ES2274154T3 - Composicion antitranspirante y procedimiento de preparacion de la misma. - Google Patents
Composicion antitranspirante y procedimiento de preparacion de la misma. Download PDFInfo
- Publication number
- ES2274154T3 ES2274154T3 ES03019409T ES03019409T ES2274154T3 ES 2274154 T3 ES2274154 T3 ES 2274154T3 ES 03019409 T ES03019409 T ES 03019409T ES 03019409 T ES03019409 T ES 03019409T ES 2274154 T3 ES2274154 T3 ES 2274154T3
- Authority
- ES
- Spain
- Prior art keywords
- aluminum
- zirconium
- antiperspirant
- glycerin
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims description 32
- 238000002360 preparation method Methods 0.000 title description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 220
- 235000011187 glycerol Nutrition 0.000 claims abstract description 109
- 239000003213 antiperspirant Substances 0.000 claims abstract description 99
- 230000001166 anti-perspirative effect Effects 0.000 claims abstract description 93
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 60
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 57
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 29
- FMXLGOWFNZLJQK-UHFFFAOYSA-N hypochlorous acid;zirconium Chemical compound [Zr].ClO FMXLGOWFNZLJQK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000001413 amino acids Chemical class 0.000 claims abstract description 7
- 150000001450 anions Chemical class 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 4
- 150000002739 metals Chemical class 0.000 claims abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 41
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 39
- 239000000047 product Substances 0.000 claims description 34
- 239000011148 porous material Substances 0.000 claims description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 22
- 238000010992 reflux Methods 0.000 claims description 14
- 239000013543 active substance Substances 0.000 claims description 12
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 10
- 239000004471 Glycine Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 5
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 5
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical class [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- NAKFRQULMGLXBT-UHFFFAOYSA-N 6-methoxyquinolin-8-ol Chemical compound N1=CC=CC2=CC(OC)=CC(O)=C21 NAKFRQULMGLXBT-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
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- 239000011975 tartaric acid Substances 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims 4
- 239000003607 modifier Substances 0.000 claims 2
- 239000012445 acidic reagent Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- ZUIZENMUYAPNDS-UHFFFAOYSA-G aluminum 2-aminoacetate zirconium(4+) Chemical class [Al+3].[Zr+4].NCC([O-])=O.NCC([O-])=O.NCC([O-])=O.NCC([O-])=O.NCC([O-])=O.NCC([O-])=O.NCC([O-])=O ZUIZENMUYAPNDS-UHFFFAOYSA-G 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 claims 1
- 238000004108 freeze drying Methods 0.000 claims 1
- 125000003630 glycyl group Chemical group [H]N([H])C([H])([H])C(*)=O 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- 238000000643 oven drying Methods 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 238000001291 vacuum drying Methods 0.000 claims 1
- 150000003752 zinc compounds Chemical class 0.000 claims 1
- -1 aluminum zirconium chlorohydrates Chemical class 0.000 abstract description 13
- YCLAMANSVUJYPT-UHFFFAOYSA-L aluminum chloride hydroxide hydrate Chemical compound O.[OH-].[Al+3].[Cl-] YCLAMANSVUJYPT-UHFFFAOYSA-L 0.000 abstract description 7
- WYANSMZYIOPJFV-UHFFFAOYSA-L aluminum;2-aminoacetic acid;zirconium(4+);chloride;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Cl-].[Zr+4].NCC(O)=O WYANSMZYIOPJFV-UHFFFAOYSA-L 0.000 abstract description 7
- 229940053431 aluminum sesquichlorohydrate Drugs 0.000 abstract description 5
- 150000003754 zirconium Chemical class 0.000 abstract description 4
- IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 abstract description 4
- 239000011149 active material Substances 0.000 abstract description 3
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 abstract description 3
- 150000005846 sugar alcohols Polymers 0.000 abstract description 3
