ES2530665T3 - Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc - Google Patents
Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc Download PDFInfo
- Publication number
- ES2530665T3 ES2530665T3 ES12708548T ES12708548T ES2530665T3 ES 2530665 T3 ES2530665 T3 ES 2530665T3 ES 12708548 T ES12708548 T ES 12708548T ES 12708548 T ES12708548 T ES 12708548T ES 2530665 T3 ES2530665 T3 ES 2530665T3
- Authority
- ES
- Spain
- Prior art keywords
- radical
- zinc
- aromatic
- aryl
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011248 coating agent Substances 0.000 title abstract 2
- MMSYPTUQQBBEJP-UHFFFAOYSA-L zinc;1h-imidazole-2-carboxylate Chemical compound [Zn+2].[O-]C(=O)C1=NC=CN1.[O-]C(=O)C1=NC=CN1 MMSYPTUQQBBEJP-UHFFFAOYSA-L 0.000 title abstract 2
- -1 cyclic hydrocarbon radical Chemical class 0.000 abstract 8
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 abstract 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002460 imidazoles Chemical class 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- QAIYREPTUDZYMV-UHFFFAOYSA-L zinc;2-ethylhexanoate;1-methylimidazole Chemical compound [Zn+2].CN1C=CN=C1.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAIYREPTUDZYMV-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/53—Base coat plus clear coat type
- B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
- C08G18/165—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22 covered by C08G18/18 and C08G18/24
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
- C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
- C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161453986P | 2011-03-18 | 2011-03-18 | |
| EP11158846 | 2011-03-18 | ||
| PCT/EP2012/054546 WO2012126796A1 (de) | 2011-03-18 | 2012-03-15 | Zink-imidazol-carboxylat-komplex katalysierte beschichtungsmittelzusammensetzung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2530665T3 true ES2530665T3 (es) | 2015-03-04 |
Family
ID=45819217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12708548T Active ES2530665T3 (es) | 2011-03-18 | 2012-03-15 | Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9206330B2 (OSRAM) |
| EP (1) | EP2686362B1 (OSRAM) |
| JP (1) | JP6071993B2 (OSRAM) |
| AU (1) | AU2012230533B2 (OSRAM) |
| BR (1) | BR112013023578A2 (OSRAM) |
| ES (1) | ES2530665T3 (OSRAM) |
| MX (1) | MX2013010492A (OSRAM) |
| WO (1) | WO2012126796A1 (OSRAM) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2686361B1 (de) * | 2011-03-14 | 2014-11-26 | BASF Coatings GmbH | Polyurethan-beschichtungsmittelzusammensetzung, mehrstufige beschichtungsverfahren unter verwendung dieser beschichtungsmittelzusammensetzungen sowie die verwendung der beschichtungsmittelzusammensetzung als klarlack und pigmentierter lack bzw. anwendung des beschichtungsverfahrens für die automobilreparaturlackierung und/oder für die beschichtung von kunststoffsubstraten und/oder nutzfahrzeugen |
| AU2012228648B2 (en) * | 2011-03-14 | 2015-01-22 | Basf Coatings Gmbh | Polyurethane coating material composition, multistage coating methods using these coating material compositions, and also the use of the coating material composition as clearcoat material and pigmented coating material, and application of the coating method for automotive refinish and/or for the coating of plastics substrates and/or of utility vehicles |
