ES2189349T3 - Metodo de aplicar un sobrerrevestimiento a un revestimiento de barrera termica y articulo revestido. - Google Patents
Metodo de aplicar un sobrerrevestimiento a un revestimiento de barrera termica y articulo revestido.Info
- Publication number
- ES2189349T3 ES2189349T3 ES99300830T ES99300830T ES2189349T3 ES 2189349 T3 ES2189349 T3 ES 2189349T3 ES 99300830 T ES99300830 T ES 99300830T ES 99300830 T ES99300830 T ES 99300830T ES 2189349 T3 ES2189349 T3 ES 2189349T3
- Authority
- ES
- Spain
- Prior art keywords
- thermal barrier
- overcreening
- applying
- barrier coating
- tbc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012720 thermal barrier coating Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000003628 erosive effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000005012 migration Effects 0.000 abstract 1
- 238000013508 migration Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/042—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material including a refractory ceramic layer, e.g. refractory metal oxides, ZrO2, rare earth oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/048—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12542—More than one such component
- Y10T428/12549—Adjacent to each other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
- Y10T428/12618—Plural oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Coating By Spraying Or Casting (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
UN SOBRERREVESTIMIENTO (20) APLICADO SOBRE REVESTIMIENTOS DE BARRERA TERMICA (18) TALES COMO YSZ Y OTRAS CERAMICAS DE GRANOS COLUMNARES. LA SUPERFICIE EXPUESTA DEL TBC (18) SE PREPARA PARA ASEGURARSE DE QUE QUEDE LIMPIA Y TENGA UNA RUGOSIDAD ADECUADA. A CONTINUACION SE TRATA LA SUPERFICIE Y SE DEPOSITA SOBRE LA SUPERFICIE EXPUESTA UN MATERIAL DE SOBRERREVESTIMIENTO TAL COMO UNA SOLUCION SOLIDA DE CROMIA Y ALUMINA MEDIANTE, POR EJEMPLO, UNA PULVERIZACION POR PLASMA PARA FORMAR UN SOBRERREVESTIMIENTO CONTINUO SOBRE EL TBC. EL SOBRERREVESTIMIENTO (20) ES PREFERENTEMENTE RESISTENTE A LA CORROSION Y A LA EROSION E INHIBE LA MIGRACION DE OXIGENO AL TBC Y A LA CAPA DE ALUMINA SUBYACENTES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/026,240 US6060177A (en) | 1998-02-19 | 1998-02-19 | Method of applying an overcoat to a thermal barrier coating and coated article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2189349T3 true ES2189349T3 (es) | 2003-07-01 |
Family
ID=21830666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99300830T Expired - Lifetime ES2189349T3 (es) | 1998-02-19 | 1999-02-04 | Metodo de aplicar un sobrerrevestimiento a un revestimiento de barrera termica y articulo revestido. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6060177A (es) |
| EP (1) | EP0937787B1 (es) |
| JP (1) | JP3051395B2 (es) |
| DE (1) | DE69904248T2 (es) |
| ES (1) | ES2189349T3 (es) |
| UA (1) | UA61920C2 (es) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9811456D0 (en) * | 1998-05-29 | 1998-07-29 | Rolls Royce Plc | A metallic article having a thermal barrier coating and a method of application thereof |
| US6203927B1 (en) * | 1999-02-05 | 2001-03-20 | Siemens Westinghouse Power Corporation | Thermal barrier coating resistant to sintering |
| US6403165B1 (en) * | 2000-02-09 | 2002-06-11 | General Electric Company | Method for modifying stoichiometric NiAl coatings applied to turbine airfoils by thermal processes |
