (7). El sistema (1) se encuentra cubierto por una lámina flexible (8).Figure 1 and Figure 2. System views (1), which includes two chopping boards (2 and 3), a flexible pipe (4) that includes a non-return valve (6) and is connected to a hydraulic pump (5) and another pipe rigid on the opposite side of the channel (7). The system (1) is covered by a flexible sheet (8).

Modo de realización de la invenciónEmbodiment of the invention

La presente invención se ilustra adicionalmente mediante el siguiente ejemplo, el cual no pretende ser limitativo de su alcance.The present invention is further illustrated by the following example, which is not intended to limit its scope.

El sistema (1), semejante a un canal con una longitud total de 1 m, está construido en metacrilato transparente de 5 mm de espesor. En los extremos de este canal encontramos dos tajaderas (2 y 3), realizadas también en metacrilato de 5 mm de espesor, con aberturas en su parte inferior que obligarán al flujo de agua a entrar por la parte baja del canal. Los espacios (9) que quedan entre los extremos del sistema (1) y las tajaderas (2 y 3) se destinan a la toma de muestras para su análisis.The system (1), similar to a channel with a total length of 1 m, is made of transparent methacrylate 5 mm thick. At the ends of this channel we find two chopping boards (2 and 3), also made of 5 mm thick methacrylate, with openings in its lower part that will force the flow of water to enter through the lower part of the channel. The spaces (9) that remain between the ends of the system (1) and the chopping boards (2 and 3) are used to take samples for analysis.

A este canal se le introduce el agua que queremos depurar/desinfectar a través de una tubería (4) flexible de PVC conectada a una bomba hidráulica (5), a un caudal fijo de 0,15 litros por hora. Dicha tubería tiene una luz de paso interior de 10 mm y consta de una válvula antirretorno (6).To this channel the water that we want to purify / disinfect is introduced through a flexible PVC pipe (4) connected to a hydraulic pump (5), at a fixed flow rate of 0.15 liters per hour. Said pipe has an internal passage light of 10 mm and consists of a non-return valve (6).

El sistema (1) se encuentra cubierto por una lámina flexible (8) de PVC transparente de 0,5 mm de espesor. Dicha lámina se fija a las paredes del sistema (1) mediante la utilización de pinzas metálicas.The system (1) is covered by a flexible sheet (8) of transparent PVC 0.5 mm thick. Said sheet is fixed to the walls of the system (1) through the use of metal clamps.

La salida del agua ya depurada y desinfectada se produce por el extremo opuesto del canal mediante otra tubería (7) rígida de PVC de 10 mm de luz de paso interior, que llevara dicha agua directamente al cultivo que deseamos regar. Esta tubería de salida será regulable en altura para poder aumentar o disminuir el nivel de agua dentro del reactor.The exit of the water already purified and disinfected is produced by the opposite end of the channel by another rigid PVC pipe (7) of 10 mm of interior passing light, which will take said water directly to the crop that we want to water. This outlet pipe will be height adjustable in order to increase or decrease the water level inside the reactor.

Claims (8)

55 1010 15fifteen 20twenty 2525 3030 3535 4040 ES 2 607 231 A1ES 2 607 231 A1 REIVINDICACIONES 1. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, caracterizado por utilizar un reactor estanco compuesto de un sistema (1) que incluye dos tajaderas (2 y 3), una tubería (4) flexible de entrada que consta de una válvula antirretorno (6) que está conectada a una bomba hidráulica (5) y otra tubería rígida de salida en la lado opuesto (7).1. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, characterized by using a sealed reactor composed of a system (1) that includes two chopping boards (2 and 3), a flexible inlet pipe (4) consisting of a non-return valve (6) that is connected to a hydraulic pump (5) and another rigid outlet pipe on the opposite side (7). 2. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicación 1, caracterizado porque el sistema (1) construido preferiblemente en metacrilato transparente, está cerrado y cubierto por una lámina flexible (8) de material transparente o translúcido que permite la penetración de radiación lumínica como fuente de energía y lo hace impermeable.2. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to claim 1, characterized in that the system (1) preferably constructed in transparent methacrylate, is closed and covered by a flexible sheet (8) of transparent or translucent material that allows The penetration of light radiation as a source of energy and makes it waterproof. 3. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque la lámina flexible (8) se fija a las paredes del sistema (1) mediante la utilización de pinzas metálicas.3. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to previous claims, characterized in that the flexible sheet (8) is fixed to the walls of the system (1) through the use of metal clamps. 4. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque el sistema (1) está dotado de un cierre hidráulico de entrada y salida.4. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to previous claims, characterized in that the system (1) is provided with a hydraulic inlet and outlet seal. 5. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque en los extremos del sistema encontramos dos tajaderas (2 y 3), realizadas también en metacrilato, con aberturas en su parte inferior que obligan al flujo de agua a entrar por la parte baja del canal.5. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to previous claims, characterized in that at the ends of the system we find two chopping boards (2 and 3), also made of methacrylate, with openings in its lower part that force the flow of water to enter through the lower part of the canal. 6. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque presenta una tubería (4) flexible de entrada y otra tubería rígida de salida en la lado opuesto (7) fabricadas en PVC.6. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to previous claims, characterized in that it has a flexible inlet pipe (4) and another rigid outlet pipe on the opposite side (7) made of PVC. 7. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque el reactor estanco se basa en la autodepuración que se da de forma natural en los medios acuáticos, debido al desarrollo de microalgas y la radiación solar.7. Method of disinfection of water by over-oxygenation by microalgae in watertight systems, according to previous claims, characterized in that the watertight reactor is based on the self-purification that occurs naturally in aquatic environments, due to the development of microalgae and solar radiation. 8. Método de desinfección de aguas por sobreoxigenación mediante microalgas en sistemas estancos, según reivindicaciones anteriores, caracterizado porque el reactor permite toma de muestras para su análisis, así como la introducción de sondas de medida para la adquisición de datos en continuo del contenido del mismo.8. Method of disinfection of water by over-oxygenation by microalgae in sealed systems, according to previous claims, characterized in that the reactor allows sampling for analysis, as well as the introduction of measurement probes for continuous data acquisition of the contents thereof .
ES201500719A 2015-09-29 2015-09-29 Method of disinfection of water by over-oxygenation by microalgae in waterproof systems Active ES2607231B1 (en)

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GB2492826B (en) * 2011-07-14 2013-08-07 Lo Ltd System for decomposition of organic compounds and method of operation thereof
US20130230904A1 (en) * 2011-08-31 2013-09-05 Exxonmobil Research And Engineering Company Lensed and striped flat panel photobioreactors
US20130102056A1 (en) * 2011-10-03 2013-04-25 Exxonmobil Research And Engineering Company Liquid curtain photobioreactors

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