ES2191883T3 - Medios para controlar el tamaño de las particulas y eliminar la incrustacion en la sintesis del 1,2-polibutadieno sindiotactico. - Google Patents
Medios para controlar el tamaño de las particulas y eliminar la incrustacion en la sintesis del 1,2-polibutadieno sindiotactico.Info
- Publication number
- ES2191883T3 ES2191883T3 ES98108781T ES98108781T ES2191883T3 ES 2191883 T3 ES2191883 T3 ES 2191883T3 ES 98108781 T ES98108781 T ES 98108781T ES 98108781 T ES98108781 T ES 98108781T ES 2191883 T3 ES2191883 T3 ES 2191883T3
- Authority
- ES
- Spain
- Prior art keywords
- syndotactic
- polibutadien
- particles
- incrustations
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/912—Reaction medium purification
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Abstract
EL 1,2 - POLIBUTADIENO SINDIOTACTICO ES UNA RESINA TERMOPLASTICA QUE TIENE ENLACES DOBLES UNIDOS DE FORMA ALTERNA A SU ELEMENTO POLIMERICO PRINCIPAL. SE PUEDEN HACER PELICULAS, FIBRAS Y ARTICULOS MOLDEADOS UTILIZANDO 1,2 - POLIBUTADIENO SINDIOTACTICO. SE PUEDE MEZCLAR TAMBIEN CON CAUCHOS Y CURARLO JUNTO CON LOS MISMOS. NORMALMENTE ES PREFERENTE SINTETIZAR EL 1,2 POLIBUTADIENO SINDIOTACTICO EN UN MEDIO ACUOSOS A TRAVES DE UNA POLIMERIZACION EN SUSPENSION O EN EMULSION. EN TALES TECNICAS DE POLIMERIZACION ACUOSA CON FRECUENCIA SURGEN PROBLEMAS DE INCRUSTACIONES EN EL REACTOR Y DE CONTROL DEL TAMAÑO DE LAS PARTICULAS. ESTA INVENCION SE BASA EN EL DESCUBRIMIENTO INESPERADO DE QUE LAS INCRUSTACIONES DEL REACTOR SE PUEDEN REDUCIR EN GRAN MEDIDA O ELIMINAR Y QUE EL TAMAÑO DE LAS PARTICULAS SE PUEDE REGULAR SI SE LLEVA A CABO UNA POLIMERIZACION ACUOSA EN PRESENCIA DE UNA CANTIDAD CONTROLADA DE OXIGENO DISUELTO EN UNA CANTIDAD DE ENTRE 0,01 PPM APROXIMADAMENTE Y 4 PPM APROXIMADAMENTE. EN ESTA INVENCION SE PRESENTA, DE FORMA MAS ESPECIFICA, UN PROCESO PARA LA PREPARACION DE 1,2 - POLIBUTADIENO SINDIOTACTICO EN UN MEDIO ACUOSO CON LA FORMACION DE INCRUSTACIONES MINIMAS EN EL REACTOR QUE CONSISTE EN POLIMERIZAR UN MONOMERO DE 1,3 BUTADIENO EN UN MEDIO ACUOSO EN PRESENCIA DE (1) UN SISTEMA CATALIZADOR COMPUESTO DE (A) UN COMPUESTO DE UN METAL DE TRANSICION, (B) UN COMPUESTO DE ORGANOALUMINIO Y (C) AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO QUE CONSISTE EN DISULFURO DE CARBONO, ISOTIOCIANATO DE FENILO Y ACIDO XANTICO Y (2) DE 0,01 PPM APROXIMADAMENTE A 4 PPM APROXIMADAMENTE DE OXIGENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/861,668 US5756606A (en) | 1997-05-22 | 1997-05-22 | Means to control particle size and eliminate fouling in the synthesis of syndiotactic 1,2 - polybutadiene |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2191883T3 true ES2191883T3 (es) | 2003-09-16 |
Family
ID=25336436
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98108781T Expired - Lifetime ES2191883T3 (es) | 1997-05-22 | 1998-05-14 | Medios para controlar el tamaño de las particulas y eliminar la incrustacion en la sintesis del 1,2-polibutadieno sindiotactico. |
Country Status (6)
Country | Link |
---|---|
US (1) | US5756606A (es) |
EP (1) | EP0879834B1 (es) |
JP (1) | JPH10330418A (es) |
BR (1) | BR9801673A (es) |
DE (1) | DE69811140T2 (es) |
ES (1) | ES2191883T3 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7182839B2 (en) * | 2001-08-06 | 2007-02-27 | Baker Hughes Incorporated | Preventing deposition of fouling agents onto equipment |
US7534824B2 (en) * | 2004-07-22 | 2009-05-19 | Jsr Corporation | Polymer composition and process for producing the same |
KR101863039B1 (ko) * | 2010-09-28 | 2018-06-01 | 바젤 폴리올레핀 게엠베하 | 중합 반응기에 정전기 방지 화합물을 공급하는 방법 |