| DE10008861A1 (de) * | 2000-02-25 | 2001-09-06 | Forschungszentrum Juelich Gmbh | Kombinierte Wärmedämmschichtsysteme |
| US6340500B1 (en) | 2000-05-11 | 2002-01-22 | General Electric Company | Thermal barrier coating system with improved aluminide bond coat and method therefor |
| US6846574B2 (en) * | 2001-05-16 | 2005-01-25 | Siemens Westinghouse Power Corporation | Honeycomb structure thermal barrier coating |
| EP1284337B1 (de) | 2001-08-14 | 2005-04-06 | ALSTOM Technology Ltd | Verfahren zur Bearbeitung einer beschichteten Gasturbinenschaufel |
| US6821641B2 (en) | 2001-10-22 | 2004-11-23 | General Electric Company | Article protected by thermal barrier coating having a sintering inhibitor, and its fabrication |
| US20030152814A1 (en) * | 2002-02-11 | 2003-08-14 | Dinesh Gupta | Hybrid thermal barrier coating and method of making the same |
| US6774076B2 (en) * | 2002-04-08 | 2004-08-10 | Saint-Gobain Ceramics & Plastics, Inc. | Chromia spray powders and a process for making the same |
| US6929852B2 (en) | 2002-08-08 | 2005-08-16 | Siemens Westinghouse Power Corporation | Protective overlayer for ceramics |
| US6893750B2 (en) * | 2002-12-12 | 2005-05-17 | General Electric Company | Thermal barrier coating protected by alumina and method for preparing same |
| US6933066B2 (en) * | 2002-12-12 | 2005-08-23 | General Electric Company | Thermal barrier coating protected by tantalum oxide and method for preparing same |
| US6925811B2 (en) * | 2002-12-31 | 2005-08-09 | General Electric Company | High temperature combustor wall for temperature reduction by optical reflection and process for manufacturing |
| US7003959B2 (en) * | 2002-12-31 | 2006-02-28 | General Electric Company | High temperature splash plate for temperature reduction by optical reflection and process for manufacturing |
| US7181915B2 (en) * | 2002-12-31 | 2007-02-27 | General Electric Company | High temperature centerbody for temperature reduction by optical reflection and process for manufacturing |
| DE10332938B4 (de) * | 2003-07-19 | 2016-12-29 | General Electric Technology Gmbh | Thermisch belastetes Bauteil einer Gasturbine |
| US7425231B2 (en) * | 2003-08-06 | 2008-09-16 | Air Products And Chemicals, Inc. | Feed gas contaminant removal in ion transport membrane systems |
| US7179323B2 (en) * | 2003-08-06 | 2007-02-20 | Air Products And Chemicals, Inc. | Ion transport membrane module and vessel system |
| US7658788B2 (en) * | 2003-08-06 | 2010-02-09 | Air Products And Chemicals, Inc. | Ion transport membrane module and vessel system with directed internal gas flow |
| DE10337019A1 (de) * | 2003-08-12 | 2005-03-10 | Alstom Technology Ltd Baden | Verfahren zur Bearbeitung einer beschichteten Gasturbinenschaufel |
| US20050100757A1 (en) * | 2003-11-12 | 2005-05-12 | General Electric Company | Thermal barrier coating having a heat radiation absorbing topcoat |
| US7285312B2 (en) * | 2004-01-16 | 2007-10-23 | Honeywell International, Inc. | Atomic layer deposition for turbine components |
| US20050238807A1 (en) * | 2004-04-27 | 2005-10-27 | Applied Materials, Inc. | Refurbishment of a coated chamber component |
| US7413808B2 (en) * | 2004-10-18 | 2008-08-19 | United Technologies Corporation | Thermal barrier coating |
| US7935387B2 (en) * | 2004-10-20 | 2011-05-03 | Ues, Inc. | Methods for fabricating YAG barrier coatings |
