ES2172208T3 - Empleo de masas de moldeo de poliester de elevado peso molecular. - Google Patents
Empleo de masas de moldeo de poliester de elevado peso molecular.Info
- Publication number
- ES2172208T3 ES2172208T3 ES98949005T ES98949005T ES2172208T3 ES 2172208 T3 ES2172208 T3 ES 2172208T3 ES 98949005 T ES98949005 T ES 98949005T ES 98949005 T ES98949005 T ES 98949005T ES 2172208 T3 ES2172208 T3 ES 2172208T3
- Authority
- ES
- Spain
- Prior art keywords
- stage
- weight
- polyester molding
- elevated
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000465 moulding Methods 0.000 title abstract 2
- 229920000728 polyester Polymers 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000001125 extrusion Methods 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000000071 blow moulding Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- -1 if necessary Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 238000006068 polycondensation reaction Methods 0.000 abstract 1
- 230000000630 rising effect Effects 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/443—Protective covering
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Empleo de masas de moldeo de poliéster termoplásticas, que contienen A)de un 80 hasta un 100 % en peso de un arilato de polialquileno con una semianchura de las exotermas de cristalización de 5ºC, y B)de un 0 hasta un 20 % en peso de otros aditivos, ascendiendo los porcentajes en peso de los componentes A) y B) a un 100 %, para la obtención de cuerpos moldeados mediante moldeo por soplado, extrusión de perfiles y/o extrusión de tubos, caracterizado porque a)se esterifican o bien transesterifican en una primera etapa un ácido dicarboxílico aromático o sus ésteres o bien sus derivados formadores de ésteres con un exceso molar de un compuesto dihidroxílico, b)se precondensa en una segunda etapa el producto de transesterificación o bien de esterificación obtenido según a), y c)se policondensa en una tercera etapa el producto obtenible de b) hasta un VZ de al menos 158 ml/g, llevándose a cabo la etapa a) y b) del procedimiento en al menos dos zonas detemperatura, agregando antes o después de la policondensación c), antes del enfriamiento de la fusión, en caso dado, el componente B) y haciendo reaccionar el compuesto dihidroxílico antes de la etapa a) primero con un catalizador y seguidamente con un compuesto alcalino(térreo).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1997145921 DE19745921A1 (de) | 1997-10-17 | 1997-10-17 | Verwendung von hochmolekularen Polyesterformmassen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2172208T3 true ES2172208T3 (es) | 2002-09-16 |
Family
ID=7845839
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98949005T Expired - Lifetime ES2172208T3 (es) | 1997-10-17 | 1998-10-05 | Empleo de masas de moldeo de poliester de elevado peso molecular. |
Country Status (9)
Country | Link |
---|---|
US (1) | US6262185B1 (es) |
EP (1) | EP1044093B1 (es) |
JP (1) | JP2001520278A (es) |
KR (1) | KR100549766B1 (es) |
CN (1) | CN1137022C (es) |
AU (1) | AU9542498A (es) |
DE (2) | DE19745921A1 (es) |
ES (1) | ES2172208T3 (es) |
WO (1) | WO1999020452A1 (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19929791A1 (de) * | 1999-06-29 | 2001-02-01 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Polybutylenterephthalat aus Terephthalsäure und Butandiol |
JP4649709B2 (ja) * | 2000-07-25 | 2011-03-16 | 東亞合成株式会社 | 共重合ポリエステルの製造方法 |
KR100446473B1 (ko) * | 2001-06-20 | 2004-09-01 | 주식회사 삼양사 | 고속압출용 고점도 폴리부틸렌테레프탈레이트 수지의제조방법 |
DE102004005652A1 (de) | 2004-02-04 | 2005-08-25 | Basf Ag | Fließfähige Polyesterformmassen |
DE102004005657A1 (de) * | 2004-02-04 | 2005-08-25 | Basf Ag | Fließfähige Polyesterformmassen |
MY139705A (en) * | 2004-07-19 | 2009-10-30 | Basf Ag | Mixtures of hyperbranched polyesters with polycarbonates as additive for polyester molding compositions |
DE102004035357A1 (de) * | 2004-07-21 | 2006-03-16 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von Polyalkylenarylaten mit hyperverzweigten Polyestern und/oder Polycarbonaten |