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical class [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 abstract description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract description 2
- KNXDJTLIRRQLBE-UHFFFAOYSA-H dialuminum;propane-1,2-diol;chloride;pentahydroxide;hydrate Chemical compound O.[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Cl-].CC(O)CO KNXDJTLIRRQLBE-UHFFFAOYSA-H 0.000 abstract description 2
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract description 2
- HAMGNFFXQJOFRZ-UHFFFAOYSA-L aluminum;zirconium(4+);chloride;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Cl-].[Zr+4] HAMGNFFXQJOFRZ-UHFFFAOYSA-L 0.000 abstract 4
- 229940071540 aluminum zirconium octachlorohydrex gly Drugs 0.000 abstract 1
- 229940048496 aluminum zirconium pentachlorohydrex gly Drugs 0.000 abstract 1
- 229940048506 aluminum zirconium tetrachlorohydrex gly Drugs 0.000 abstract 1
- 229940072028 aluminum zirconium trichlorohydrex gly Drugs 0.000 abstract 1
- SJXYSRSHDPPYIU-UHFFFAOYSA-L aluminum;propane-1,2-diol;chloride;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Cl-].CC(O)CO SJXYSRSHDPPYIU-UHFFFAOYSA-L 0.000 abstract 1
- YXZZLAMCXFHTTE-UHFFFAOYSA-N aluminum;propane-1,2-diol;trihypochlorite;hydrate Chemical compound O.[Al+3].Cl[O-].Cl[O-].Cl[O-].CC(O)CO YXZZLAMCXFHTTE-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 abstract 1
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
- AZOOXWWPWARTFV-UHFFFAOYSA-N zirconium hydrochloride Chemical class Cl.[Zr] AZOOXWWPWARTFV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/58—Metal complex; Coordination compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/244,701 US6649153B1 (en) | 2002-09-16 | 2002-09-16 | Skin friendly antiperspirant composition and method of making |
| US244701 | 2002-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2274154T3 true ES2274154T3 (es) | 2007-05-16 |
Family
ID=29420111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03019409T Expired - Lifetime ES2274154T3 (es) | 2002-09-16 | 2003-08-27 | Composicion antitranspirante y procedimiento de preparacion de la misma. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6649153B1 (enExample) |
| EP (1) | EP1398023B1 (enExample) |
| JP (1) | JP2004107345A (enExample) |
| CN (1) | CN1494896A (enExample) |
| AT (1) | ATE342041T1 (enExample) |
| AU (1) | AU2003235034A1 (enExample) |
| CA (1) | CA2440492A1 (enExample) |
| DE (1) | DE60308973T2 (enExample) |
| ES (1) | ES2274154T3 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6902724B1 (en) * | 2004-03-24 | 2005-06-07 | Reheis, Inc. | Enhanced efficacy basic aluminum halides, antiperspirant active compositions and methods for making |
| US7014843B2 (en) | 2004-03-24 | 2006-03-21 | Reheis, Inc. | Enhanced efficacy basic aluminum halides/metal cation salt, antiperspirants actives and compositions containing such materials and methods for making |
| WO2007031137A1 (en) * | 2005-07-30 | 2007-03-22 | Unilever Plc | Spray compositions |
| GB0525395D0 (en) * | 2005-10-28 | 2006-01-18 | Unilever Plc | Antiperspirant or deodorant compositions |
| US20090081639A1 (en) * | 2007-05-31 | 2009-03-26 | Phil Hill | Assay for sensitivity to chemotherapeutic agents |
| US20090016979A1 (en) * | 2007-07-09 | 2009-01-15 | Zijun Li | Aluminum and aluminum-zirconium compositions of enhanced efficacy containing reduced buffer and/or reduced zirconium |
| PL2187863T3 (pl) * | 2007-09-21 | 2013-09-30 | Colgate Palmolive Co | Przeciwpotowe sole okso-heksameryczny cyrkon-oktaaminokwasu |
| AU2008308824C1 (en) | 2007-10-01 | 2012-07-12 | Colgate-Palmolive Company | Propylene glycol/glycerin-based deodorant |
| HK1216012A1 (zh) * | 2012-12-19 | 2016-10-07 | Colgate-Palmolive Company | 含鋅氨基酸/三甲基甘氨酸鹵化物前體的組合物 |
| US11369554B2 (en) | 2018-03-27 | 2022-06-28 | Elc Management Llc | Catalyzed dye system |
| US10952947B2 (en) * | 2018-03-27 | 2021-03-23 | Elc Management Llc | Thickened catalyzed dye system |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL291778A (enExample) | 1962-04-27 | |||
| US3405153A (en) | 1965-09-15 | 1968-10-08 | Armour Pharma | Metal-aluminum inorganic-organic complexes and methods of preparing same |
