ES2552560R1 - Uso de un catalizador de metaloceno para producir una Polialfa-olefina - Google Patents
Uso de un catalizador de metaloceno para producir una Polialfa-olefina Download PDFInfo
- Publication number
- ES2552560R1 ES2552560R1 ES201530755A ES201530755A ES2552560R1 ES 2552560 R1 ES2552560 R1 ES 2552560R1 ES 201530755 A ES201530755 A ES 201530755A ES 201530755 A ES201530755 A ES 201530755A ES 2552560 R1 ES2552560 R1 ES 2552560R1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- radicals
- substituted
- polyalpha
- metallocene catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
- C07C2/34—Metal-hydrocarbon complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/85—Chromium, molybdenum or tungsten
- C07C2523/88—Molybdenum
- C07C2523/882—Molybdenum and cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
Abstract
Uso de un catalizador de metaloceno para producir una polialfa-olefina.#La invención se refiere al uso, en una reacción de oligomerización llevada a cabo en presencia de hidrógeno y a una temperatura elevada, de un catalizador racémico de metaloceno puenteado, un compuesto de metaloceno (A) que está representado por medio de la fórmula R(Cp{sub,1})(Cp{sub,2}) M X{sub,1} X{sub,2} en la que R es un grupo puenteante alquileno C{sub,1}-C{sub,20}; Cp{sub,1} y Cp{sub,2} son anillos tetrahidroindenilo sustituidos o no sustituidos iguales o diferentes, en los que sí están sustituidos, las sustituciones pueden ser independientes y/o estar ligadas para formar estructuras multicíclicas; M es un metal de transición seleccionado entre el grupo que consiste en titanio, circonio y hafnio; X{sub,1} y X{sub,2} son de forma independiente hidrógeno, halógeno, radicales hidruro, radicales hidrocarbilo, radicales hidrocarbilo sustituidos, radicales halocarbilo, radicales halocarbilo sustituidos, radicales sililcarbilo, radicales sililcarbilo sustituidos, radicales germilcarbilo, radicales germilcarbilo sustituidos; o ambos X{sub,1} y X{sub,2} se unen y enlazan al átomo metálico para formar un anillo de metalaciclo que contiene de 3 a 20 átomos de carbono; para la producción de polialfa-olefinas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14170548 | 2014-05-30 | ||
EP14170548 | 2014-05-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2552560A2 ES2552560A2 (es) | 2015-11-30 |
ES2552560R1 true ES2552560R1 (es) | 2015-12-09 |
Family
ID=50943066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES201530755A Pending ES2552560R1 (es) | 2014-05-30 | 2015-05-29 | Uso de un catalizador de metaloceno para producir una Polialfa-olefina |
Country Status (9)
Country | Link |
---|---|
US (1) | US9688792B2 (es) |
EP (1) | EP3140266B1 (es) |
CA (1) | CA2949322A1 (es) |
DE (1) | DE102015006903A1 (es) |
ES (1) | ES2552560R1 (es) |
FR (1) | FR3021657A1 (es) |
GB (1) | GB2531842A (es) |
NL (1) | NL2014894B1 (es) |
WO (1) | WO2015181280A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3021664B1 (fr) * | 2014-05-30 | 2020-12-04 | Total Marketing Services | Polyolefines lubrifiantes de basse viscosite |
CN105885929B (zh) * | 2016-06-03 | 2017-08-29 | 中国科学院上海高等研究院 | 一种低粘度茂金属pao基础油的制备方法 |
US10968290B2 (en) | 2017-03-28 | 2021-04-06 | Exxonmobil Chemical Patents Inc. | Metallocene-catalyzed polyalpha-olefins |
EP3752540A4 (en) | 2018-02-12 | 2021-12-01 | ExxonMobil Chemical Patents Inc. | CATALYST SYSTEMS AND PROCESSES FOR POLY ALPHA-OLEFIN WITH HIGH VINYLIDENE CONTENT |
US11078308B2 (en) | 2018-02-12 | 2021-08-03 | Exxonmobil Chemical Patents Inc. | Processes to produce poly alpha-olefin trimers |
US11021553B2 (en) | 2018-02-12 | 2021-06-01 | Exxonmobil Chemical Patents Inc. | Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers |
EP3853273A4 (en) | 2018-09-17 | 2022-08-31 | ExxonMobil Chemical Patents Inc. | METALLOCENE-SELECTIVE DIMER CATALYSTS AND METHODS FOR PRODUCING POLY ALPHA-OLEFIN DIMERS |
EP3887414A4 (en) * | 2018-11-29 | 2021-12-29 | ExxonMobil Chemical Patents Inc. | Poly(alpha-olefin)s and methods thereof |
WO2021086926A1 (en) | 2019-10-28 | 2021-05-06 | Exxonmobil Chemical Patents Inc. | Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith |
CN115943197A (zh) | 2020-04-29 | 2023-04-07 | 埃克森美孚化学专利公司 | 聚α-烯烃组合物和生产聚α-烯烃的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1164146A2 (en) * | 2000-05-30 | 2001-12-19 | Idemitsu Petrochemical Co., Ltd. | Process for producing a polymer of an alpha-olefin and lubricant |
WO2002014384A2 (en) * | 2000-08-11 | 2002-02-21 | Uniroyal Chemical Company, Inc. | Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor and lubricants containing the same |
WO2003104292A1 (en) * | 2002-06-04 | 2003-12-18 | Crompton Corporation | PROCESS FOR THE OLIGOMERIZATION OF α-OLEFINS HAVING LOW UNSATURATION |
