SG11201501863TA - Activation and use of hydroalkylation catalysts for the preparation of cycloalkylaromatic compounds, phenol and cyclohexanone - Google Patents
Activation and use of hydroalkylation catalysts for the preparation of cycloalkylaromatic compounds, phenol and cyclohexanoneInfo
- Publication number
- SG11201501863TA SG11201501863TA SG11201501863TA SG11201501863TA SG11201501863TA SG 11201501863T A SG11201501863T A SG 11201501863TA SG 11201501863T A SG11201501863T A SG 11201501863TA SG 11201501863T A SG11201501863T A SG 11201501863TA SG 11201501863T A SG11201501863T A SG 11201501863TA
- Authority
- SG
- Singapore
- Prior art keywords
- cyclohexanone
- phenol
- activation
- preparation
- cycloalkylaromatic compounds
- Prior art date
Links
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 title 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title 1
- 230000004913 activation Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7276—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7476—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261712980P | 2012-10-12 | 2012-10-12 | |
PCT/US2013/063187 WO2014074248A1 (en) | 2012-10-12 | 2013-10-03 | Activation and use of hydroalkylation catalysts for the preparation of cycloalkylaromatic compounds, phenol and cyclohexanone |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11201501863TA true SG11201501863TA (en) | 2015-04-29 |
Family
ID=49474699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11201501863TA SG11201501863TA (en) | 2012-10-12 | 2013-10-03 | Activation and use of hydroalkylation catalysts for the preparation of cycloalkylaromatic compounds, phenol and cyclohexanone |
Country Status (6)
Country | Link |
---|---|
US (1) | US9364823B2 (en) |
EP (1) | EP2906346A1 (en) |
KR (1) | KR101705474B1 (en) |
CN (1) | CN103721740B (en) |
SG (1) | SG11201501863TA (en) |
WO (1) | WO2014074248A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9169170B2 (en) | 2013-10-01 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Hydroalkylating process |
US9718744B2 (en) | 2013-10-18 | 2017-08-01 | Exxonmobil Chemical Patents Inc. | Hydroalkylating process comprising an activation of the hydroalkylation catalyst and method of making phenol and cyclohexanone |
US9868117B2 (en) | 2014-04-30 | 2018-01-16 | Exxonmobil Chemical Patents Inc. | Method of improving metal-impregnated catalyst performance |
US10967364B2 (en) | 2015-03-25 | 2021-04-06 | University Of Virginia Patent Foundation | Catalysts and methods for forming alkenyl and alkyl substituted arenes |
CN112221521B (en) * | 2016-01-27 | 2024-05-17 | 中国石油化工股份有限公司 | Catalyst, preparation method thereof and method for preparing cyclohexylbenzene |
CN107008477B (en) * | 2016-01-27 | 2020-05-19 | 中国石油化工股份有限公司 | Catalyst, preparation method thereof and method for preparing cyclohexylbenzene |
CN110354913B (en) * | 2018-04-11 | 2021-09-21 | 中国石油化工股份有限公司 | In-situ activation method of light hydrocarbon hydrogenation catalyst |
JP7241893B2 (en) * | 2019-01-25 | 2023-03-17 | エクソンモービル ケミカル パテンツ インコーポレイテッド | Activation of low metal content catalysts |
US11433386B2 (en) | 2019-01-25 | 2022-09-06 | Exxonmobil Chemical Patents Inc. | Activation of low metal content catalyst |
CN110479355A (en) * | 2019-09-03 | 2019-11-22 | 中触媒新材料股份有限公司 | A kind of preparation method of the catalyst for synthesizing cyclohexyl benzene |