| MX2013006983A (es) * | 2011-03-14 | 2013-07-30 | Basf Coatings Gmbh | Composicion de material de recubrimiento de poliuretano, metodos de recubrimiento de multiples etapas usando estas composiciones de material de recubrimiento, y tambien el suso de la composicion de material de recubrimiento como material de capa transparente y material de recubrimiento pigmentado, y aplicacion del metodo de recubrimiento para acabado automotriz y/o para el recubrimiento de sustratos de palstico y/o vehiculos de utilidad. |
| AU2013213637B2 (en) * | 2012-01-25 | 2016-05-05 | Basf Coatings Gmbh | Zinc (1-methylimidazole)bis(2-ethylhexanoate) complex catalyzed coating material composition |
| CN104487472B (zh) | 2012-07-25 | 2017-07-14 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物及其用途、多阶段涂覆方法 |
| CN104487473B (zh) | 2012-07-25 | 2017-05-17 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物、多阶段涂覆方法 |
| EP2851379A1 (de) | 2013-09-23 | 2015-03-25 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestelllte, bei niedrigen Temperaturen härtbare Beschichtungen und sowie deren Verwendung |
| EP2851403A1 (de) | 2013-09-23 | 2015-03-25 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestellte, bei niedrigen temperaturen härtbare beschichtungen und sowie deren verwendung |
| JPWO2015087920A1 (ja) * | 2013-12-12 | 2017-03-16 | 関西ペイント株式会社 | 塗料組成物 |
| EP2910612A1 (de) | 2014-02-20 | 2015-08-26 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestellte Beschichtungen und sowie deren Verwendung |
| WO2017204345A1 (ja) | 2016-05-26 | 2017-11-30 | 積水化学工業株式会社 | ポリウレタン組成物 |
| KR20210104869A (ko) | 2018-12-24 | 2021-08-25 | 바스프 코팅스 게엠베하 | 수계 코팅의 저온 경화 |
| JP7333826B2 (ja) * | 2019-04-18 | 2023-08-25 | ダウ グローバル テクノロジーズ エルエルシー | 接着剤組成物 |
| EP4015547A1 (de) | 2020-12-15 | 2022-06-22 | Covestro Deutschland AG | Nichtionisch hydrophilierte polyisocyanate, katalyse mit zink-komplexen |
| CN118829697A (zh) * | 2022-02-18 | 2024-10-22 | 关西涂料株式会社 | 涂料组合物和涂膜形成方法 |
| WO2025029574A2 (en) * | 2023-08-02 | 2025-02-06 | The Board Of Regents Of The University Of Oklahoma | Zinc imidazole salicylaldoxime-based adsorptive membranes for removal of metal ions from aqueous solutions |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2434185A1 (de) | 1974-07-16 | 1976-02-05 | Bayer Ag | Verfahren zur herstellung von amidin-metall-komplexen |
| DE2835451C2 (de) | 1978-08-12 | 1985-10-24 | Saarbergwerke AG, 6600 Saarbrücken | Verfahren zum Verfestigen von Kohle und/oder Gestein im Bergbau |
| EP0249201A3 (en) | 1986-06-10 | 1989-07-19 | Union Carbide Corporation | High solids sag resistant cycloaliphatic epoxy coatings containing low molecular weight high tg organic polymeric sag resisting additives |
| NO170944C (no) | 1987-01-24 | 1992-12-30 | Akzo Nv | Fortykkede, vandige preparater, samt anvendelse av slike |
| US5084541A (en) | 1988-12-19 | 1992-01-28 | American Cyanamid Company | Triazine crosslinking agents and curable compositions |
| US4939213A (en) | 1988-12-19 | 1990-07-03 | American Cyanamid Company | Triazine crosslinking agents and curable compositions containing the same |
| JPH032288A (ja) * | 1989-05-30 | 1991-01-08 | Hitachi Chem Co Ltd | ポリウレタン塗料の硬化速度の制御方法 |
| DE4310413A1 (de) | 1993-03-31 | 1994-10-06 | Basf Lacke & Farben | Nichtwäßriger Lack und Verfahren zur Herstellung einer zweischichtigen Decklackierung |
| DE4310414A1 (de) | 1993-03-31 | 1994-10-06 | Basf Lacke & Farben | Verfahren zur Herstellung einer zweischichtigen Decklackierung auf einer Substratoberfläche |
