ES2493891T3 - Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa - Google Patents

Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa Download PDF

Info

Publication number
ES2493891T3
ES2493891T3 ES10763051.9T ES10763051T ES2493891T3 ES 2493891 T3 ES2493891 T3 ES 2493891T3 ES 10763051 T ES10763051 T ES 10763051T ES 2493891 T3 ES2493891 T3 ES 2493891T3
Authority
ES
Spain
Prior art keywords
tars
removal
hydrocarbon
phase
based fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10763051.9T
Other languages
English (en)
Inventor
Robin Willem Rudolf Zwart
Alexander Bos
Johannes Kuipers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Energy Research Centre of the Netherlands
Original Assignee
Energy Research Centre of the Netherlands
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Research Centre of the Netherlands filed Critical Energy Research Centre of the Netherlands
Application granted granted Critical
Publication of ES2493891T3 publication Critical patent/ES2493891T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • C10K1/18—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/028—Dust removal by electrostatic precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/046—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/024—Dust removal by filtration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Método para la gasificación de biomasa en un reactor (3) a una temperatura de entre 600 y1300°C y purificación del flujo de gas resultante del reactor para la eliminación de alquitranes de dicho flujo de gas, comprendiendo la eliminación de dichos alquitranes en dos fases, donde en la primera fase de limpieza (8) el gas del reactor (3) se satura a una temperatura de entre 250 y 900°C con un primer fluido basado en hidrocarburo que comprende hidrocarburos aromáticos y donde en una segunda fase de limpieza (18) después de la primera fase de limpieza (8) los alquitranes restantes son absorbidos del gas con un segundo fluido basado en hidrocarburo, donde una mezcla de los alquitranes y el primer fluido basado en hidrocarburo resultante de la primera fase de limpieza se lleva a una primera fase de separación (23) separada de dicho segundo fluido basado en hidrocarburo, caracterizado por el hecho de que en dicha primera fase de separación (23) la mezcla de alquitranes y el primer fluido basado en hidrocarburo se separan basándose en la temperatura de evaporación, y donde la parte ligera resultante de la primera fase de separación se añade al flujo de gas del reactor (3) en la primera fase de limpieza (8) y donde se elimina la parte pesada

Description

imagen1
imagen2
imagen3
imagen4

Claims (1)

  1. imagen1
    imagen2
ES10763051.9T 2009-09-25 2010-09-24 Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa Active ES2493891T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL2003547A NL2003547C2 (en) 2009-09-25 2009-09-25 Method and system for gasifying biomass.
NL2003547 2009-09-25
PCT/NL2010/050622 WO2011037463A1 (en) 2009-09-25 2010-09-24 Method and device for removing tars from synthesis gas obtained during gasification of biomass

Publications (1)

Publication Number Publication Date
ES2493891T3 true ES2493891T3 (es) 2014-09-12

Family

ID=42227822

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10763051.9T Active ES2493891T3 (es) 2009-09-25 2010-09-24 Método y dispositivo para la eliminación de alquitranes de gas de síntesis obtenido durante la gasificación de biomasa

Country Status (15)

Country Link
US (1) US9181504B2 (es)
EP (1) EP2480637B1 (es)
JP (1) JP5763079B2 (es)
KR (1) KR101721003B1 (es)
CN (1) CN102639680B (es)
AU (1) AU2010298801B2 (es)
BR (1) BR112012006344B1 (es)
CA (1) CA2774700C (es)
ES (1) ES2493891T3 (es)
NL (1) NL2003547C2 (es)
PL (1) PL2480637T3 (es)
RU (1) RU2555046C2 (es)
UA (1) UA108861C2 (es)
WO (1) WO2011037463A1 (es)
ZA (1) ZA201202167B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2009310C2 (en) 2012-08-10 2014-02-18 Stichting Energie Tar-scrubbing liquid.
JP6048133B2 (ja) * 2012-12-27 2016-12-21 株式会社Ihi 合成ガス生成システム、および、合成ガス生成方法
CN103333718A (zh) * 2013-03-29 2013-10-02 张晓� 一种含固体粉尘、含焦油气的气体的分离方法
NL2018908B1 (en) 2017-05-12 2018-11-15 Stichting Energieonderzoek Centrum Nederland Production and isolation of monocyclic aromatic compounds from a gasification gas
EP3622041A1 (en) 2017-05-12 2020-03-18 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO Removal of monocyclic aromatic compounds (btex) from a gas
RU2723865C1 (ru) * 2019-08-12 2020-06-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") Способ получения синтез-газа из биомассы растительного происхождения

