ES2163670T3 - Preparacion de complejos de bisciclopentadienildieno. - Google Patents
Preparacion de complejos de bisciclopentadienildieno.Info
- Publication number
- ES2163670T3 ES2163670T3 ES96945575T ES96945575T ES2163670T3 ES 2163670 T3 ES2163670 T3 ES 2163670T3 ES 96945575 T ES96945575 T ES 96945575T ES 96945575 T ES96945575 T ES 96945575T ES 2163670 T3 ES2163670 T3 ES 2163670T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- cation
- metal
- zircony
- hafnium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
LA INVENCION SE REFIERE A COMPLEJOS DE BICICLOPENTADIENILO CON METALES DE TRANSICION DEL GRUPO IV, QUE CONTIENEN UN LIGANDO DE DIENO CONJUGADO, ESTANDO UNIDO DICHO DIENO AL METAL DE TRANSICION, BIEN EN FORMA DE COMPLEJO SI O BIEN EN FORMA DE COMPLEJO PI . DICHOS COMPLEJOS SE PREPARAN FACILMENTE HACIENDO REACCIONAR EN UN ORDEN CUALQUIERA: A) UNA SAL METALICA DEL GRUPO IV, CORRESPONDIENTE A LA FORMULA M''X 3 O M''''X 4 , O UN ADUCTO DE UNA BASE DE LEWIS DEL MISMO, B) UN DIENO CONJUGADO, C) UN AGENTE REDUCTOR Y D) UN COMPUESTO DE FORMULA CPM* O (CP CP)M* N , DONDE M'' ES TITANIO, ZIRCONIO O HAFNIO EN ESTADO DE OXIDACION FORMAL +3; M'''' ES TITANIO, ZIRCONIO O HAFNIO EN ESTADO DE OXIDACION FORMAL +4; X ES UN HALURO, HIDROCARBILOXI C 1-6 O UN GRUPO DI(HIDROCARBIL C 1-6 )AMIDO; D'' ES UN DIENO NO COORDINADO QUE TIENE EL MISMO NUMERO DE CARBONOS QUE D Y EL MISMO PATRON DE SUSTITUCION QUE D; M* ES UN CATION METALICO DEL GRUPO I O II, UN CATION REACTIVO DE GRIGNARD O UN GRUPO TRI(HIDROCARBIL C 1-4 )SILILO;N ES 1 CUANDO M* ES UN CATION METALICO DEL GRUPO II Y N ES 2 CUANDO M* ES UN CATION METALICO DEL GRUPO I, UN CATION DE UN REACTIVO DE GRIGNARD O UN GRUPO TRIHIDROCARBILISILILO, CON LA CONDICION DE QUE LOS REACTIVOS A) Y B) NO SE PONGAN EN CONTACTO ENTRE SI EN AUSENCIA DEL REACTIVO C).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US968496P | 1996-01-03 | 1996-01-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2163670T3 true ES2163670T3 (es) | 2002-02-01 |
Family
ID=21739119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96945575T Expired - Lifetime ES2163670T3 (es) | 1996-01-03 | 1996-12-05 | Preparacion de complejos de bisciclopentadienildieno. |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US5679816A (es) |
| EP (1) | EP0873344B1 (es) |
| JP (1) | JP4115528B2 (es) |
| KR (1) | KR19990076977A (es) |
| CN (1) | CN1070196C (es) |
| AR (1) | AR005356A1 (es) |
| AT (1) | ATE209654T1 (es) |
| AU (1) | AU707297B2 (es) |
| BR (1) | BR9612460A (es) |
| CA (1) | CA2241262C (es) |
| CO (1) | CO4770884A1 (es) |
| CZ (1) | CZ210398A3 (es) |
| DE (1) | DE69617462T2 (es) |
| ES (1) | ES2163670T3 (es) |
| HU (1) | HUP9902085A3 (es) |
| IL (1) | IL125178A (es) |
| MX (1) | MX9805415A (es) |
| NO (1) | NO983068D0 (es) |
| PL (1) | PL327505A1 (es) |
| PT (1) | PT873344E (es) |
| SK (1) | SK92298A3 (es) |
| TR (1) | TR199801263T2 (es) |
| TW (1) | TW419481B (es) |
| WO (1) | WO1997025336A1 (es) |
| ZA (1) | ZA9721B (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996016094A1 (en) * | 1994-11-23 | 1996-05-30 | The Dow Chemical Company | Preparation of syndiotactic polyolefins from prochiral olefins |
| AU3603797A (en) * | 1996-03-27 | 1997-10-17 | Dow Chemical Company, The | Allyl containing metal complexes and olefin polymerization process |
| ES2182494T3 (es) * | 1998-03-11 | 2003-03-01 | Dow Chemical Co | Procedimiento integrado para la preparacion de complejos de dienos. |
| WO2001004164A2 (en) * | 1999-07-09 | 2001-01-18 | The Dow Chemical Company | Hydrogenation of unsaturated polymers using divalent diene-containing bis-cyclopentadienyl group iv metal catalysts |
| MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
| ITMI20022055A1 (it) * | 2002-09-27 | 2004-03-28 | Enitecnologie Spa | Procedimento per la idrogenazione di omopolimeri e copolimeri di dieni coniugati. |
| US7319083B2 (en) * | 2002-10-25 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Polymerized catalyst composition |
| US20040152591A1 (en) * | 2002-10-25 | 2004-08-05 | Guo-Xin Jin | Polymerized metallocene catalyst composition |
| US7176158B2 (en) * | 2002-10-25 | 2007-02-13 | Exxonmobil Chemical Patents Inc. | Polymerization catalyst composition |