| TW328955B (en) | 1993-05-14 | 1998-04-01 | Cytec Tech Corp | Process for preparing bis- or tris-carbamate functional 1,3,5-triazines, substantially halogen contamination free crosslinker compositions and new bis-or tris-carbamate functional 1,3,5-triazines |
| WO1997012945A1 (en) | 1995-10-06 | 1997-04-10 | Cabot Corporation | Aqueous thixotropes for waterborne systems |
| JPH09125000A (ja) * | 1995-11-01 | 1997-05-13 | Asahi Chem Ind Co Ltd | 上塗り塗料及び塗装方法 |
| AU6801298A (en) | 1997-06-05 | 1998-12-10 | Rohm And Haas Company | Coating compositions having extended pot life and shortened cure time and combination of chemicals used therein |
| US6046270A (en) | 1998-10-14 | 2000-04-04 | Bayer Corporation | Silane-modified polyurethane resins, a process for their preparation and their use as moisture-curable resins |
| DE60033403T2 (de) | 1999-07-30 | 2007-10-31 | Ppg Industries Ohio, Inc. | Beschichtungszusammensetzungen mit verbesserter kratzfestigkeit, beschichtete oberfläche und verfahren zu deren herstellung |
| JP2002212499A (ja) * | 2001-01-22 | 2002-07-31 | Nippon Paint Co Ltd | 熱硬化性艶消し粉体塗料組成物 |
| DE10132938A1 (de) | 2001-07-06 | 2003-01-16 | Degussa | Nichtwässriges, wärmehärtendes Zweikomponenten-Beschichtungsmittel |
| DE10244142A1 (de) | 2002-09-23 | 2004-04-01 | Henkel Kgaa | Stabile Polyurethansysteme |
| DE602004004561T2 (de) | 2003-03-18 | 2007-11-15 | Tosoh Corp. | Katalysatorzusammensetzung für die Herstellung von Polyurethanharz und Verfahren zu ihrer Herstellung |
| US6992149B2 (en) | 2004-02-12 | 2006-01-31 | Basf Corporation | Use of carbamate-modified aminoplast resins to improve the appearance and performance of powder coatings |
| US20060036007A1 (en) | 2004-08-12 | 2006-02-16 | King Industries, Inc. | Organometallic compositions and coating compositions |
| US7485729B2 (en) | 2004-08-12 | 2009-02-03 | King Industries, Inc. | Organometallic compositions and coating compositions |
| CA2708101A1 (en) * | 2007-12-20 | 2009-07-09 | E. I. Dupont De Nemours And Company | Process for producing a multilayer coating |
| DE102008026341A1 (de) | 2008-05-07 | 2009-11-12 | Bayer Materialscience Ag | Katalysatoren zur Synthese von Polyurethanen |
-
2012
- 2012-03-15 WO PCT/EP2012/054546 patent/WO2012126796A1/de not_active Ceased
- 2012-03-15 EP EP12708548.8A patent/EP2686362B1/de not_active Not-in-force
- 2012-03-15 AU AU2012230533A patent/AU2012230533B2/en not_active Ceased
- 2012-03-15 JP JP2014500329A patent/JP6071993B2/ja not_active Expired - Fee Related
- 2012-03-15 MX MX2013010492A patent/MX2013010492A/es not_active Application Discontinuation
- 2012-03-15 US US14/006,024 patent/US9206330B2/en not_active Expired - Fee Related
- 2012-03-15 BR BR112013023578A patent/BR112013023578A2/pt not_active IP Right Cessation
- 2012-03-15 ES ES12708548T patent/ES2530665T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP6071993B2 (ja) | 2017-02-01 |
| MX2013010492A (es) | 2013-10-17 |
| AU2012230533A1 (en) | 2013-09-19 |
| US9206330B2 (en) | 2015-12-08 |
| JP2014510174A (ja) | 2014-04-24 |
| BR112013023578A2 (pt) | 2016-12-06 |
| WO2012126796A1 (de) | 2012-09-27 |
| AU2012230533B2 (en) | 2014-08-28 |
| EP2686362B1 (de) | 2015-01-14 |
| EP2686362A1 (de) | 2014-01-22 |
| US20140162074A1 (en) | 2014-06-12 |
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