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB158915A (en) * 1917-11-03 1921-02-24 Barbet & Fils & Cie E Improved process for removing the tar from the products of the distillation of wood,coal and the like
GB568593A (en) * 1940-09-12 1945-04-12 Foster Wheeler Ltd Improvements in the recovery of benzene from gases by absorption in wash oils
US4123502A (en) * 1975-02-06 1978-10-31 Heinz Holter Process for the purification of gas generated in the pressure gasification of coal
DE2607745C2 (de) * 1976-02-26 1984-03-15 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum Behandeln von Kondensat aus der Kühlung von Rohgas der Druckvergasung fester Brennstoffe
US4211539A (en) * 1976-05-26 1980-07-08 Metallgesellschaft Aktiengesellschaft Producing pure gas of high calorific value from gasification of solid fuel
US4211540A (en) * 1978-12-29 1980-07-08 Fluor Corporation Process for the manufacture of fuel gas
US4324643A (en) * 1980-08-26 1982-04-13 Occidental Research Corporation Pyrolysis process for producing condensed stabilized hydrocarbons
AT385765B (de) * 1985-02-07 1988-05-10 Waagner Biro Ag Verfahren zur erzeugung teerarmer generatorgase und brennstoffvergasungsanlage zur durchfuehrung des verfahrens
CA2134871C (en) * 1992-05-08 2001-12-18 Terence R. Johnson Integrated carbonaceous fuel drying and gasification process and apparatus
NL1018803C2 (nl) * 2001-08-22 2003-02-25 Stichting Energie Werkwijze en stelsel voor het vergassen van een biomassa.
JP3943042B2 (ja) * 2003-02-26 2007-07-11 東洋エンジニアリング株式会社 タール含有ガスの洗浄方法および装置並びに可燃性ガス製造方法および装置
JP4312632B2 (ja) * 2004-03-03 2009-08-12 中外炉工業株式会社 バイオマスガス化システムおよびその運転方法
NZ567582A (en) * 2005-10-21 2011-12-22 Taylor Biomass Energy Llc Process and system for gasification with in-situ tar removal having a gas conditioning module
JP2007238670A (ja) * 2006-03-06 2007-09-20 Mitsubishi Heavy Ind Ltd ガス浄化装置及び方法、ガス化システム、ガス化発電システム
NL2000151C2 (nl) * 2006-07-20 2008-01-24 Stichting Energie Werkwijze en systeem voor het reinigen van een uit biomassa gevormd productgas.
JP5344447B2 (ja) * 2007-10-17 2013-11-20 独立行政法人産業技術総合研究所 ガス化炉で蒸発したアルカリを再利用したガス化システム
JP2009132829A (ja) * 2007-11-30 2009-06-18 Yanmar Co Ltd バイオマス分解ガス処理装置
JP2009215445A (ja) * 2008-03-11 2009-09-24 Mitsui Eng & Shipbuild Co Ltd 熱分解ガスの改質方法及びシステム
US8470078B2 (en) * 2008-03-12 2013-06-25 Ihi E&C International Corporation Process for removing tar from synthesis gas

Also Published As

Publication number Publication date
EP2480637A1 (en) 2012-08-01
AU2010298801A2 (en) 2012-05-24
AU2010298801B2 (en) 2015-11-26
BR112012006344A2 (pt) 2017-07-25
CA2774700C (en) 2018-03-27
CN102639680A (zh) 2012-08-15
NL2003547C2 (en) 2011-03-29
RU2012116535A (ru) 2013-10-27
KR20120091052A (ko) 2012-08-17
US9181504B2 (en) 2015-11-10
AU2010298801A1 (en) 2012-05-10
JP5763079B2 (ja) 2015-08-12
RU2555046C2 (ru) 2015-07-10
UA108861C2 (uk) 2015-06-25
EP2480637B1 (en) 2014-06-18
BR112012006344B1 (pt) 2018-09-18
US20120216460A1 (en) 2012-08-30
JP2013506026A (ja) 2013-02-21
WO2011037463A1 (en) 2011-03-31
ZA201202167B (en) 2012-11-28
PL2480637T3 (pl) 2014-11-28
CA2774700A1 (en) 2011-03-31
KR101721003B1 (ko) 2017-03-29
CN102639680B (zh) 2016-01-06

Similar Documents

Publication Publication Date Title
JP6818760B2 (ja) コンパクトな海中脱水
PE20110129A1 (es) Procesos para convertir alcanos gaseosos en hidrocarburos liquidos
DK179711B1 (da) Separating carbon dioxide and hydrogen sulfide from a natural gas stream using co-current contacting systems
AR081347A1 (es) Procedimiento para la preparacion de gas de sintesis
AU2010298708B2 (en) Maintaining low carbon monoxide levels in product carbon dioxide
PE20140727A1 (es) Medio de absorcion con contenido de amina, procedimiento y dispositivo para la absorcion de gases acidos a partir de mezclas gaseosas
UY33666A (es) Métodos mejorados para el almacenamiento y transporte de gas natural en disolventes líquidos
AR077603A1 (es) Sistemas y metodos para extraer hidrocarburos pesados y gases acidos de una corriente de gases de hidrocarburos
MX2016011957A (es) Proceso y aparato para la eliminacion de hidrocarburos pesados del gas natural pobre antes de la licuefaccion.
EA201401226A1 (ru) Способ абсорбции coиз газовой смеси
MX2013012789A (es) Sistema de reactor subterraneo.
AR058123A1 (es) Proceso para convertir alcanos gaseosos a olefinas e hidrocarburos liquidos
CL2018000105A1 (es) Dispositivo y método para producir gas sintético
CL2016001422A1 (es) Proceso para la producción de gas de síntesis.
PE20141950A1 (es) Procedimiento de remojo previo mejorado para la conversion de biomasa
BRPI0419012A (pt) armazenamento de gás natural em solventes lìquidos e métodos para absorver e separar gás natural para dentro e para fora de solventes lìquidos
BR112015026245B1 (pt) edulcoração de gás natural por agente de contato de membrana
CL2024002506A1 (es) Un método para formar un gas de síntesis para producir hidrocarburos líquidos
ES2344115T3 (es) Procedimiento para producir olefinas.
ES3041522T3 (en) Production and isolation of monocyclic aromatic compounds from a gasification gas
MX2022015417A (es) Metodos para separar dioxido de carbono de gases de combustion y secuestrar dioxido de carbono liquido.
WO2015140460A3 (fr) Procédé et appareil de séparation cryogénique d'un gaz de synthèse contenant du monoxyde de carbone, du méthane et de l'hydrogène
AR087318A1 (es) Procedimiento para retirar contaminantes oxigenados de una corriente de etileno
BR112015017802B1 (pt) processo para decomposição de um gás de alimentação
RU2017113723A (ru) Высокоселективная полиимидная мембрана для повышения качества природного газа и очистки водорода