DE102004059243A1 (de) * | 2004-08-10 | 2006-02-23 | Basf Ag | Thermoplastische Formmassen mit verbesserten Fließ- und Entformungseigenschaften |
DE102004038976A1 (de) * | 2004-08-10 | 2006-02-23 | Basf Ag | Fließfähige Polyesterformmassen mit ASA/ABS und SAN |
DE102004038979A1 (de) | 2004-08-10 | 2006-02-23 | Basf Ag | Schlagzähmodifizierte Polyester mit hyperverzweigten Polyestern |
DE102004049342A1 (de) | 2004-10-08 | 2006-04-13 | Basf Ag | Fließfähige Thermoplaste mit halogenfreiem Flammschutz |
DE102004050025A1 (de) * | 2004-10-13 | 2006-04-20 | Basf Ag | Fließfähige Thermoplaste mit Halogenflammschutz |
DE102004051241A1 (de) * | 2004-10-20 | 2006-05-04 | Basf Ag | Fließfähige Polyamide mit hyperverzweigten Polyestern/Polycarbonaten |
AU2005301432B2 (en) * | 2004-11-04 | 2008-10-23 | Nokia Technologies Oy | Apparatus and method for signal transmission and reception using downlink channel information in a sleep mode in a BWA communication system |
DE102005002044A1 (de) | 2005-01-14 | 2006-07-20 | Basf Ag | Fließfähige Polyester mit Hydrolyseschutz |
DE102005004856A1 (de) * | 2005-02-01 | 2006-08-03 | Basf Ag | Fliessfähige Polyester mit Carbodilmid-Stabilisatoren |
DE102005027549A1 (de) | 2005-06-14 | 2006-12-21 | Basf Ag | Mehrkomponentenformkörper mit Polyesterschichten |
DE102005034980A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Ag | Fasern und Flüssigkeitsbehälter aus PET |
DE102005034999A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Ag | Fließfähige Polyester mit Polyesterelastomeren |
MY179967A (en) * | 2013-03-18 | 2020-11-19 | Basf Se | Polyester for profile extrusion and/or tube extrusion |
PL3512913T3 (pl) * | 2016-09-14 | 2020-12-14 | Basf Se | Poliester do wytłaczania profili i/lub wytłaczania rur |
CN109385052A (zh) * | 2018-10-22 | 2019-02-26 | 江苏亨通光电股份有限公司 | 线缆微束管及微束管线缆 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3172576D1 (en) * | 1980-04-08 | 1985-11-14 | Asahi Chemical Ind | Polyester molding composition, production thereof and molded articles produced therefrom |
EP0447450A1 (en) * | 1988-12-12 | 1991-09-25 | Raychem Corporation | Electrical conductor coated with polybutylene terephthalate |
US5026790A (en) * | 1990-08-14 | 1991-06-25 | General Electric Company | Polyester compositions exhibiting enhanced melt viscosity |
DE4401055A1 (de) * | 1994-01-15 | 1995-07-20 | Basf Ag | Verfahren zur Herstellung von thermoplastischen Polyestern mit niedrigem Carboxylendgruppengehalt |
JP3354769B2 (ja) * | 1994-11-24 | 2002-12-09 | ポリプラスチックス株式会社 | 光ファイバー被覆チューブ |
DE19509551A1 (de) * | 1995-03-16 | 1996-09-19 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastischen Polyestern |
US5695710A (en) * | 1995-05-09 | 1997-12-09 | Hoechst Celanese Corp. | Transesterified pet/pen via melt extrusion |
-
1997
- 1997-10-17 DE DE1997145921 patent/DE19745921A1/de not_active Withdrawn
-
1998
- 1998-10-05 WO PCT/EP1998/006302 patent/WO1999020452A1/de active IP Right Grant
- 1998-10-05 DE DE59802677T patent/DE59802677D1/de not_active Expired - Lifetime
- 1998-10-05 ES ES98949005T patent/ES2172208T3/es not_active Expired - Lifetime
- 1998-10-05 KR KR1020007004054A patent/KR100549766B1/ko active IP Right Grant
- 1998-10-05 EP EP19980949005 patent/EP1044093B1/de not_active Expired - Lifetime
- 1998-10-05 CN CNB988100959A patent/CN1137022C/zh not_active Expired - Lifetime
- 1998-10-05 JP JP2000516822A patent/JP2001520278A/ja not_active Withdrawn
- 1998-10-05 US US09/529,187 patent/US6262185B1/en not_active Expired - Lifetime
- 1998-10-05 AU AU95424/98A patent/AU9542498A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR20010031150A (ko) | 2001-04-16 |
AU9542498A (en) | 1999-05-10 |
KR100549766B1 (ko) | 2006-02-08 |
EP1044093A1 (en) | 2000-10-18 |
CN1275106A (zh) | 2000-11-29 |
WO1999020452A1 (de) | 1999-04-29 |
US6262185B1 (en) | 2001-07-17 |
EP1044093B1 (de) | 2002-01-16 |
CN1137022C (zh) | 2004-02-04 |
DE59802677D1 (de) | 2002-02-21 |
JP2001520278A (ja) | 2001-10-30 |
DE19745921A1 (de) | 1999-04-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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