ES2164868T3 - Reactivos, compuestos y procedimiento para la perfluoroalquilacion de compuestos nucleofilos, y derivados obtenidos. - Google Patents

Reactivos, compuestos y procedimiento para la perfluoroalquilacion de compuestos nucleofilos, y derivados obtenidos.

Info

Publication number
ES2164868T3
ES2164868T3 ES96904161T ES96904161T ES2164868T3 ES 2164868 T3 ES2164868 T3 ES 2164868T3 ES 96904161 T ES96904161 T ES 96904161T ES 96904161 T ES96904161 T ES 96904161T ES 2164868 T3 ES2164868 T3 ES 2164868T3
Authority
ES
Spain
Prior art keywords
sub
representing
compounds
zero
preferently
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96904161T
Other languages
English (en)
Inventor
Bernard Langlois
Nicolas Roques
Claude Wakselman
Marc Tordeux
Gerard Forat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9502157A external-priority patent/FR2730992B1/fr
Priority claimed from FR9510937A external-priority patent/FR2738814B1/fr
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2164868T3 publication Critical patent/ES2164868T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C391/00—Compounds containing selenium
    • C07C391/02—Compounds containing selenium having selenium atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/02—Addition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/32—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/22—Esters of monothiocarboxylic acids having carbon atoms of esterified thiocarboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C07C327/34—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups with amino groups bound to the same hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/04—Thiosulfonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UN REACTIVO. ESTE REACTIVO SE DEFINE PORQUE LLEVA COMO ADICION SUCESIVA O SIMULTANEA UN COMPUESTO DE FORMULA (I): R{SUB,F} M(X)(Z){SUB,N} REPRESENTANDO R UN RADICAL HIDROCARBONADO VENTAJOSAMENTE DE A LO SUMO 10 ATOMOS DE CARBONO, PREFERENTEMENTE ELEGIDO ENTRE LOS ALCOILOS O LOS ARILOS; CON R{SUB,F} REPRESENTANDO UN RADICAL DE FORMULA (II): R{SUB,1} CAL CARBONADO DONDE M ES CERO O UN NUMERO ENTERO COMPRENDIDO ENTRE 0 Y 12, DONDE LOS {CI} SEMEJANTES O DIFERENTES REPRESENTAN ATOMOS DE CLORO O PREFERENTEMENTE DE FLUOR; CON LA CONDICION DE QUE CUANDO M ES IGUAL A CERO, R{SUB,1} ES ELECTROATRAYENTE, PREFERENTEMENTE UN ATOMO DE FLUOR, CON N REPRESENTANDO CERO O 1; CON M REPRESENTANDO UN METALOIDE ELEGIDO ENTRE EL CARBONO Y LO CALCOGENOS DE RANGO SUPERIOR AL OXIGENO, CON X, Y, Z SEMEJANTES O DIFERENTES REPRESENTANDO UN CALCOGENO; UN GENERADOR DE RADICALES. APLICACION EN LA SINTESIS ORGANICA.
ES96904161T 1995-02-24 1996-02-19 Reactivos, compuestos y procedimiento para la perfluoroalquilacion de compuestos nucleofilos, y derivados obtenidos. Expired - Lifetime ES2164868T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9502157A FR2730992B1 (fr) 1995-02-24 1995-02-24 Procede d'obtention de composes perhalogenoalkyles et/ou acyles et agents de perhalogenoalkylation et/ou acylation susceptibles d'etre mis en oeuvre dans ce procede
FR9510937A FR2738814B1 (fr) 1995-09-15 1995-09-15 Reactif, compose et procede pour la perfluoroalc(o)ylation de nucleophile, ainsi que les derives obtenus

Publications (1)

Publication Number Publication Date
ES2164868T3 true ES2164868T3 (es) 2002-03-01

Family

ID=26231781

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96904161T Expired - Lifetime ES2164868T3 (es) 1995-02-24 1996-02-19 Reactivos, compuestos y procedimiento para la perfluoroalquilacion de compuestos nucleofilos, y derivados obtenidos.

Country Status (12)

Country Link
US (2) US6156163A (es)
EP (1) EP0810993B1 (es)
JP (1) JPH11504619A (es)
CN (2) CN1528722A (es)
AT (1) ATE209631T1 (es)
AU (1) AU4835796A (es)
DE (1) DE69617401T2 (es)
ES (1) ES2164868T3 (es)
HU (1) HUP9702299A3 (es)
IL (1) IL117215A0 (es)
TR (1) TR199600145A2 (es)
WO (1) WO1996026185A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU770866B2 (en) 1999-07-21 2004-03-04 Dow Agrosciences Llc Process for trifluoroacetate esters and thioesters
CN101687892B (zh) * 2007-03-30 2013-06-05 斯伯恩特私人有限公司 四卤化硅或有机卤硅烷的等离子体辅助的有机官能化
JP2009292777A (ja) * 2008-06-06 2009-12-17 Univ Meijo パーフルオロ炭化水素基導入方法
CN105646122B (zh) * 2015-01-30 2017-11-07 中国科学院上海有机化学研究所 一种含二氟甲硫基的化合物、其制备方法及应用
CN105985274B (zh) * 2015-01-30 2017-11-07 中国科学院上海有机化学研究所 二氟甲基取代的硫代芳基磺酸酯、其制备方法及应用
CN112573994B (zh) * 2020-12-15 2022-11-25 中船(邯郸)派瑞特种气体股份有限公司 一种三氟甲烷的制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822904A (en) * 1985-12-12 1989-04-18 Ethyl Corporation Perfluoroalkylation process
FR2662439B1 (fr) * 1990-05-23 1993-11-19 Rhone Poulenc Chimie Reactif et procede de perfluoroalkylation de substrats nucleophiles par les perfluoroalcanesulfinates de sodium en milieu oxydant.

Also Published As

Publication number Publication date
EP0810993A1 (fr) 1997-12-10
IL117215A0 (en) 1996-06-18
EP0810993B1 (fr) 2001-11-28
DE69617401D1 (de) 2002-01-10
HUP9702299A3 (en) 1999-03-01
US6156163A (en) 2000-12-05
TR199600145A2 (tr) 1996-10-21
DE69617401T2 (de) 2002-07-18
ATE209631T1 (de) 2001-12-15
WO1996026185A1 (fr) 1996-08-29
AU4835796A (en) 1996-09-11
CN1179148A (zh) 1998-04-15
HUP9702299A1 (hu) 1998-03-30
CN1160328C (zh) 2004-08-04
JPH11504619A (ja) 1999-04-27
CN1528722A (zh) 2004-09-15
US6506286B1 (en) 2003-01-14

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