ES2174545T3 - Procedimiento y dispositivo para la reduccion de oxidos de nitrogeno en el gas de escape de una instalacion de combustion. - Google Patents

Procedimiento y dispositivo para la reduccion de oxidos de nitrogeno en el gas de escape de una instalacion de combustion.

Info

Publication number
ES2174545T3
ES2174545T3 ES98966533T ES98966533T ES2174545T3 ES 2174545 T3 ES2174545 T3 ES 2174545T3 ES 98966533 T ES98966533 T ES 98966533T ES 98966533 T ES98966533 T ES 98966533T ES 2174545 T3 ES2174545 T3 ES 2174545T3
Authority
ES
Spain
Prior art keywords
exhaust gas
nitrogen oxides
reducing agent
procedure
reduction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98966533T
Other languages
English (en)
Inventor
Gerhard Wissler
Gunther Pajonk
Manfred Weigl
Lothar Hofmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Application granted granted Critical
Publication of ES2174545T3 publication Critical patent/ES2174545T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8696—Controlling the catalytic process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9431—Processes characterised by a specific device
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9495—Controlling the catalytic process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
    • F01N2900/06—Parameters used for exhaust control or diagnosing
    • F01N2900/18—Parameters used for exhaust control or diagnosing said parameters being related to the system for adding a substance into the exhaust
    • F01N2900/1806—Properties of reducing agent or dosing system
    • F01N2900/1818—Concentration of the reducing agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Treating Waste Gases (AREA)

Abstract

Procedimiento para la reducción catalítica de óxidos de nitrógeno en el gas de escape (A) de una instalación de combustión (1), especialmente de un motor Diesel, donde en función de parámetros que caracterizan el estado de funcionamiento de la instalación de combustión (1), el gas de escape (A) y/o un catalizador (5), se determina una cantidad a dosicar de una solución de agente reductor y se introduce en la dirección de la circulación del gas de escape (A) delante del catalizador (5) en el gas de escape (A), siendo liberado un agente reductor a partir de la solución de agente reductor (R) y siendo convertido con los óxidos de nitrógeno en el catalizador (5), caracterizado porque se determina la concentración de la solución de agente reductor (R) de una manera discontinua durante y/o antes de la introducción de la solución de agente reductor en el gas de escape y se adapta la cantidad a dosificar a la concentración determinada.
ES98966533T 1997-12-17 1998-12-11 Procedimiento y dispositivo para la reduccion de oxidos de nitrogeno en el gas de escape de una instalacion de combustion. Expired - Lifetime ES2174545T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19756251A DE19756251C1 (de) 1997-12-17 1997-12-17 Verfahren und Vorrichtung zur Reduzierung der Stickoxide im Abgas einer Verbrennungsanlage

Publications (1)

Publication Number Publication Date
ES2174545T3 true ES2174545T3 (es) 2002-11-01

Family

ID=7852340

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98966533T Expired - Lifetime ES2174545T3 (es) 1997-12-17 1998-12-11 Procedimiento y dispositivo para la reduccion de oxidos de nitrogeno en el gas de escape de una instalacion de combustion.

Country Status (9)

Country Link
US (1) US6408619B1 (es)
EP (1) EP1042052B1 (es)
JP (1) JP2002508466A (es)
KR (1) KR100373433B1 (es)
AT (1) ATE214628T1 (es)
DE (2) DE19756251C1 (es)
DK (1) DK1042052T3 (es)
ES (1) ES2174545T3 (es)
WO (1) WO1999030810A1 (es)

