ES2189069T3 - Complejos cataliticos basados en lantanidos para la (co) polimerizacion de dienos conjugados. - Google Patents
Complejos cataliticos basados en lantanidos para la (co) polimerizacion de dienos conjugados.Info
- Publication number
- ES2189069T3 ES2189069T3 ES98121294T ES98121294T ES2189069T3 ES 2189069 T3 ES2189069 T3 ES 2189069T3 ES 98121294 T ES98121294 T ES 98121294T ES 98121294 T ES98121294 T ES 98121294T ES 2189069 T3 ES2189069 T3 ES 2189069T3
- Authority
- ES
- Spain
- Prior art keywords
- lantanids
- polymerization
- lnx
- catalitic
- complexes based
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002642 lithium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
- C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
Abstract
LA INVENCION SE REFIERE A COMPLEJOS DE LANTANIDOS QUE SON EFECTIVOS PARA LA POLIMERIZACION DE DIENOS CONJUGADOS, OBTENIDOS HACIENDO REACCIONAR LNX 3 CON AL MENOS UN COMPUESTO DE LITIO, SELECCIONADO A PARTIR DE: (I) LI(A), ESTANDO COMPRENDIDA LA RELACION MOLAR LI(A)/LNX 3 ENTRE 1,5 Y 2,5; (II) LILN(A) 4 , ESTANDO COMPRENDIDA LA RELACION MOLAR ENTRE LILN(A ) 4 Y ESTANDO COMPRENDIDO LNX 3 ENTRE 0,5 Y 1,5; DONDE LN SE SELECCIONA A PARTIR DE CUALQUIER LANTANIDO; X SE SELECCIONA A PARTIR DE HALUROS, CARBOXILATOS, ALCOHOLATOS, - N(R SUB,X )(R Y ), DONDE R X Y R Y , IGUALES O DISTINT OS, SON RADICALES ALQUILO C 1 - C 5 ; A ES UN RADICAL ALILO CON LA SIGUIENTE FORMULA GENERAL: DONDE R 1 , R 2 , R 3 , R 4 Y R 5 , IGUALES O DISTINTOS, SE SEL ECCIONAN A PARTIR DE HIDROGENO Y RADICALES ALQUILO C 1 C 10 .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT97MI002628A IT1296572B1 (it) | 1997-11-27 | 1997-11-27 | Complessi catalitici a base di lantanidi per la (co)polimerizzazione di dieni coniugati |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2189069T3 true ES2189069T3 (es) | 2003-07-01 |
Family
ID=11378272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98121294T Expired - Lifetime ES2189069T3 (es) | 1997-11-27 | 1998-11-09 | Complejos cataliticos basados en lantanidos para la (co) polimerizacion de dienos conjugados. |
Country Status (14)
Country | Link |
---|---|
US (1) | US6121429A (es) |
EP (1) | EP0919573B1 (es) |
JP (1) | JP4749521B2 (es) |
KR (1) | KR100318646B1 (es) |
CN (1) | CN1139603C (es) |
BR (1) | BR9805054A (es) |
CA (1) | CA2251403C (es) |
DE (1) | DE69811043T2 (es) |
ES (1) | ES2189069T3 (es) |
IT (1) | IT1296572B1 (es) |
RU (1) | RU2213100C2 (es) |
TR (1) | TR199802437A2 (es) |
TW (1) | TW499440B (es) |
ZA (1) | ZA9810791B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100352764B1 (ko) * | 2000-03-16 | 2002-09-16 | 금호석유화학 주식회사 | 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매 |
FR2814737B1 (fr) * | 2000-10-03 | 2003-08-29 | Rhodia Terres Rares | Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur |
JP5001000B2 (ja) | 2003-02-21 | 2012-08-15 | スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 共役オレフィンのホモ重合又は共重合方法 |
DE102005059940B4 (de) | 2004-12-14 | 2018-12-20 | Albemarle Germany Gmbh | Verfahren zur Herstellung von wasserfreien Seltenerdmetallhalogeniden, wasserfreie Seltenerdmetallhalogenide enthaltende Synthesegemische und deren Verwendung |
