ES2497341R1 - Catalizador soportado sobre alúmina para su uso en la polimerización de olefinas y método para su preparación - Google Patents

Catalizador soportado sobre alúmina para su uso en la polimerización de olefinas y método para su preparación Download PDF

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Publication number
ES2497341R1
ES2497341R1 ES201490061A ES201490061A ES2497341R1 ES 2497341 R1 ES2497341 R1 ES 2497341R1 ES 201490061 A ES201490061 A ES 201490061A ES 201490061 A ES201490061 A ES 201490061A ES 2497341 R1 ES2497341 R1 ES 2497341R1
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ES
Spain
Prior art keywords
preparation
alumina
polymerization
olefins
catalyst supported
Prior art date
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Granted
Application number
ES201490061A
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English (en)
Other versions
ES2497341A2 (es
ES2497341B1 (es
Inventor
Luciana BORTOLIN RAMIS
Fernando Reis Da Cunha
Rafael SILVA DIAS
Natalia Dantas Do Vale Batista
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Petroleo Brasileiro SA Petrobras
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Petroleo Brasileiro SA Petrobras
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Publication of ES2497341A2 publication Critical patent/ES2497341A2/es
Publication of ES2497341R1 publication Critical patent/ES2497341R1/es
Application granted granted Critical
Publication of ES2497341B1 publication Critical patent/ES2497341B1/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Catalizador soportado sobre alúmina para su uso en la polimerización de olefinas y método para su preparación.#La presente invención se refiere a un catalizador soportado para la polimerización de olefinas. Más específicamente, la presente invención proporciona un catalizador que comprende un soporte de alúmina esférica modificado mediante la adición de un compuesto de magnesio que contiene un alcóxido de magnesio y el producto de la reacción del mismo con un haluro de titanio. La presente invención también se refiere al método para preparar dicho catalizador soportado.
ES201490061A 2011-12-22 2011-12-22 Catalizador soportado sobre alúmina para su uso en la polimerización de olefinas y método para su preparación Active ES2497341B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/BR2011/000487 WO2013091033A1 (pt) 2011-12-22 2011-12-22 Catalisador suportado em alumina para uso em polimerização de olefinas e método de preparo do mesmo

Publications (3)

Publication Number Publication Date
ES2497341A2 ES2497341A2 (es) 2014-09-22
ES2497341R1 true ES2497341R1 (es) 2014-12-12
ES2497341B1 ES2497341B1 (es) 2015-09-23

Family

ID=48667533

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201490061A Active ES2497341B1 (es) 2011-12-22 2011-12-22 Catalizador soportado sobre alúmina para su uso en la polimerización de olefinas y método para su preparación

Country Status (7)

Country Link
US (1) US20140038809A1 (es)
EP (1) EP2796478A4 (es)
JP (1) JP5873930B2 (es)
BR (1) BR112014011174A2 (es)
CA (1) CA2855529A1 (es)
ES (1) ES2497341B1 (es)
WO (1) WO2013091033A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10634602B2 (en) 2015-06-12 2020-04-28 Cytochip Inc. Fluidic cartridge for cytometry and additional analysis
CN108025904B (zh) 2015-06-12 2021-10-15 芯易诊有限公司 用于多分析物分析的流体单元和流体卡式盒
CN108027310B (zh) 2015-07-14 2020-12-22 芯易诊有限公司 流体盒中的体积感测
WO2019083844A1 (en) 2017-10-23 2019-05-02 Cytochip Inc. DEVICES AND METHOD FOR MEASURING TARGET ANALYTES AND PARTICLES
JP7162035B2 (ja) * 2020-06-29 2022-10-27 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒、オレフィン類重合用触媒の製造方法及びオレフィン類重合体の製造方法
CN115490793B (zh) * 2021-06-18 2024-06-04 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分、制备方法及应用
CN116023536A (zh) * 2021-10-26 2023-04-28 中国石油化工股份有限公司 一种烯烃聚合用烷氧基镁载体、制备方法、催化剂及应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056668A (en) * 1966-10-21 1977-11-01 Solvay & Cie Process for the polymerization and copolymerization of olefins with a solid support catalyst
EP0064637A1 (de) * 1981-05-02 1982-11-17 BASF Aktiengesellschaft Verfahren zur Herstellung von Homo- und Copolymerisaten von Monoolefinen durch Polymerisation des bzw. der Monomeren mittels eines Ziegler-Katalysatorsystems auf der Basis einer Vanadium enthaltenden Katalysatorkomponente
EP0292134A2 (en) * 1987-05-04 1988-11-23 Shell Oil Company Preparation of olefin polymerization catalyst component
US5015612A (en) * 1988-09-14 1991-05-14 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst subjected to preliminary polymerization treatment
EP0626393A1 (en) * 1993-04-05 1994-11-30 Petroleo Brasileiro S.A. - Petrobras Ziegler-type spherical catalyst for olefin polymerization, its preparation and its use