| US7771519B2 (en) * | 2005-01-03 | 2010-08-10 | Air Products And Chemicals, Inc. | Liners for ion transport membrane systems |
| US7306859B2 (en) * | 2005-01-28 | 2007-12-11 | General Electric Company | Thermal barrier coating system and process therefor |
| US20060280955A1 (en) * | 2005-06-13 | 2006-12-14 | Irene Spitsberg | Corrosion resistant sealant for EBC of silicon-containing substrate and processes for preparing same |
| US20060280954A1 (en) * | 2005-06-13 | 2006-12-14 | Irene Spitsberg | Corrosion resistant sealant for outer EBL of silicon-containing substrate and processes for preparing same |
| US8021742B2 (en) * | 2006-12-15 | 2011-09-20 | Siemens Energy, Inc. | Impact resistant thermal barrier coating system |
| US20080145643A1 (en) | 2006-12-15 | 2008-06-19 | United Technologies Corporation | Thermal barrier coating |
| US8001669B2 (en) * | 2007-09-27 | 2011-08-23 | United Technologies Corporation | Pressurized cleaning of a turbine engine component |
| US9725797B2 (en) | 2008-04-30 | 2017-08-08 | United Technologies Corporation | Process for forming an improved durability thick ceramic coating |
| US20100028549A1 (en) * | 2008-07-31 | 2010-02-04 | United Technologies Corporation | Dispersion Strengthened Rare Earth Stabilized Zirconia |
| US20100304037A1 (en) * | 2009-06-01 | 2010-12-02 | United Technologies Corporation | Thermal Barrier Coatings and Application Methods |
| EP2506980B1 (en) | 2009-11-30 | 2016-06-01 | United Technologies Corporation | Coating methods and apparatus |
| FR2962447B1 (fr) * | 2010-07-06 | 2013-09-20 | Snecma | Barriere thermique pour aube de turbine, a structure colonnaire avec des colonnes espacees |
| US9139897B2 (en) | 2010-12-30 | 2015-09-22 | United Technologies Corporation | Thermal barrier coatings and methods of application |
| US8642140B2 (en) | 2011-03-09 | 2014-02-04 | United Technologies Corporation | Ceramic coating deposition |
| US8951350B2 (en) | 2011-05-03 | 2015-02-10 | United Technologies Corporation | Coating methods and apparatus |
| US9023437B2 (en) | 2012-05-15 | 2015-05-05 | United Technologies Corporation | Ceramic coating deposition |
| DE102015213555A1 (de) * | 2015-07-20 | 2017-03-09 | MTU Aero Engines AG | Dichtrippenpanzerung und Verfahren zur Herstellung derselben |
| US10578014B2 (en) * | 2015-11-20 | 2020-03-03 | Tenneco Inc. | Combustion engine components with dynamic thermal insulation coating and method of making and using such a coating |
| JP6908973B2 (ja) * | 2016-06-08 | 2021-07-28 | 三菱重工業株式会社 | 遮熱コーティング、タービン部材、ガスタービン、ならびに遮熱コーティングの製造方法 |
| US9988716B2 (en) | 2016-07-28 | 2018-06-05 | United Technologies Corporation | Coating methods and apparatus |
| EP3333284A1 (en) * | 2016-12-08 | 2018-06-13 | Siemens Aktiengesellschaft | Nondestructive method to evaluate microstructure of segmented coatings |
| US12196093B2 (en) * | 2017-05-25 | 2025-01-14 | Rtx Corporation | Aluminum-chromium oxide coating and method therefor |
| CN109023201B (zh) * | 2018-07-19 | 2020-05-22 | 西安交通大学 | 一种双层梯度结构热障涂层及其制备工艺 |
| EP3892750A1 (en) * | 2020-04-07 | 2021-10-13 | Siemens Aktiengesellschaft | Surface treatment before applying tbc |
| CN113897573B (zh) * | 2021-09-28 | 2023-12-12 | 德清创智科技股份有限公司 | 一种适用于化纤倍捻机铝基转杯陶瓷涂层的制备方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4321310A (en) * | 1980-01-07 | 1982-03-23 | United Technologies Corporation | Columnar grain ceramic thermal barrier coatings on polished substrates |
