ES2493891T3 - Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa - Google Patents

Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa Download PDF

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Publication number
ES2493891T3
ES2493891T3 ES10763051.9T ES10763051T ES2493891T3 ES 2493891 T3 ES2493891 T3 ES 2493891T3 ES 10763051 T ES10763051 T ES 10763051T ES 2493891 T3 ES2493891 T3 ES 2493891T3
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Spain
Prior art keywords
tars
removal
hydrocarbon
phase
based fluid
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ES10763051.9T
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English (en)
Inventor
Robin Willem Rudolf Zwart
Alexander Bos
Johannes Kuipers
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Energieonderzoek Centrum Nederland ECN
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Energieonderzoek Centrum Nederland ECN
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Publication of ES2493891T3 publication Critical patent/ES2493891T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • C10K1/18—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/028—Dust removal by electrostatic precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/046—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/024—Dust removal by filtration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Método para la gasificación de biomasa en un reactor (3) a una temperatura de entre 600 y1300°C y purificación del flujo de gas resultante del reactor para la eliminación de alquitranes de dicho flujo de gas, comprendiendo la eliminación de dichos alquitranes en dos fases, donde en la primera fase de limpieza (8) el gas del reactor (3) se satura a una temperatura de entre 250 y 900°C con un primer fluido basado en hidrocarburo que comprende hidrocarburos aromáticos y donde en una segunda fase de limpieza (18) después de la primera fase de limpieza (8) los alquitranes restantes son absorbidos del gas con un segundo fluido basado en hidrocarburo, donde una mezcla de los alquitranes y el primer fluido basado en hidrocarburo resultante de la primera fase de limpieza se lleva a una primera fase de separación (23) separada de dicho segundo fluido basado en hidrocarburo, caracterizado por el hecho de que en dicha primera fase de separación (23) la mezcla de alquitranes y el primer fluido basado en hidrocarburo se separan basándose en la temperatura de evaporación, y donde la parte ligera resultante de la primera fase de separación se añade al flujo de gas del reactor (3) en la primera fase de limpieza (8) y donde se elimina la parte pesada

Description

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Claims (1)

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ES10763051.9T 2009-09-25 2010-09-24 Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa Active ES2493891T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL2003547 2009-09-25
NL2003547A NL2003547C2 (en) 2009-09-25 2009-09-25 Method and system for gasifying biomass.
PCT/NL2010/050622 WO2011037463A1 (en) 2009-09-25 2010-09-24 Method and device for removing tars from synthesis gas obtained during gasification of biomass

Publications (1)

Publication Number Publication Date
ES2493891T3 true ES2493891T3 (es) 2014-09-12

Family

ID=42227822

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10763051.9T Active ES2493891T3 (es) 2009-09-25 2010-09-24 Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa

Country Status (15)

Country Link
US (1) US9181504B2 (es)
EP (1) EP2480637B1 (es)
JP (1) JP5763079B2 (es)
KR (1) KR101721003B1 (es)
CN (1) CN102639680B (es)
AU (1) AU2010298801B2 (es)
BR (1) BR112012006344B1 (es)
CA (1) CA2774700C (es)
ES (1) ES2493891T3 (es)
NL (1) NL2003547C2 (es)
PL (1) PL2480637T3 (es)
RU (1) RU2555046C2 (es)
UA (1) UA108861C2 (es)
WO (1) WO2011037463A1 (es)
ZA (1) ZA201202167B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2009310C2 (en) 2012-08-10 2014-02-18 Stichting Energie Tar-scrubbing liquid.
JP6048133B2 (ja) * 2012-12-27 2016-12-21 株式会社Ihi 合成ガス生成システム、および、合成ガス生成方法
CN103333718A (zh) * 2013-03-29 2013-10-02 张晓� 一种含固体粉尘、含焦油气的气体的分离方法
BR112019023806B1 (pt) 2017-05-12 2022-08-23 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Processo para isolar uma fração de compostos aromáticos monocíclicos a partir de um gás e sistema modular
NL2018908B1 (en) 2017-05-12 2018-11-15 Stichting Energieonderzoek Centrum Nederland Production and isolation of monocyclic aromatic compounds from a gasification gas
RU2723865C1 (ru) * 2019-08-12 2020-06-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") Способ получения синтез-газа из биомассы растительного происхождения