| US7119155B2 (en) * | 2002-10-25 | 2006-10-10 | Exxonmobil Chemical Patents Inc. | Polymerized catalyst composition II |
| CN102675511B (zh) * | 2011-03-07 | 2014-09-10 | 河南科技大学 | 耐磨聚双环戊二烯纳米复合材料及其制备方法 |
| CN112218873B (zh) | 2018-07-03 | 2023-11-21 | 埃克森美孚化学专利公司 | 金属茂合成方法 |
| KR102668044B1 (ko) * | 2020-05-28 | 2024-05-23 | 한화솔루션 주식회사 | 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3205550A1 (de) * | 1982-02-17 | 1983-08-25 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Herstellung von uebergangsmetallkomplexen |
| US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| NZ268270A (en) * | 1993-06-24 | 1997-10-24 | Dow Chemical Co | Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr) |
| US5543480A (en) * | 1994-06-28 | 1996-08-06 | The Dow Chemical Company | Polymerization process using diene containing catalysts |
| US5616664A (en) * | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
| US5541349A (en) * | 1994-09-12 | 1996-07-30 | The Dow Chemical Company | Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom |
| US5512693A (en) * | 1994-12-07 | 1996-04-30 | The Dow Chemical Company | Preparation of titanium (II) or zirconium (II) complexes |
-
1996
- 1996-01-03 US US08/582,324 patent/US5679816A/en not_active Expired - Lifetime
- 1996-12-05 HU HU9902085A patent/HUP9902085A3/hu unknown
- 1996-12-05 PT PT96945575T patent/PT873344E/pt unknown
- 1996-12-05 CA CA002241262A patent/CA2241262C/en not_active Expired - Fee Related
- 1996-12-05 PL PL96327505A patent/PL327505A1/xx unknown
- 1996-12-05 KR KR1019980705106A patent/KR19990076977A/ko active IP Right Grant
- 1996-12-05 CN CN96199513A patent/CN1070196C/zh not_active Expired - Fee Related
- 1996-12-05 TR TR1998/01263T patent/TR199801263T2/xx unknown
- 1996-12-05 SK SK922-98A patent/SK92298A3/sk unknown
- 1996-12-05 EP EP96945575A patent/EP0873344B1/en not_active Expired - Lifetime
- 1996-12-05 BR BR9612460A patent/BR9612460A/pt not_active Application Discontinuation
- 1996-12-05 AU AU16834/97A patent/AU707297B2/en not_active Ceased
- 1996-12-05 DE DE69617462T patent/DE69617462T2/de not_active Expired - Fee Related
- 1996-12-05 CZ CZ982103A patent/CZ210398A3/cs unknown
- 1996-12-05 AT AT96945575T patent/ATE209654T1/de not_active IP Right Cessation
- 1996-12-05 JP JP52519297A patent/JP4115528B2/ja not_active Expired - Fee Related
- 1996-12-05 WO PCT/US1996/019281 patent/WO1997025336A1/en active IP Right Grant
- 1996-12-05 IL IL12517896A patent/IL125178A/xx not_active IP Right Cessation
- 1996-12-05 ES ES96945575T patent/ES2163670T3/es not_active Expired - Lifetime
- 1996-12-31 TW TW085116361A patent/TW419481B/zh not_active IP Right Cessation
-
1997
- 1997-01-02 ZA ZA9721A patent/ZA9721B/xx unknown
- 1997-01-02 CO CO97000044A patent/CO4770884A1/es unknown
- 1997-01-03 AR ARP970100025A patent/AR005356A1/es unknown
-
1998
- 1998-07-02 NO NO983068A patent/NO983068D0/no not_active Application Discontinuation
- 1998-07-02 MX MX9805415A patent/MX9805415A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69617462T2 (de) | 2002-07-11 |
| BR9612460A (pt) | 1999-07-13 |
| NO983068L (no) | 1998-07-02 |
| MX9805415A (es) | 1998-10-31 |
| AR005356A1 (es) | 1999-04-28 |
| CN1070196C (zh) | 2001-08-29 |
| WO1997025336A1 (en) | 1997-07-17 |
| ATE209654T1 (de) | 2001-12-15 |
| JP4115528B2 (ja) | 2008-07-09 |
| CA2241262C (en) | 2004-11-23 |
| CO4770884A1 (es) | 1999-04-30 |
| IL125178A0 (en) | 1999-03-12 |
| DE69617462D1 (de) | 2002-01-10 |
| HUP9902085A3 (en) | 1999-11-29 |
| AU1683497A (en) | 1997-08-01 |
| EP0873344A1 (en) | 1998-10-28 |
| NO983068D0 (no) | 1998-07-02 |
| JP2000503023A (ja) | 2000-03-14 |
| TW419481B (en) | 2001-01-21 |
| US5679816A (en) | 1997-10-21 |
| AU707297B2 (en) | 1999-07-08 |
| CN1207103A (zh) | 1999-02-03 |
| PT873344E (pt) | 2002-04-29 |
| EP0873344B1 (en) | 2001-11-28 |
| KR19990076977A (ko) | 1999-10-25 |
| HUP9902085A2 (hu) | 1999-10-28 |
| SK92298A3 (en) | 1999-03-12 |
| IL125178A (en) | 2001-01-11 |
| CZ210398A3 (cs) | 1998-11-11 |
| CA2241262A1 (en) | 1997-07-17 |
| PL327505A1 (en) | 1998-12-21 |
| ZA9721B (en) | 1998-07-02 |
| TR199801263T2 (xx) | 1998-11-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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