| US3420932A (en) | 1966-12-20 | 1969-01-07 | Armour Pharma | Methods of making alcohol soluble complexes of aluminum and preparations employing the complexes |
| US3532130A (en) | 1969-11-13 | 1970-10-06 | Charles K Dunlap Jr | Wound tube with string loop |
| US3873686A (en) | 1969-12-01 | 1975-03-25 | Stewart M Beekman | Process for preparing alcohol-soluble aluminum chlorhydroxide-polyol complexes and product |
| US3981986A (en) | 1973-11-23 | 1976-09-21 | Armour Pharmaceutical Company | Zirconium-aluminum-polyol buffered anti-perspirant complexes |
| DE3670569D1 (de) | 1985-03-01 | 1990-05-31 | Procter & Gamble | Milder reinigungsschaum. |
| EP0295070A3 (en) * | 1987-06-11 | 1989-05-31 | The Procter & Gamble Company | Liquid antiperspirant actives and processes for preparing the same |
| US4829092A (en) | 1987-07-27 | 1989-05-09 | Chesebrough-Pond's Inc. | Glycerol and diglycerol mixtures for skin moisturizing |
| GB9002290D0 (en) | 1990-02-01 | 1990-03-28 | Procter & Gamble | Cosmetic compositions |
| US5043359A (en) | 1990-03-05 | 1991-08-27 | Dow Corning Corporation | Skin conditioning compositions containing glyceroxyfunctional silanes and siloxanes |
| CA2064179C (en) | 1991-05-03 | 2006-01-03 | Anthony J. Benfatto | Clear gelled cosmetic compositions and process for production |
| US5215759A (en) | 1991-10-01 | 1993-06-01 | Chanel, Inc. | Cosmetic composition |
| AU676465B2 (en) | 1992-01-24 | 1997-03-13 | Gillette Company, The | Usnic acid deodorant stick |
| US5871754A (en) | 1993-08-06 | 1999-02-16 | The Procter & Gamble Company | Cosmetic compositions |
| US5409691A (en) | 1993-10-18 | 1995-04-25 | Swain; Dan E. | Solution comprising aluminum acetate and glycerin |
| WO1996014052A1 (en) | 1994-11-02 | 1996-05-17 | The Gillette Company | Method of making polyhydric alcohol solutions of enhanced efficacy antiperspirant actives |
| GB9502495D0 (en) | 1995-02-09 | 1995-03-29 | Unilever Plc | Antiperspirant compositions |
| DE69618968T2 (de) | 1995-08-31 | 2002-11-28 | Procter & Gamble | Hautpflegemittel. das silikongummi sowie eine mischung aus polyoxiethylenen und einer glycerinverbindung enthalt |
| US6010688A (en) * | 1997-06-25 | 2000-01-04 | The Gillette Company | Polyhydric alcohol stabilized antiperspirant salt solutions |
| US5997850C1 (en) | 1997-10-29 | 2001-11-27 | Colgate Palmolive Co | Antiperspirant actives and formulations made therefrom |
| US5972362A (en) | 1997-12-23 | 1999-10-26 | Wenker; Naamah T. | Therapeutic skin preparation |
| JP2001002555A (ja) * | 1999-06-24 | 2001-01-09 | Shin Etsu Chem Co Ltd | 皮膚化粧料 |
| US6451296B1 (en) * | 2000-02-01 | 2002-09-17 | Zijun Li | Enhanced efficacy aluminum-zirconium antiperspirants and methods for making |
| US6403067B1 (en) * | 2000-05-19 | 2002-06-11 | Colgate-Palmolive Company | Stable emulsions for cosmetic products |
| US6383476B1 (en) | 2001-03-05 | 2002-05-07 | The Procter & Gamble Company | Anhydrous antiperspirant and deodorant compositions containing a solid, water-soluble, skin active agent |
| US6719965B2 (en) * | 2002-02-19 | 2004-04-13 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Antiperspirant or deodorant composition |
-
2002
- 2002-09-16 US US10/244,701 patent/US6649153B1/en not_active Expired - Fee Related
-
2003
- 2003-08-15 AU AU2003235034A patent/AU2003235034A1/en not_active Abandoned
- 2003-08-27 DE DE60308973T patent/DE60308973T2/de not_active Expired - Fee Related
- 2003-08-27 EP EP03019409A patent/EP1398023B1/en not_active Expired - Lifetime
- 2003-08-27 AT AT03019409T patent/ATE342041T1/de not_active IP Right Cessation
- 2003-08-27 ES ES03019409T patent/ES2274154T3/es not_active Expired - Lifetime
- 2003-08-29 CN CNA031577172A patent/CN1494896A/zh active Pending
- 2003-09-08 CA CA002440492A patent/CA2440492A1/en not_active Abandoned
- 2003-09-16 JP JP2003323396A patent/JP2004107345A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ATE342041T1 (de) | 2006-11-15 |
| JP2004107345A (ja) | 2004-04-08 |
| DE60308973T2 (de) | 2007-05-31 |
| EP1398023B1 (en) | 2006-10-11 |
| US6649153B1 (en) | 2003-11-18 |
| DE60308973D1 (de) | 2006-11-23 |
| CA2440492A1 (en) | 2004-03-16 |
| EP1398023A1 (en) | 2004-03-17 |
| AU2003235034A1 (en) | 2004-04-01 |
| CN1494896A (zh) | 2004-05-12 |
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