ES2161562T3 - Poliisocianatos bloqueados con ester malonico y estabilizados con formaldehido contra el termoamarilleo. - Google Patents

Poliisocianatos bloqueados con ester malonico y estabilizados con formaldehido contra el termoamarilleo.

Info

Publication number
ES2161562T3
ES2161562T3 ES99105280T ES99105280T ES2161562T3 ES 2161562 T3 ES2161562 T3 ES 2161562T3 ES 99105280 T ES99105280 T ES 99105280T ES 99105280 T ES99105280 T ES 99105280T ES 2161562 T3 ES2161562 T3 ES 2161562T3
Authority
ES
Spain
Prior art keywords
blocked
stabilized
formaldehyde
termoamarille
polyisocianates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99105280T
Other languages
English (en)
Inventor
Eberhard Dr Konig
Claus Dr Kobusch
Wolfram Kuttner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2161562T3 publication Critical patent/ES2161562T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8054—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38
    • C08G18/8058—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38 with compounds of C08G18/3819
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8093—Compounds containing active methylene groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/20—Compositions for powder coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

LA INVENCION TRATA DE POLIISOCIANATOS BLOQUEADOS CON ESTER MALONICO, QUE ESTAN ESTABILIZADOS CON FORMALDEHIDO CONTRA EL AMARILLEAMIENTO TERMICO. ES CONOCIDO HACE TIEMPO EL ESTER MALONICO COMO BLOQUEANTE DEL ISOCIANATO (LIEBIGS AN. CHEM. 562 (1949) PAGINA 205 Y SIGUIENTES). UNA VARIANTE NUEVA ESPECIAL DE ESTE TIPO DE BLOQUEADO SE DESCRIBE POR EJEMPLO EN LA EP-A 600 314. LAS VENTAJAS DEL RETICULANTE BLOQUEADO DE POLIISOCIANATO CON LOS ESTERES ACIDOS DE CH ESTAN EN QUE SE CONSIGUE CON ELLOS TEMPERATURAS DE RETICULACION DE APROXIMADAMENTE UNOS 100 C, Y QUE ESTOS AGENTES BLOQUEANTES SON MAS FACILMENTE MANEJABLES EN LA INDUSTRIA.
ES99105280T 1998-03-26 1999-03-15 Poliisocianatos bloqueados con ester malonico y estabilizados con formaldehido contra el termoamarilleo. Expired - Lifetime ES2161562T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19813352A DE19813352A1 (de) 1998-03-26 1998-03-26 Malonesterblockierte Polyisocyanate mit Formaldehyd gegen Thermovergilbung

Publications (1)

Publication Number Publication Date
ES2161562T3 true ES2161562T3 (es) 2001-12-01

Family

ID=7862418

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99105280T Expired - Lifetime ES2161562T3 (es) 1998-03-26 1999-03-15 Poliisocianatos bloqueados con ester malonico y estabilizados con formaldehido contra el termoamarilleo.

Country Status (12)