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GB158915A (en) * 1917-11-03 1921-02-24 Barbet & Fils & Cie E Improved process for removing the tar from the products of the distillation of wood,coal and the like
GB568593A (en) * 1940-09-12 1945-04-12 Foster Wheeler Ltd Improvements in the recovery of benzene from gases by absorption in wash oils
US4123502A (en) * 1975-02-06 1978-10-31 Heinz Holter Process for the purification of gas generated in the pressure gasification of coal
DE2607745C2 (de) * 1976-02-26 1984-03-15 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum Behandeln von Kondensat aus der Kühlung von Rohgas der Druckvergasung fester Brennstoffe
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US4211539A (en) * 1976-05-26 1980-07-08 Metallgesellschaft Aktiengesellschaft Producing pure gas of high calorific value from gasification of solid fuel
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US4324643A (en) * 1980-08-26 1982-04-13 Occidental Research Corporation Pyrolysis process for producing condensed stabilized hydrocarbons
AT385765B (de) * 1985-02-07 1988-05-10 Waagner Biro Ag Verfahren zur erzeugung teerarmer generatorgase und brennstoffvergasungsanlage zur durchfuehrung des verfahrens
HU216910B (hu) * 1992-05-08 1999-10-28 State Electricity Commission Of Victoria Eljárás és berendezés szénalapú tüzelőanyag integrált szárítására és elgázosítására
NL1018803C2 (nl) 2001-08-22 2003-02-25 Stichting Energie Werkwijze en stelsel voor het vergassen van een biomassa.
JP3943042B2 (ja) * 2003-02-26 2007-07-11 東洋エンジニアリング株式会社 タール含有ガスの洗浄方法および装置並びに可燃性ガス製造方法および装置
JP4312632B2 (ja) * 2004-03-03 2009-08-12 中外炉工業株式会社 バイオマスガス化システムおよびその運転方法
WO2007048058A2 (en) * 2005-10-21 2007-04-26 Taylor Biomass Energy, Llc Process and system for gasification with in-situ tar removal
JP2007238670A (ja) 2006-03-06 2007-09-20 Mitsubishi Heavy Ind Ltd ガス浄化装置及び方法、ガス化システム、ガス化発電システム
NL2000151C2 (nl) * 2006-07-20 2008-01-24 Stichting Energie Werkwijze en systeem voor het reinigen van een uit biomassa gevormd productgas.
JP5344447B2 (ja) * 2007-10-17 2013-11-20 独立行政法人産業技術総合研究所 ガス化炉で蒸発したアルカリを再利用したガス化システム
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Also Published As

Publication number Publication date
US20120216460A1 (en) 2012-08-30
BR112012006344A2 (pt) 2017-07-25
CN102639680A (zh) 2012-08-15
WO2011037463A1 (en) 2011-03-31
CA2774700A1 (en) 2011-03-31
JP5763079B2 (ja) 2015-08-12
UA108861C2 (uk) 2015-06-25
RU2012116535A (ru) 2013-10-27
CN102639680B (zh) 2016-01-06
JP2013506026A (ja) 2013-02-21
AU2010298801A2 (en) 2012-05-24
RU2555046C2 (ru) 2015-07-10
AU2010298801B2 (en) 2015-11-26
EP2480637A1 (en) 2012-08-01
AU2010298801A1 (en) 2012-05-10
ZA201202167B (en) 2012-11-28
KR20120091052A (ko) 2012-08-17
KR101721003B1 (ko) 2017-03-29
PL2480637T3 (pl) 2014-11-28
EP2480637B1 (en) 2014-06-18
BR112012006344B1 (pt) 2018-09-18
CA2774700C (en) 2018-03-27
NL2003547C2 (en) 2011-03-29
US9181504B2 (en) 2015-11-10

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