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DE10047519A1 (de) * 2000-09-22 2002-04-18 Bosch Gmbh Robert Verfahren und Vorrichtung zur Dosierung eines Reduktionsmittels zur Entfernung von Stickoxiden aus Abgasen
DE10102237A1 (de) * 2001-01-19 2002-08-08 Bosch Gmbh Robert Vorrichtung zur Dosierung einer Harnstofflösung
DE10139142A1 (de) * 2001-08-09 2003-02-20 Bosch Gmbh Robert Abgasbehandlungseinheit und Messvorrichtung zur Ermittlung einer Konzentration einer Harnstoff-Wasser-Lösung
DE20116379U1 (de) 2001-10-05 2002-01-03 PUREM Abgassysteme GmbH & Co. KG, 58706 Menden Vorrichtung zum Dosieren eines gasförmigen Reduktionsmittels
US20040083721A1 (en) * 2002-11-06 2004-05-06 Ford Global Technologies, Inc. Diesel aftertreatment systems
DE10300408A1 (de) * 2003-01-09 2004-07-22 Emitec Gesellschaft Für Emissionstechnologie Mbh Verfahren zur Behandlung eines Fluids und Wabenkörper
JP3687915B2 (ja) 2003-10-27 2005-08-24 日産ディーゼル工業株式会社 液体判別装置
JP3687916B2 (ja) 2003-10-28 2005-08-24 日産ディーゼル工業株式会社 エンジンの排気浄化装置
JP3687917B2 (ja) 2003-10-31 2005-08-24 日産ディーゼル工業株式会社 液体還元剤の濃度及び残量検出装置
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US7776265B2 (en) * 2004-03-18 2010-08-17 Cummins Filtration Ip, Inc. System for diagnosing reagent solution quality
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JP3686670B1 (ja) 2004-10-29 2005-08-24 日産ディーゼル工業株式会社 排気浄化装置
JP3686669B1 (ja) 2004-10-29 2005-08-24 日産ディーゼル工業株式会社 液体還元剤判別装置
JP3714559B1 (ja) 2004-11-05 2005-11-09 日産ディーゼル工業株式会社 排気浄化装置
JP4681284B2 (ja) * 2004-11-18 2011-05-11 日野自動車株式会社 排気浄化装置
JP4327072B2 (ja) * 2004-11-19 2009-09-09 日産ディーゼル工業株式会社 排気浄化装置の液体還元剤判別システム
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WO2008071727A1 (en) * 2006-12-14 2008-06-19 Inergy Automotive Systems Research (Société Anonyme) Method and system for metering an aqueous ammonia precursor solution into the exhaust gases of an engine
US7954312B2 (en) * 2007-05-09 2011-06-07 Ford Global Technologies, Llc Approach for detecting reductant availability and make-up
JP5468732B2 (ja) * 2007-09-27 2014-04-09 国立大学法人豊橋技術科学大学 尿素改質装置及びそれを備えた排ガス浄化装置
FR2928411B1 (fr) 2008-03-06 2012-04-06 Peugeot Citroen Automobiles Sa Procede et dispositif de gestion d'une solution de traitement des gaz d'echappement.
GB2460825A (en) * 2008-06-06 2009-12-16 Delphi Tech Inc Reagent dosing system
US8116961B2 (en) * 2009-06-03 2012-02-14 Ford Global Technologies, Llc Controlling of a vehicle responsive to reductant conditions
US8424286B2 (en) 2009-09-11 2013-04-23 Ford Global Technologies, Llc Vehicle relocatable exhaust system components
DE102009055738A1 (de) * 2009-11-26 2011-06-09 Continental Automotive Gmbh Verfahren zur Bestimmung des Zustandes eines Reduktionsmittels in einem Reduktionsmitteltank
DE102009055716A1 (de) * 2009-11-26 2011-06-01 Continental Automotive Gmbh Reduktionsmitteltank mit einem Tankentnahmesystem
DE102010047416B4 (de) 2010-10-02 2014-01-16 Volkswagen Ag Verfahren und Steuergerät zur Dosierung eines Reduktionsmittelträgers stromauf eines SCR-Katalysators
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Also Published As

Publication number Publication date
DE59803471D1 (de) 2002-04-25
ATE214628T1 (de) 2002-04-15
KR100373433B1 (ko) 2003-02-25
WO1999030810A1 (de) 1999-06-24
KR20010024739A (ko) 2001-03-26
DE19756251C1 (de) 1999-07-22
DK1042052T3 (da) 2002-07-08
JP2002508466A (ja) 2002-03-19
EP1042052A1 (de) 2000-10-11
EP1042052B1 (de) 2002-03-20
US6408619B1 (en) 2002-06-25

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