US7129197B2 (en) * | 2001-08-31 | 2006-10-31 | Shell Oil Company | Synthesis of poly-alpha olefin and use thereof |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
WO2007011462A1 (en) * | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
WO2007011459A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Polyalpha-olefin compositions and processes to produce the same |
US9469704B2 (en) * | 2008-01-31 | 2016-10-18 | Exxonmobil Chemical Patents Inc. | Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins |
WO2012027139A2 (en) * | 2010-08-25 | 2012-03-01 | Exxonmobil Chemical Patents Inc. | Functionalizable synthetic hydrocarbon fluids and integrated method of for production thereof |
WO2012134688A1 (en) * | 2011-03-30 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins by oligomerization and isomerization |
-
2015
- 2015-05-28 CA CA2949322A patent/CA2949322A1/en not_active Abandoned
- 2015-05-28 EP EP15725026.7A patent/EP3140266B1/en not_active Not-in-force
- 2015-05-28 WO PCT/EP2015/061815 patent/WO2015181280A1/en active Application Filing
- 2015-05-29 US US14/725,540 patent/US9688792B2/en not_active Expired - Fee Related
- 2015-05-29 ES ES201530755A patent/ES2552560R1/es active Pending
- 2015-05-29 FR FR1501116A patent/FR3021657A1/fr active Pending
- 2015-05-29 DE DE102015006903.9A patent/DE102015006903A1/de not_active Withdrawn
- 2015-05-29 GB GB1509242.2A patent/GB2531842A/en not_active Withdrawn
- 2015-06-01 NL NL2014894A patent/NL2014894B1/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1164146A2 (en) * | 2000-05-30 | 2001-12-19 | Idemitsu Petrochemical Co., Ltd. | Process for producing a polymer of an alpha-olefin and lubricant |
WO2002014384A2 (en) * | 2000-08-11 | 2002-02-21 | Uniroyal Chemical Company, Inc. | Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor and lubricants containing the same |
US7129197B2 (en) * | 2001-08-31 | 2006-10-31 | Shell Oil Company | Synthesis of poly-alpha olefin and use thereof |
WO2003104292A1 (en) * | 2002-06-04 | 2003-12-18 | Crompton Corporation | PROCESS FOR THE OLIGOMERIZATION OF α-OLEFINS HAVING LOW UNSATURATION |
Also Published As
Publication number | Publication date |
---|---|
WO2015181280A1 (en) | 2015-12-03 |
US20150344598A1 (en) | 2015-12-03 |
US9688792B2 (en) | 2017-06-27 |
NL2014894A (en) | 2016-03-15 |
EP3140266A1 (en) | 2017-03-15 |
GB2531842A (en) | 2016-05-04 |
ES2552560A2 (es) | 2015-11-30 |
NL2014894B1 (en) | 2016-07-25 |
CA2949322A1 (en) | 2015-12-03 |
FR3021657A1 (es) | 2015-12-04 |
EP3140266B1 (en) | 2018-05-16 |
DE102015006903A1 (de) | 2015-12-03 |
GB201509242D0 (en) | 2015-07-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2552560R1 (es) | Uso de un catalizador de metaloceno para producir una Polialfa-olefina | |
EA033278B1 (ru) | СПОСОБ ПОЛУЧЕНИЯ ТВЕРДОГО КОМПОНЕНТА КАТАЛИЗАТОРА НА ПОДЛОЖКЕ MgCl | |
MD3806955T2 (ro) | Agoniști ai receptorului GLP-1 și utilizările acestora | |
AR084730A1 (es) | Ligandos heterociclicos nitrogenados de receptores sigma utiles para el tratamiento de dolor por cancer de huesos | |
AR087418A1 (es) | Inhibidores de replica de virus de influenza | |
UY36101A (es) | Herbicidas de piridazinona | |
CO2018007440A2 (es) | Análogos del egf(a) con sustituyentes de ácidos grasos | |
UY35225A (es) | Lactamas Fusionadas de Arilo y Heteroarilo | |
AR091185A1 (es) | Derivados de 1,2,4-triazol | |
AR060506A1 (es) | Compuestos organicos | |
AR058124A1 (es) | Derivados de ftalazinona como inhibidores de parp-1 | |
ES2626801T3 (es) | Compuestos de triazolopiridina como inhibidores de pde10a | |
ECSP10010434A (es) | Inhibidores de hsp90 | |
JP2015042636A5 (ja) | 有機化合物 | |
AR090005A1 (es) | Imidazo[1,2-a]pirimidinas y piridinas sustituidas | |
AR088829A1 (es) | DERIVADOS DE CICLOHEXILAMINA QUE TIENEN ACTIVIDAD COMO AGONISTAS ADRENERGICOS b2 Y COMO ANTAGONISTAS MUSCARINICOS M3 | |
EA201692461A1 (ru) | Прокатализатор для полимеризации олефинов | |
PE20141042A1 (es) | Nuevos derivados biciclicos de dihidroquinolina-2-ona | |
MY177142A (en) | Catalyst component for propene polymerization, preparation method thereof, and catalyst containing the same | |
WO2010146176A3 (en) | Process for hydrogenation of halogenoalkenes without dehalogenation | |
AR082441A1 (es) | Uso de ligandos sigma en la hiperalgesia inducida por opioides | |
AR080802A1 (es) | Compuestos de complejos de fe (iii) para el tratamiento y la profilaxis de los sintomas de deficiencia de hierro y anemias por deficiencia de hierro | |
BR112018071511A2 (pt) | polímeros à base de etileno e processos para fazer os mesmos | |
MY157193A (en) | Process for production of olefin | |
AR102731A1 (es) | Compuestos espiroisoquinolin-1,4-piperidínicos con actividad multimodal contra el dolor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Grant refused |
Effective date: 20161222 |