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2996460A (en) * 1957-02-20 1961-08-15 Nalco Chemical Co Compositions containing alumina and method for the preparation thereof
US2998520A (en) * 1958-07-25 1961-08-29 Gen Dynamics Corp Fluid flow regulator
GB1076450A (en) * 1963-12-06 1967-07-19 Grace W R & Co Improvements relating to the production of alumina gels
CA975346A (en) * 1971-01-28 1975-09-30 Carl F. Cross Spheroidal catalyst and catalyst support
CA1142908A (en) * 1979-03-07 1983-03-15 Arthur W. Langer, Jr. Trialkyl aluminum cocatalyst
EP0032308A3 (en) * 1980-01-10 1981-08-05 Imperial Chemical Industries Plc Ethylene polymerisation process
JPS57121003A (en) * 1981-01-22 1982-07-28 Mitsubishi Petrochem Co Ltd Preparation of olefin polymer
JPS58122904A (ja) * 1982-01-19 1983-07-21 Nippon Oil Co Ltd オレフイン重合触媒用担体の製造方法
JPS58138713A (ja) * 1982-02-12 1983-08-17 Nippon Oil Co Ltd オレフイン重合触媒用担体の製造方法
US5330949A (en) * 1985-06-17 1994-07-19 Idemitsu Petrochemical Company, Ltd. Method for producing polyolefin
US4728705A (en) * 1986-02-28 1988-03-01 Shell Oil Company Olefin polymerization catalyst composition
IN168393B (es) * 1986-02-28 1991-03-23 Shell Oil Co
US4914069A (en) * 1987-05-04 1990-04-03 Shell Oil Company Preparation of olefin polymerization catalyst component
US4937300A (en) * 1987-06-22 1990-06-26 Phillips Petroleum Company Catalyst and polymerization of olefins
US4855271A (en) * 1987-06-22 1989-08-08 Phillips Petroleum Company Catalyst and polymerization of olefins
IT1237812B (it) * 1989-12-22 1993-06-17 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
JP3266942B2 (ja) * 1992-09-10 2002-03-18 住友化学工業株式会社 エチレンの高温高圧重合方法
DE4300185A1 (de) * 1993-01-07 1994-07-14 Huels Chemische Werke Ag Lagerstabile Lösungen eines Gemisches aus carbonisiertem Magnesiummethylat, carbonisiertem Magnesiumethylat und deren carbonisiertem Mischalkoxid in einem Gemisch aus Methanol und Ethanol sowie deren Herstellung und Verwendung
US5705579A (en) * 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
US6084042A (en) * 1998-06-29 2000-07-04 Nova Chemicals (International) S.A. Mixed titanium-vanadium catalysts for solution ethylene polymerization
BE1012219A3 (fr) * 1998-10-05 2000-07-04 Solvay Catalyseur destine a la polymerisation des olefines, procede pour sa fabrication et utilisation.
DE10003872A1 (de) 1999-11-26 2001-08-16 Basell Polyolefine Gmbh Verfahren zum Herstellen eines Poly-l-olefins in Gegenwart eines Ziegler Katalysators
EP1525231B1 (en) * 2002-07-02 2007-12-05 Basell Poliolefine Italia S.r.l. Catalyst system for the polymerization of olefins
RU2350594C1 (ru) * 2007-08-13 2009-03-27 Общество с ограниченной ответственностью "Катализ" Алюмооксидный носитель, способ получения алюмооксидного носителя и способ получения катализатора дегидрирования c3-c5 парафиновых углеводородов на этом носителе

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056668A (en) * 1966-10-21 1977-11-01 Solvay & Cie Process for the polymerization and copolymerization of olefins with a solid support catalyst
EP0064637A1 (de) * 1981-05-02 1982-11-17 BASF Aktiengesellschaft Verfahren zur Herstellung von Homo- und Copolymerisaten von Monoolefinen durch Polymerisation des bzw. der Monomeren mittels eines Ziegler-Katalysatorsystems auf der Basis einer Vanadium enthaltenden Katalysatorkomponente
EP0292134A2 (en) * 1987-05-04 1988-11-23 Shell Oil Company Preparation of olefin polymerization catalyst component
US5015612A (en) * 1988-09-14 1991-05-14 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst subjected to preliminary polymerization treatment
EP0626393A1 (en) * 1993-04-05 1994-11-30 Petroleo Brasileiro S.A. - Petrobras Ziegler-type spherical catalyst for olefin polymerization, its preparation and its use

Also Published As

Publication number Publication date
EP2796478A1 (en) 2014-10-29
EP2796478A4 (en) 2015-11-11
WO2013091033A1 (pt) 2013-06-27
BR112014011174A2 (pt) 2017-05-02
ES2497341A2 (es) 2014-09-22
JP2015500914A (ja) 2015-01-08
JP5873930B2 (ja) 2016-03-01
CA2855529A1 (en) 2013-06-27
US20140038809A1 (en) 2014-02-06
ES2497341B1 (es) 2015-09-23
WO2013091033A8 (pt) 2013-09-06

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