Country Link
US (1) US6060573A (es)
EP (1) EP0947531B1 (es)
JP (1) JP4347945B2 (es)
AT (1) ATE203036T1 (es)
BR (1) BR9903045A (es)
CA (1) CA2266250A1 (es)
DE (2) DE19813352A1 (es)
DK (1) DK0947531T3 (es)
ES (1) ES2161562T3 (es)
GR (1) GR3036856T3 (es)
NO (1) NO317757B1 (es)
PT (1) PT947531E (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59903122D1 (de) * 1998-12-07 2002-11-21 Bayer Ag Malonester/triazolmischblockiertes hdi-trimerisat/formaldehydstabilisierung
DE19941213A1 (de) * 1999-08-30 2001-03-01 Bayer Ag Malonester-blockiertes HDI-Trimerisat mit IPDA- und Formaldehydstabilisierung
US6362359B1 (en) * 2000-12-01 2002-03-26 Bayer Corporation One-component thermoset coating compositions
DE10062411A1 (de) 2000-12-14 2002-06-20 Bayer Ag Blockierte Polyisocyanate auf HDI-Basis
DE10109228A1 (de) * 2001-02-26 2002-09-05 Bayer Ag 1K-Polyurethaneinbrennlacke und deren Verwendung
DE10132016A1 (de) * 2001-07-03 2003-01-16 Bayer Ag Cyclische Ketone als Blockierungsmittel
DE10260299A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Reaktivsysteme, deren Herstellung und deren Verwendung
DE10260269A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Neue Dual Cure-Systeme
DE10260298A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Hydrophilierte blockierte Polysocyanate
DE10300155A1 (de) * 2003-01-07 2004-07-15 Bayer Ag Neue Beschichtungssysteme
DE102004043363A1 (de) * 2004-09-08 2006-03-09 Bayer Materialscience Ag Abspalterfrei-härtende blockierte Polyisocyanate für Dual Cure Systeme
US20060089480A1 (en) * 2004-10-21 2006-04-27 Roesler Richard R Biuretized isocyanates and blocked biuretized isocyanates
US20060089481A1 (en) * 2004-10-21 2006-04-27 Roesler Richard R Blocked biuretized isocyanates
US7371807B2 (en) * 2004-10-21 2008-05-13 Bayer Materialscience Llc Blocked biuretized isocyanates
DE102004057916A1 (de) * 2004-11-30 2006-06-01 Bayer Materialscience Ag Neue Dual Cure-Systeme
JP5382979B2 (ja) * 2006-01-13 2014-01-08 三井化学株式会社 ブロックドポリイソシアネート、および該ブロックドポリイソシアネートを含む熱硬化性発泡樹脂組成物
US9394443B2 (en) 2011-11-10 2016-07-19 Momentive Performance Materials, Inc. Moisture curable organopolysiloxane composition
WO2013070227A1 (en) 2011-11-10 2013-05-16 Momentive Performance Materials Inc. Moisture curable composition of a polymer having silyl groups
KR20140113948A (ko) 2011-12-15 2014-09-25 모멘티브 퍼포먼스 머티리얼즈 인크. 수분 경화성 오가노폴리실록산 조성물
US9663657B2 (en) 2011-12-15 2017-05-30 Momentive Performance Materials Inc. Moisture curable organopolysiloxane compositions
WO2013101755A1 (en) 2011-12-29 2013-07-04 Momentive Performance Materials, Inc. Moisture curable organopolysiloxane composition
JP6272359B2 (ja) 2013-02-15 2018-01-31 モーメンティブ・パフォーマンス・マテリアルズ・インク シリコーンヒドロゲルを含む防汚システム
TW201434882A (zh) 2013-03-13 2014-09-16 Momentive Performance Mat Inc 可濕氣固化之有機聚矽氧烷組成物
JP2016521309A (ja) 2013-05-10 2016-07-21 モーメンティブ・パフォーマンス・マテリアルズ・インク 非金属触媒室温湿気硬化性オルガノポリシロキサン組成物
EP2805976A1 (en) * 2013-05-24 2014-11-26 Huntsman International Llc Aldehyde comprising compositions suitable for making curable polyisocyanate compositions
US10174169B2 (en) 2013-11-26 2019-01-08 Momentive Performance Materials Inc. Moisture curable compound with metal-arene complexes
EP3556789A1 (de) 2018-04-16 2019-10-23 Evonik Degussa GmbH Hydrophile vernetzer enthaltend alkoxysilangruppen
WO2022061705A1 (zh) * 2020-09-25 2022-03-31 万华化学集团股份有限公司 一种色度稳定的含异氰脲酸酯的多异氰酸酯组合物及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4518522A (en) * 1983-09-19 1985-05-21 Mobay Chemical Corporation Blocked polyisocyanates with improved storage stability
US4677180A (en) * 1986-07-16 1987-06-30 Mobay Corporation Polyurethane compositions with improved storage stability
DE4240480A1 (de) * 1992-12-02 1994-08-25 Bayer Ag Organische Polyisocyanate mit zumindest teilweise blockierten Isocyanatgruppen
DE4339367A1 (de) * 1993-11-18 1995-05-24 Bayer Ag Blockierte Polyisocyanate
DE19637334A1 (de) * 1996-09-13 1998-03-19 Bayer Ag Stabilisierte blockierte Isocyanate

Also Published As

Publication number Publication date
US6060573A (en) 2000-05-09
EP0947531B1 (de) 2001-07-11
EP0947531A1 (de) 1999-10-06
GR3036856T3 (en) 2002-01-31
DE59900152D1 (de) 2001-08-16
DK0947531T3 (da) 2001-10-01
CA2266250A1 (en) 1999-09-26
JP4347945B2 (ja) 2009-10-21
NO991457D0 (no) 1999-03-25
DE19813352A1 (de) 1999-09-30
JPH11322892A (ja) 1999-11-26
ATE203036T1 (de) 2001-07-15
BR9903045A (pt) 2000-05-02
NO991457L (no) 1999-09-27
PT947531E (pt) 2001-10-31
NO317757B1 (no) 2004-12-13

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