CN113336623B (en) * | 2020-03-03 | 2023-05-30 | 台湾中油股份有限公司 | Process for producing dialiphatic diol |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3760017A (en) | 1971-05-17 | 1973-09-18 | Texaco Inc | Hydroalkylation catalyst and process |
US3760018A (en) | 1971-05-17 | 1973-09-18 | Texaco Inc | Hydroalkylation catalyst and process |
US4268699A (en) | 1978-07-21 | 1981-05-19 | Phillips Petroleum Company | Hydroalkylation using nickel-ruthenium catalyst on zeolite type support |
US4329531A (en) | 1980-05-29 | 1982-05-11 | Phillips Petroleum Company | Hydroalkylation catalyst and methods for producing and employing same |
DE3117135A1 (en) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | CRYSTALLINE ALUMOSILICATE, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR CATALYTICALLY CONVERTING METHANOL AND / OR DIMETHYL ETHER IN HYDROCARBONS |
US4826667A (en) | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
US4954325A (en) | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
IT1205681B (en) | 1987-05-26 | 1989-03-31 | Eniricerche Spa | SYNTHETIC POROUS CRYSTALLINE MATERIAL CONTAINING SILICON AND BORON OXIDES |
GB8809214D0 (en) | 1988-04-19 | 1988-05-25 | Exxon Chemical Patents Inc | Reductive alkylation process |
US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
ES2124154B1 (en) | 1995-11-08 | 1999-12-01 | Univ Politecnica De Valencia C | PREPARATION METHOD AND CATALYTIC PROPERTIES OF A MICROPOROUS SOLID WITH HIGH EXTERNAL SURFACE. |
ES2105982B1 (en) | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | ZEOLITE ITQ-1 |
TW382146B (en) | 1998-06-19 | 2000-02-11 | United Microeletronics Corp | Semiconductor step-down voltage device having low power consumption |
US6037513A (en) | 1998-07-09 | 2000-03-14 | Mobil Oil Corporation | Hydroalkylation of aromatic hydrocarbons |
DE10015874A1 (en) | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Process for the preparation of aromatic alcohols, especially phenol |
US6756030B1 (en) | 2003-03-21 | 2004-06-29 | Uop Llc | Crystalline aluminosilicate zeolitic composition: UZM-8 |
ES2363571T3 (en) * | 2007-02-23 | 2011-08-09 | Mitsui Chemicals, Inc. | PROCESS TO PREPARE A RENTED AROMATIC COMPOUND. |
ES2373189T3 (en) | 2007-08-15 | 2012-02-01 | Exxonmobil Chemical Patents Inc. | PROCEDURE TO PRODUCE CYCLHEXILBENZENE. |
CN101687784B (en) | 2007-08-22 | 2014-11-12 | 埃克森美孚化学专利公司 | Oxidation of hydrocarbons |
ES2573261T3 (en) * | 2008-04-14 | 2016-06-06 | Exxonmobil Chemical Patents Inc. | Procedure to produce cyclohexylbenzene |
CN102407166B (en) * | 2010-09-21 | 2013-07-10 | 中国石油化工股份有限公司 | Pretreating method for copper, ruthenium, cobalt, nickel, palladium and platinum-based metal catalyst |
WO2012050751A1 (en) * | 2010-10-11 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
-
2013
- 2013-10-03 WO PCT/US2013/063187 patent/WO2014074248A1/en active Application Filing
- 2013-10-03 KR KR1020157009280A patent/KR101705474B1/en active IP Right Grant
- 2013-10-03 SG SG11201501863TA patent/SG11201501863TA/en unknown
- 2013-10-03 US US14/424,832 patent/US9364823B2/en active Active
- 2013-10-03 EP EP13780262.5A patent/EP2906346A1/en not_active Withdrawn
- 2013-10-14 CN CN201310477160.0A patent/CN103721740B/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20150224493A1 (en) | 2015-08-13 |
KR20150056595A (en) | 2015-05-26 |
US9364823B2 (en) | 2016-06-14 |
CN103721740A (en) | 2014-04-16 |
CN103721740B (en) | 2017-09-26 |
WO2014074248A1 (en) | 2014-05-15 |
KR101705474B1 (en) | 2017-02-09 |
WO2014074248A8 (en) | 2015-01-15 |
EP2906346A1 (en) | 2015-08-19 |
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