ES2165850T3 - Procedimiento para el control de la polidispersidad de polipropileno. - Google Patents

Procedimiento para el control de la polidispersidad de polipropileno.

Info

Publication number
ES2165850T3
ES2165850T3 ES93870239T ES93870239T ES2165850T3 ES 2165850 T3 ES2165850 T3 ES 2165850T3 ES 93870239 T ES93870239 T ES 93870239T ES 93870239 T ES93870239 T ES 93870239T ES 2165850 T3 ES2165850 T3 ES 2165850T3
Authority
ES
Spain
Prior art keywords
groups
control
tertiary carbon
equal
rent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93870239T
Other languages
English (en)
Inventor
Edwar Shamshoum
David Rauscher
Douglas Burmaster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Application granted granted Critical
Publication of ES2165850T3 publication Critical patent/ES2165850T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION DESCRIBE UN SISTEMA CATALIZADOR QUE EXHIBE UN CONTROL INESPERADO DE LAS PROPIEDADES DESEADAS EN EL PRODUCTO POLIMERO. EL SISTEMA CATALIZADOR INCLUYE UN CATALIZADOR DE TITANIO DE NUEVA GENERACION EN COMBINACION CON UN DONANTE DE ELECTRON DESCRITO POR LA FORMULA (I), DONDE R1 ES UN GRUPO ALQUILO QUE CONTIENE UN ATOMO DE CARBONO TERCIARIO UNIDO A UN ATOMO DE SILICONA; R2 Y R3 SON GRUPOS ALQUILOS O ARILOS; Y R4 ES UN GRUPO ALQUILO CON UN ATOMO DE CARBONO TERCIARIO UNIDO A UN ATOMO DE SILICONA; R1 Y R4 SON IGUALES O DIFERENTES. R1 Y R4 SON PREFERENTEMENTE GRUPOS CARBONO TERCIARIOS DE 4-14 ATOMOS DE CARBONO, MAS PREFERENTEMENTE DE 4-7 ATOMOS DE CARBONO; MAS PREFERENTEMENTE R1 Y R4 SON IGUALES Y SON GRUPOS BUTIL-T. EL SISTEMA TAMBIEN EXHIBE UN BUEN CONTROL SOBRE LA DISPERSABILIDAD DE LOS PRODUCTOS POLIMERO.
ES93870239T 1992-12-23 1993-12-21 Procedimiento para el control de la polidispersidad de polipropileno. Expired - Lifetime ES2165850T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US99621792A 1992-12-23 1992-12-23

Publications (1)

Publication Number Publication Date
ES2165850T3 true ES2165850T3 (es) 2002-04-01

Family

ID=25542630

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93870239T Expired - Lifetime ES2165850T3 (es) 1992-12-23 1993-12-21 Procedimiento para el control de la polidispersidad de polipropileno.

Country Status (5)

Country Link
EP (1) EP0607771B1 (es)
JP (1) JP3399067B2 (es)
KR (1) KR100302824B1 (es)
DE (1) DE69330942T2 (es)
ES (1) ES2165850T3 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6133385A (en) * 1994-04-06 2000-10-17 Fina Technology, Inc. Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins
WO2001018075A1 (fr) * 1999-09-08 2001-03-15 Japan Polychem Corporation PROCEDE DE FABRICATION D'UN POLYMERE D'α-OLEFINE
KR101114073B1 (ko) * 2009-12-08 2012-02-22 삼성토탈 주식회사 프로필렌 중합용 고체촉매의 제조 방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991002758A1 (en) * 1989-08-18 1991-03-07 Tonen Corporation CATALYTIC COMPONENT FOR α-OLEFIN POLYMERIZATION
CA2040598A1 (en) * 1990-04-20 1991-10-21 Masatoshi Toda Process for producing polyolefins
JP3034977B2 (ja) * 1990-04-20 2000-04-17 出光石油化学株式会社 オレフィン重合体の製造方法
DE69328215T2 (de) * 1992-06-08 2000-08-10 Fina Technology, Inc. Elektrondonor zur verbesserten Olefinpolymerisation

Also Published As

Publication number Publication date
KR100302824B1 (ko) 2001-11-22
JP3399067B2 (ja) 2003-04-21
DE69330942T2 (de) 2002-06-20
EP0607771A1 (en) 1994-07-27
DE69330942D1 (de) 2001-11-22
JPH06228224A (ja) 1994-08-16
KR940014460A (ko) 1994-07-18
EP0607771B1 (en) 2001-10-17

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