| US4405659A (en) * | 1980-01-07 | 1983-09-20 | United Technologies Corporation | Method for producing columnar grain ceramic thermal barrier coatings |
| DE3513882A1 (de) * | 1985-04-17 | 1986-10-23 | Plasmainvent AG, Zug | Schutzschicht |
| US4738227A (en) * | 1986-02-21 | 1988-04-19 | Adiabatics, Inc. | Thermal ignition combustion system |
| US4904542A (en) * | 1988-10-11 | 1990-02-27 | Midwest Research Technologies, Inc. | Multi-layer wear resistant coatings |
| US5087477A (en) * | 1990-02-05 | 1992-02-11 | United Technologies Corporation | Eb-pvd method for applying ceramic coatings |
| US5034284A (en) * | 1990-05-10 | 1991-07-23 | United Technologies Corporation | Thermal fatigue resistant coatings |
| US5169674A (en) * | 1990-10-23 | 1992-12-08 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Method of applying a thermal barrier coating system to a substrate |
| US5236787A (en) * | 1991-07-29 | 1993-08-17 | Caterpillar Inc. | Thermal barrier coating for metallic components |
| US5245264A (en) * | 1992-03-24 | 1993-09-14 | J. M. Voith, Gmbh | Real time straightness deviation measuring and compensation device for machine tools |
| US5305726A (en) * | 1992-09-30 | 1994-04-26 | United Technologies Corporation | Ceramic composite coating material |
| US5350599A (en) * | 1992-10-27 | 1994-09-27 | General Electric Company | Erosion-resistant thermal barrier coating |
| US5338577A (en) * | 1993-05-14 | 1994-08-16 | Kemira, Inc. | Metal with ceramic coating and method |
| US5562998A (en) * | 1994-11-18 | 1996-10-08 | Alliedsignal Inc. | Durable thermal barrier coating |
| US5660885A (en) * | 1995-04-03 | 1997-08-26 | General Electric Company | Protection of thermal barrier coating by a sacrificial surface coating |
| US5740515A (en) * | 1995-04-06 | 1998-04-14 | Siemens Aktiengesellschaft | Erosion/corrosion protective coating for high-temperature components |
| US5773141A (en) * | 1995-04-06 | 1998-06-30 | General Electric Company | Protected thermal barrier coating composite |
| CH690856A5 (de) * | 1995-04-06 | 2001-02-15 | Gen Electric | Verfahren und Verbundstoff zum Schutz eines Wärmesperrenüberzuges durch einen undurchlässigen Sperrüberzug. |
| US5512382A (en) * | 1995-05-08 | 1996-04-30 | Alliedsignal Inc. | Porous thermal barrier coating |
| US5683825A (en) * | 1996-01-02 | 1997-11-04 | General Electric Company | Thermal barrier coating resistant to erosion and impact by particulate matter |
| US5900326A (en) * | 1997-12-16 | 1999-05-04 | United Technologies Corporation | Spallation/delamination resistant thermal barrier coated article |
-
1998
- 1998-02-19 US US09/026,240 patent/US6060177A/en not_active Expired - Lifetime
-
1999
- 1999-02-04 DE DE69904248T patent/DE69904248T2/de not_active Expired - Lifetime
- 1999-02-04 EP EP99300830A patent/EP0937787B1/en not_active Expired - Lifetime
- 1999-02-04 ES ES99300830T patent/ES2189349T3/es not_active Expired - Lifetime
- 1999-02-16 JP JP11036692A patent/JP3051395B2/ja not_active Expired - Fee Related
- 1999-02-18 UA UA99020956A patent/UA61920C2/uk unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0937787A1 (en) | 1999-08-25 |
| JP3051395B2 (ja) | 2000-06-12 |
| DE69904248T2 (de) | 2003-08-14 |
| EP0937787B1 (en) | 2002-12-04 |
| DE69904248D1 (de) | 2003-01-16 |
| US6060177A (en) | 2000-05-09 |
| UA61920C2 (en) | 2003-12-15 |
| JPH11310885A (ja) | 1999-11-09 |
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