FR2899903B1 (fr) * | 2006-04-14 | 2012-01-06 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene. |
RU2011116768A (ru) * | 2008-10-03 | 2013-03-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Композиции для износостойких пен и способы для их производства |
CN102245511B (zh) | 2008-10-08 | 2016-11-09 | 凯密特尔有限责任公司 | 制造在有机溶剂中的混合金属的稀土金属卤化物溶液的方法 |
FR2939800B1 (fr) | 2008-12-15 | 2011-06-17 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique fonctionnalise, tel qu'un polybutadiene. |
US9266978B2 (en) | 2010-07-30 | 2016-02-23 | Bridgestone Corporation | Copolymer and method of manufacturing the same |
JP6055827B2 (ja) * | 2012-07-04 | 2016-12-27 | 株式会社ブリヂストン | ポリブタジエンの製造方法、ポリブタジエン、ゴム組成物及びタイヤ |
KR101899637B1 (ko) | 2015-06-24 | 2018-09-17 | 주식회사 엘지화학 | 공액 디엔계 중합체 제조용 촉매 조성물 및 이를 이용하여 제조된 공액 디엔계 중합체 |
CN109880008B (zh) * | 2019-01-29 | 2021-07-02 | 大连理工大学 | 间戊二烯-异戊二烯共聚橡胶及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4801666A (en) * | 1985-03-25 | 1989-01-31 | Northwestern University | Olefin and cycloalkene polymerization with organolanthanide catalysts |
CN1146466A (zh) * | 1996-06-24 | 1997-04-02 | 中国科学院成都有机化学研究所 | 生物降解性聚酯材料的合成方法 |
-
1997
- 1997-11-27 IT IT97MI002628A patent/IT1296572B1/it active IP Right Grant
-
1998
- 1998-11-06 CA CA002251403A patent/CA2251403C/en not_active Expired - Fee Related
- 1998-11-09 EP EP98121294A patent/EP0919573B1/en not_active Expired - Lifetime
- 1998-11-09 DE DE69811043T patent/DE69811043T2/de not_active Expired - Lifetime
- 1998-11-09 ES ES98121294T patent/ES2189069T3/es not_active Expired - Lifetime
- 1998-11-12 KR KR1019980048454A patent/KR100318646B1/ko not_active IP Right Cessation
- 1998-11-16 US US09/192,323 patent/US6121429A/en not_active Expired - Lifetime
- 1998-11-25 TR TR1998/02437A patent/TR199802437A2/xx unknown
- 1998-11-25 BR BR9805054-0A patent/BR9805054A/pt not_active IP Right Cessation
- 1998-11-25 ZA ZA9810791A patent/ZA9810791B/xx unknown
- 1998-11-26 RU RU98121226/04A patent/RU2213100C2/ru not_active IP Right Cessation
- 1998-11-27 TW TW87119743A patent/TW499440B/zh not_active IP Right Cessation
- 1998-11-27 JP JP33741498A patent/JP4749521B2/ja not_active Expired - Fee Related
- 1998-11-27 CN CNB981265219A patent/CN1139603C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0919573A1 (en) | 1999-06-02 |
JP4749521B2 (ja) | 2011-08-17 |
TR199802437A3 (tr) | 1999-06-21 |
TW499440B (en) | 2002-08-21 |
DE69811043T2 (de) | 2003-09-04 |
RU2213100C2 (ru) | 2003-09-27 |
KR100318646B1 (ko) | 2002-06-20 |
KR19990045237A (ko) | 1999-06-25 |
ITMI972628A1 (it) | 1999-05-27 |
ZA9810791B (en) | 1999-05-25 |
TR199802437A2 (xx) | 1999-06-21 |
DE69811043D1 (de) | 2003-03-06 |
JP2000204109A (ja) | 2000-07-25 |
CA2251403C (en) | 2008-09-09 |
US6121429A (en) | 2000-09-19 |
CA2251403A1 (en) | 1999-05-27 |
BR9805054A (pt) | 1999-12-14 |
IT1296572B1 (it) | 1999-07-14 |
EP0919573B1 (en) | 2003-01-29 |
CN1139603C (zh) | 2004-02-25 |
CN1222532A (zh) | 1999-07-14 |
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