WO2012041811A1 (en) * | 2010-09-28 | 2012-04-05 | Basell Polyolefine Gmbh | Method for feeding an antistatic compound to a polymerization reactor |
EP2589612A1 (en) * | 2011-11-03 | 2013-05-08 | Basell Polyolefine GmbH | Process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators |
JP6015758B2 (ja) * | 2012-07-30 | 2016-10-26 | 宇部興産株式会社 | 変性シス−1,4−ポリブタジエンの製造方法 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE759763A (fr) * | 1969-12-02 | 1971-05-17 | Ube Industries | Procede pour la preparption de 1,2-polybutadiene |
CA1040347A (en) * | 1973-09-27 | 1978-10-10 | Hideo Ishikawa | Process for producing butadiene polymers |
US4153767A (en) * | 1977-11-22 | 1979-05-08 | Ube Industries Limited | Method of producing 1,2-polybutadiene |
JPS54132904A (en) * | 1978-04-06 | 1979-10-16 | Bridgestone Corp | Pneumatic tire with improved heating property |
US4394473A (en) * | 1981-10-06 | 1983-07-19 | The Coca-Cola Company | Rubber compounding bags and film made from syndiotactic 1,2-polybutadiene |
US4429085A (en) * | 1982-09-17 | 1984-01-31 | The Goodyear Tire & Rubber Company | Microencapsulated aqueous polymerization catalyst |
US4518770A (en) * | 1984-01-30 | 1985-05-21 | Atlantic Richfield Company | Process for the preparation of polyhydroxybutadienes |
DE3538130A1 (de) * | 1985-10-26 | 1987-04-30 | Bunawerke Huels Gmbh | Verfahren und katalysator zur herstellung von syndiotaktischem 1,2-polybutadien |
US4790365A (en) * | 1987-09-11 | 1988-12-13 | The Goodyear Tire & Rubber Company | Tire compounds containing syndiotactic-1,2-polybutadiene |
US4902741A (en) * | 1988-08-24 | 1990-02-20 | The Goodyear Tire & Rubber Company | Syndiotactic 1,2-polybutadiene latex |
US5021381A (en) * | 1988-08-24 | 1991-06-04 | The Goodyear Tire & Rubber Company | Syndiotactic 1,2-polybutadiene latex |
US4957970A (en) * | 1989-01-23 | 1990-09-18 | The Goodyear Tire & Rubber Company | Package for compounding rubber and compounded rubber |
US5011896A (en) * | 1990-09-10 | 1991-04-30 | The Goodyear Tire & Rubber Company | Syndiotactic 1,2-polybutadiene synthesis in an aqueous medium |
US5213678A (en) * | 1991-02-08 | 1993-05-25 | Ashchem I.P., Inc. | Method for inhibiting foulant formation in organic streams using erythorbic acid or oximes |
US5346971A (en) * | 1992-05-15 | 1994-09-13 | Ube Industries, Ltd. | Aqueous suspension polymerization of 1,3-butadiene to produce syndiotactic-1,2-polybutadiene |
US5278263A (en) * | 1992-10-05 | 1994-01-11 | The Goodyear Tire & Rubber Company | Syndiotactic 1,2-polybutadiene synthesis in an aqueous medium utilizing N,N-dibutylformamide as a modifier |
US5677400A (en) * | 1995-05-02 | 1997-10-14 | Ube Industries, Ltd. | Process for producing syndiotactic-1,2-polybutadiene |
JPH0912633A (ja) * | 1995-06-27 | 1997-01-14 | Ube Ind Ltd | ポリブタジエンの製造方法 |
-
1997
- 1997-05-22 US US08/861,668 patent/US5756606A/en not_active Expired - Lifetime
-
1998
- 1998-05-14 ES ES98108781T patent/ES2191883T3/es not_active Expired - Lifetime
- 1998-05-14 DE DE69811140T patent/DE69811140T2/de not_active Expired - Fee Related
- 1998-05-14 EP EP98108781A patent/EP0879834B1/en not_active Expired - Lifetime
- 1998-05-19 JP JP10136793A patent/JPH10330418A/ja active Pending
- 1998-05-21 BR BR9801673A patent/BR9801673A/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH10330418A (ja) | 1998-12-15 |
BR9801673A (pt) | 1999-05-18 |
US5756606A (en) | 1998-05-26 |
DE69811140T2 (de) | 2003-10-23 |
DE69811140D1 (de) | 2003-03-13 |
EP0879834B1 (en) | 2003-02-05 |
EP0879834A1 (en) | 1998-11-25 |
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